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Safety Data Sheet EN

Cementitious building materials in general

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Cementitious building materials in general
Product Form
dry mortar / powder
Chemical Name
Portland Cement Clinker; Flue Dust

Regulatory Identifiers

CAS Number
N/A

Identified Uses

The building material is a hydraulically setting dry mortar for the use in earthworks and civil engineering. The product is simply mixed with water and does not need any further additives. Related activities include the handling of dry materials (powder) as well as of materials mixed with water (suspension).

Manufacturers & Suppliers

H

HEIDELBERGCEMENT

manufacturer

H

HeidelbergCement AG

manufacturer

Berliner Str. 6, 69120 Heidelberg, Germany

+49 6221 / 481 – 0

Emergency Contacts

Poison Information Center in Mainz, Germany

+49 6131 / 19 240

24 hours / 7 days

DE, EN

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P102 Keep out of reach of children.
P261 Avoid breathing dust.
P280 Wear protective gloves/protective clothing/eye protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P501 Dispose of contents/container to suitable waste collection points.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Portland cement clinker EC: 266-043-4 65997-15-1 2 - 100% Yes
Flue Dust EC: 270-659-9 68475-76-3 0.1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Seek fresh air. Dust should quickly be removed from throat and nose.

Symptoms: discomfort, coughing or persistent irritation

Skin contact

Remove dry product and rinse abundantly with water. Rinse wet product with plenty of water. Remove contaminated clothing, footwear, watches, etc. and clean these thoroughly before re-using them.

Symptoms: irritation or burns

Eye contact

Do not rub eyes dry. Where applicable, remove contact lenses and immediately rinse the eye, while open, under running water for at least 20 minutes in order to remove all particles. If possible, use isotonic eye-cleansing solution (0.9 % NaCl).

Symptoms: mechanical stress may cause additional damage to the cornea

Ingestion

Do not induce vomiting. If the person is conscious, wash out mouth with water and give plenty of water to drink.

Immediate Medical Attention

Always consult an occupational physician or ophthalmologist for eye contact. Seek medical treatment in all cases of skin irritation or burns. Consult a physician for inhalation if symptoms such as discomfort, coughing or persistent irritation occur. Get immediate medical attention or contact the poison information center for ingestion.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Specific hazards

The products are non-combustible and non-explosive and will not facilitate or sustain the combustion of other materials.

Instructions

No special measures are required.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment as described in section 8. Follow the advice for safe handling and use given in section 7.

Environmental

The products should not penetrate the sewage water system, surface water or groundwater.

Cleanup methods

Dry product: Absorb spilled product and reuse, if possible. Use dry methods to clean, such as vacuum exhaust (portable devices with highly efficient filter systems (EPA and HEPA filters, EN 1822-1:2009) or equivalent techniques). Wet product: Clean up wet product and place into a container. Allow material to dry and solidify before disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear dust respirator and protective goggles in dusty environment. Use protective gloves to avoid skin contact.

Storage

The products should be stored under dry (minimizing internal condensation), water-protected conditions, clean and protected from contamination.

Hygiene

Do not eat, drink, or smoke when working.

Fire prevention

Not applicable.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Measures to prevent formation and spreading of dust, for example suitable ventilation systems and cleaning methods, which do not stir up dust. Specific technical installations (e.g., local exhaust ventilation, general ventilation) are recommended based on the exposure scenario (see table in 8.2.1). For professional use (PROC 19), process only in well-ventilated rooms or outdoors.

Hands

Wear waterproof, abrasion, and alkali-resistant gloves. Leather gloves are not suitable due to their water penetrability and can release chromate-containing compounds. For handling the products, special gloves for chemicals (Cat. III) are not required. Investigations have proven that nitrile impregnated cotton gloves (layer thickness of about 0.15 mm) provide sufficient protection over a period of 480 minutes. Change soaked gloves. Have spare gloves ready.

Eyes

Use tight-fitting safety goggles according to EN 166 where dust is formed or in case of risk of spilling.

Respiratory

Use adequate respirator masks when there is a risk that exposure limit values are exceeded (e.g. during open handling of dry powder products). If compliance with maximum allowable concentrations cannot be guaranteed by dust-limiting measures, particle-filtering half-masks of the type FFP (according to EN 149) must be used (see table in 8.2.2). General information can be found in Rule 112-190 of the DGUV. For manual and mechanical handling of ready-made cement paste, cement mortar and concrete, respiratory protective equipment is not required.

Skin/Body

Wear tight footwear and long-sleeved clothing. If contact with moist product cannot be avoided, protective clothing should also be waterproof. Take care that no moist product is flowing in shoes or boots from above. Observe skin protection plan. Apply skin care products, in particular after work. General information can be found in Rule 112-195 of the DGUV.

Environmental

Air: Compliance with dust emission limit values in accordance with the Technical Instructions on Air Quality. Water: Do not discharge the products into groundwater or wastewater systems in larger quantities. An increase in pH value is possible through exposure. At a pH value above 9, ecotoxicological effects may occur. Water directed or drained off into the wastewater system or surface water should therefore not lead to such a relevant pH value. Wastewater and groundwater regulations must be observed. Soil: Compliance with the German Federal Soil Protection Act (BBodSchG) and the German Federal Soil Protection and Contamination Ordinance (BBodSchV).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
0.8-2.2 g/cm³
Vapor Pressure
Not applicable, as melting point > 1250 °C.
Ph
11-13.5
Partition Coefficient
Not applicable, as it is an inorganic mixture.
Density
2.50-3.60 g/cm³
Cloud Point
---
Decomposition Temperature
Not applicable, as not self-reactive and no organic peroxides present.
Lower Explosive Limit
Do not apply to solids.
Auto Ignition Temperature
Not applicable, only applies to gases and liquids.
Melting Point
> 1250 °C
Evaporation Rate
---
State Under Standard Conditions
---
Explosive Limits
---
Crystallisation Point
---
Appearance
---
Vapor Density
---
Solidification Point
---
Colour
light gray to dark gray
Boiling Point
Not applicable, as under normal atmospheric conditions the melting point is above 1250 °C.
Relative Evaporation Rate
---
Dynamic Viscosity
---
Form
powdery to fine-grained
Solubility In Fat
---
Softening Point
---
Relative Density
---
Physical State
The dry product is a powdery to fine-grained inorganic material.
Odor
Odorless
Physical State Data
solid
Odor Threshold
---
Kinematic Viscosity
Not applicable, only applies to liquids.
Voc Content
---
Flammability
Not applicable, as material is not combustible.
Metal Corrosion
---
Colour Intensity
---
Solubility
---
Molecular Weight
---
Properties Status
---
Upper Explosive Limit
Do not apply to solids.
Freezing Point
---
Flash Point
Does not apply to solids.
Solubility In Water
low (0.1-1.5 g/l)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable, as long as it is properly stored (see section 7).

Reactivity

The product is a hydraulic material. When mixed with water, an intended reaction takes place. As a result, the product hardens and forms a solid mass, which does not react with its environment.

Hazardous reactions

Wet product is alkaline and incompatible with acids, ammonium salts, aluminum, and other base metals. Here, hydrogen can be formed. The product dissolves in hydrofluoric acid, forming corrosive silicon tetrafluoride gas.

Avoid

It should be kept dry. Contact with incompatible materials should be avoided.

Incompatible

acids, ammonium salts, aluminum, and other base metals, hydrofluoric acid, strongly oxidizing agents such as fluorides.

Decomposition

hydrogen, corrosive silicon tetrafluoride gas, calcium silicate hydrates, calcium aluminate hydrates and calcium hydroxide (formed with water).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Gather dryly. Label container. If possible, reuse material, avoiding dust exposure and observing date of expiry. In case of disposal, cure with water and dispose of as described under 'Products cured after water addition'.

Disposal

Dispose of in strict accordance with local official directives. Do not dispose of in the sewage water system. Dispose of the cured products like of concrete waste and concrete sludge.

Waste Codes

10 13 06 Other particulates and dust EWC
17 01 01 concrete EWC
10 13 14 waste concrete and concrete sludge EWC
15 01 01 paper and cardboard packaging EWC
15 01 05 composite packaging EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Restrictions on use of cement and cement-containing mixtures regarding Chromium(VI) content per REACH Annex XVII. National German regulations include WGK 1, GISCODE ZP 1, and various TRGS.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Cementitious building materials in general?

The signal word is danger.

What is the physical form of Cementitious building materials in general?

Cementitious building materials in general is a the dry product is a powdery to fine-grained inorganic material. with light gray to dark gray color. It has odorless odor.

What is Cementitious building materials in general used for?

The building material is a hydraulically setting dry mortar for the use in earthworks and civil engineering. The product is simply mixed with water and does not need any further additives. Related activities include the handling of dry materials (powder) as well as of materials mixed with water (suspension).

What are the hazard statements for Cementitious building materials in general?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H335: May cause respiratory irritation.

What is the melting point of Cementitious building materials in general?

The melting point is > 1250 °C and the boiling point is Not applicable, as under normal atmospheric conditions the melting point is above 1250 °C..