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Safety Data Sheet EN

POLISH KP92 – Polishing Powder

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
POLISH KP92 – Polishing Powder
Product Form
powder

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Polishing powder for marble and stone, for professional use

Manufacturers & Suppliers

KLINDEX SRL logo

KLINDEX SRL

manufacturer

s.s.5 Tiburtina Valeria km 209+200, 65024 Manoppello ( PE ) ITALIA

(+39) 085 859 8546

http://www.klindex.it

Emergency Contacts

SERVIZIO ANTIVELENI – IST. GASLINI – GENOVA

010 5636245

IT

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H302
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed
H312 Harmful in contact with skin
H318 It causes serious eye damage

Precautionary Statements

P264 Carefully wash the parts of the body exposed, after use of the product.
P280 Wear protective gloves / protective clothing / eye / face.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
IN CASE OF EYE CONTACT: Remove contact lenses if easy to do. Continue rinsing thoroughly for several minutes. Call a POISON CENTER or doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Potassium trihydrogen dioxalate EC: 204-873-0 127-96-8 53 - 70% Yes
Oxalic acid EC: 205-634-3 6153-56-6 1 - 4% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Bring the subject outdoors. If breathing is difficult, seek medical attention.

Skin contact

Wash immediately with plenty of running water and possibly with soap areas of the body that have come in contact with the product, even if only suspected. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediately and dispose of safely.

Eye contact

Remove any contact lenses. Wash immediately with plenty of water for at least 15 minutes, opening her eyelids. Consult a doctor if the problem persists.

Ingestion

Call a doctor immediately. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person unless authorized by your doctor. Show this safety data sheet.

Medical Treatment

Follow your doctor's instructions.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

carbon dioxide, foam, powder and nebulised water.

Unsuitable media

No one in particular.

Specific hazards

HAZARDS CAUSED BY EXPOSURE IN CASE OF FIRE. Do not breathe combustion products. ACID SALTS OXALIC: To combustion can form caustic potassium oxide fumes.

Instructions

Cool down with water jets the containers to prevent product decomposition and the development of substances potentially hazardous for health. Collect extinguishing water which must not be discharged into drains. Dispose of contaminated water used for extinction and the remains according to current regulations.

Firefighter Protection

Always wear full fire prevention gear. Normal clothing for fire fighting, such as a compressed air breathing apparatus open circuit (EN 137), complete flame retardant (EN469), flame-resistant gloves (EN 659) and boots for the Fire Brigade (HO A29 or A30).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid breathing vapors / mist / gas.

Environmental

Contain waste with earth or sand. If you contaminate a water course, a sewer or has contaminated soil or vegetation, consult the competent authority network.

Cleanup methods

Collect mechanically spark leaked product and add it to containers for recovery or disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle the product after consultation with all other sections of this SDS. Avoid dispersal into the environment. Do not eat, drink or smoke while handling it. Remove contaminated clothing and protective equipment before entering areas in which you eat.

Storage

Store only in the original container. Store closed containers in well-ventilated place, away from direct sunlight.

Hygiene

Do not eat, drink or smoke while handling it. Remove contaminated clothing and protective equipment before entering areas in which you eat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Given that the use of appropriate technical measures should always take priority over personal protection equipment, ensure good ventilation in the workplace through effective local aspiration.

Hands

In case there is a prolonged contact with the product, it is advisable to protect your hands with work gloves resistant to penetration (ref. Standard EN 374). Recommended a thickness of gloves> 0.11 mm NBR (Nitrile rubber) or Neoprene. Final selection of the material of the gloves must also evaluate the process of using the product and any other products derived from them. It also recalled that the latex gloves can lead to sensitization.

Eyes

It is advisable to wear protective airtight goggles (ref. Standard EN 166). If there is the risk of being exposed to splashes or squirts during work, provision should be made adequate protection of the mucous membranes (mouth, nose, eyes) in order to prevent accidental absorption.

Respiratory

In case of exceeding the threshold value of one or more of the substances present in the preparation reported to the daily exposure to work environment or to a fraction established by the service of prevention and corporate security, wear a facial filter type FFP3 (ref. standard EN 141). The use of respiratory protection means, such as masks with cartridges for organic vapor and dust / mist, it is necessary in the absence of technical measures to limit the exposure of the worker. The protection provided by masks is in any case limited. In the case in which the substance in question is odorless or its olfactory threshold is higher than the relative exposure and in case of emergency limit, ie, when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear a compressed air breathing apparatus open circuit (ref. standard EN 137) or respirator outside air inlet for use with full face mask, half mask or mouthpiece (ref. standard EN 138).

Skin/Body

Wear work clothing with long sleeves and safety footwear for professional use Category II (ref. Directive 89/686 / EEC and standard EN ISO 20344). Wash with soap and water after removing protective clothing.

Environmental

The emissions from production processes, including those from ventilation should be checked for compliance with the environmental protection legislation.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Form
---
Explosive Limits
---
Crystallisation Point
---
Melting Point
90°C-170°C (start/end)
Colour
White-Yellow
Metal Corrosion
---
Appearance
---
Vapor Pressure
N.A.
Auto Ignition Temperature
N.A.
Flammability
N.A
Dynamic Viscosity
N.A.
Odor
Slightly peppery
Cloud Point
---
Evaporation Rate
N.A
Softening Point
---
Physical State
Powdered
Flash Point
Not inflammable
Density
---
Odor Threshold
---
Solidification Point
---
Lower Explosive Limit
N.A.
Solubility In Water
---
Solubility In Fat
---
Decomposition Temperature
N.A.
Molecular Weight
---
Bulk Density
0,97 gr/cm³
Colour Intensity
---
State Under Standard Conditions
---
Boiling Point
N.A.
Ph
1,0-1,5 (10% in water)
Relative Evaporation Rate
---
Vapor Density
N.A
Solubility
Partially soluble
Partition Coefficient
N.A.
Properties Status
---
Freezing Point
N.A.
Voc Content
---
Relative Density
N.A.
Upper Explosive Limit
N.A
Kinematic Viscosity
N.A.
Physical State Data
solid
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable under normal conditions of use and storage.

Reactivity

There are no particular risks of reaction with other substances in normal conditions of use. Saturated aqueous solutions (15%) behave as mediumstrong acids.

Hazardous reactions

Oxalic acid generates explosive reaction mixtures with various oxidizing agents. It reacts violently developing heat with alkali metals, ammonia, mercury, furfuryl acid, chlorates and hypochlorites. Risk of explosion on contact with: silver and sodium chlorite.

Avoid

temperatures above 157 ° C

Incompatible

Strong oxidizing agents. Metals and alkali metals, furfuryl acid and some of the chlorine compounds.

Decomposition

Oxalic acid carbon oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

12.1. Toxicity

Fish Toxicity: CL50 160 mg/l (48h Carassius auratus) – Source literature Daphnia toxicity: EC50 (48h): 162,2 mg/l Daphnia Magna – Method OECD TG 202 Toxicity to algae: 80 mg/l (8 d, Microcystis aeruginosa) – Source literature Toxicity to bacteria: 1550 mg/l (16h, Pseudomonas putida) – Source literature

12.2. Persistence and degradability

Physico-chemical removability: not available Biodegradation: 89% (20 d, BOD5/CODX100) Readily biodegradable Chemical oxygen demand (COD): about 180 mg/g – Source literature Biochemical oxygen demand (BOD5): about 160 mg/g – Source literature

12.3 Potential for bioaccumulation.

12.3 Potential for bioaccumulation.

12.3 Potential for bioaccumulation.

Given the low value of the octanol / water partition coefficient (LogPow) is not expected to bioaccumulate.

The substance is not expected to bioaccumulate due to its low octanol/water partition coefficient (LogPow).

12.4 Mobility in soil

Information not available.

12.5. Results of PBT and vPvB.

The substance does not meet the criteria in Annex XIII of Regulation (EC) 1907/2006 and is not identified as a PBT or vPvB.

The substance does not meet the criteria in Annex XIII of Regulation (EC) 1907/2006 and is not identified as a PBT or vPvB.

12.6. Other adverse effects.

The product must not enter drains, waterways or soil. Do not release to the environment.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

In the case of acid or basic product, at first always neutralize the product.

Disposal

Disposal must be performed through an authorized waste management, in compliance with national and local regulations.

Waste Codes

Not specified Waste codes are not product specific, but application specific. Waste codes should be assigned by the user, preferably in discussion with the authorities for the disposal of waste. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Workers exposed to this chemical agent to health must undergo health checks according to the provisions of Article. 41 of Legislative Decree no. 81 of April 9, 2008 unless the risk to the safety and health of the worker has been assessed irrelevant, according to art. 224 paragraph 2.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for POLISH KP92 – Polishing Powder?

The signal word is warning.

What is the physical form of POLISH KP92 – Polishing Powder?

POLISH KP92 – Polishing Powder is a powdered with white-yellow color. It has slightly peppery odor.

What is the solubility of POLISH KP92 – Polishing Powder?

Partially soluble

What is POLISH KP92 – Polishing Powder used for?

Polishing powder for marble and stone, for professional use

What are the hazard statements for POLISH KP92 – Polishing Powder?

This substance has 3 hazard statements:

  • H302: Harmful if swallowed
  • H312: Harmful in contact with skin
  • H318: It causes serious eye damage

What is the melting point of POLISH KP92 – Polishing Powder?

The melting point is 90°C-170°C (start/end) and the boiling point is N.A..