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Safety Data Sheet EN

cis-1,4-Dichloro-2-butene

CAS 1476-11-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
cis-1,4-Dichloro-2-butene
Product Code
AC187600000; AC187600250; AC187601000; AC187605000
Chemical Name
cis-1,4-Dichloro-2-butene

Regulatory Identifiers

CAS Number
1476-11-5 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 3
Acute Tox. Cat. 3
Acute Tox. Cat. 2
Skin Corrosion/Irritation Cat. 1B
Serious Eye Damage/Eye Irritation Cat. 1
Carc. Cat. 1A
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapor
H301 + H311 Toxic if swallowed or in contact with skin
H314 Causes severe skin burns and eye damage
H330 Fatal if inhaled
H335 May cause respiratory irritation
H350i May cause cancer

Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 Keep container tightly closed
P235 Keep cool
P240 Ground and bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/lighting equipment
P242 Use non-sparking tools
P243 Take action to prevent static discharges
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 Wear respiratory protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor
P330 Rinse mouth
P331 Do NOT induce vomiting
P362 + P364 Take off contaminated clothing and wash before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam to extinguish
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
2-Butene, 1,4-dichloro-, (Z)- 1476-11-5 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove to fresh air. Immediate medical attention is required.

Symptoms: Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water mist may be used to cool closed containers. CO₂, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

No information available

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Instructions

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material, suitable, closed containers

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Flammables area. Keep away from heat, sparks and flame. Protect from direct sunlight. Corrosives area. To maintain product quality: Keep refrigerated.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting equipment. Ensure adequate ventilation, especially in confined areas.

Hands

Wear appropriate protective gloves to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter. Type A. Brown. conforming to EN14387.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Appearance
Yellow
Flammability
Flammable
Density
---
Kinematic Viscosity
---
Bulk Density
Not applicable
Relative Density
1.180
Solidification Point
---
Evaporation Rate
---
Odor Threshold
No information available
Colour Intensity
---
Physical State Data
liquid
Melting Point
-48 °C / -54.4 °F
Partition Coefficient
No data available
Odor
pungent
Colour
Yellow
Ph
No information available
Solubility In Water
No information available
Auto Ignition Temperature
No data available
Physical State
Liquid
Boiling Point
152 °C / 305.6 °F
Form
---
Lower Explosive Limit
---
Freezing Point
---
Decomposition Temperature
No data available
Metal Corrosion
---
Voc Content
---
Upper Explosive Limit
---
Crystallisation Point
---
State Under Standard Conditions
---
Explosive Limits
---
Molecular Weight
125
Dynamic Viscosity
---
Vapor Density
4.32 (Air = 1.0)
Flash Point
55 °C / 131 °F
Softening Point
No data available
Vapor Pressure
No data available
Solubility In Fat
---
Properties Status
---
Solubility
---
Relative Evaporation Rate
---
Cloud Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Light sensitive. Moisture sensitive.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to moist air or water. Exposure to light.

Incompatible

Strong oxidizing agents

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3489
Shipping Name
TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S.
Transport Class
6.1
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for cis-1,4-Dichloro-2-butene?

The signal word is danger.

What is the physical form of cis-1,4-Dichloro-2-butene?

cis-1,4-Dichloro-2-butene is a liquid appearing as yellow with yellow color. It has pungent odor.

What is cis-1,4-Dichloro-2-butene used for?

Laboratory chemicals.

What are the hazard statements for cis-1,4-Dichloro-2-butene?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapor
  • H301 + H311: Toxic if swallowed or in contact with skin
  • H314: Causes severe skin burns and eye damage
  • H330: Fatal if inhaled
  • H335: May cause respiratory irritation
  • H350i: May cause cancer

What is the melting point of cis-1,4-Dichloro-2-butene?

The melting point is -48 °C / -54.4 °F and the boiling point is 152 °C / 305.6 °F.