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Safety Data Sheet EN

SELEMIX 9-080 ACRYLIC HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SELEMIX 9-080 ACRYLIC HARDENER
Product Code
1.959.5080/E1

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial applications. Hardener.

Manufacturers & Suppliers

P

PPG Industries Italia S.r.l.

manufacturer

Via Comasina, 121, 20161 Milano, Italy

+39 02 6404.1

P

PPG Industries (UK) Ltd.

manufacturer

Needham Road, Stowmarket, Suffolk, IP14 2AD, UK

+44 (0) 1449 613161

P

PPG Industries (UK) Ltd.

national supplier

Customer Services and Sales Group, Needham Road, Stowmarket, Suffolk, IP14 2AD

+44 (0) 1449 771779

Emergency Contacts

Emergency Contact

+39 02 6404.1

0800-1700

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P235 Keep cool.
P261 Avoid breathing vapour.
P280 Wear protective gloves.
P280 Wear eye or face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
n-butyl acetate EC: 204-658-1 123-86-4 25 - 50% Yes
Hexamethylene diisocyanate, oligomers EC: 500-060-2 28182-81-2 25 - 50% Yes
2-butoxyethyl acetate EC: 203-933-3 112-07-2 5 - 10% Yes
3-Isocyanatomethyl-3,5, 5-trimethylcyclohexyl isocyanate, oligomers EC: 500-125-5 53880-05-0 5 - 10% Yes
Solvent naphtha (petroleum), light arom. Nota(s) P EC: 265-199-0 64742-95-6 1 - 5% Yes
1,2,4-trimethylbenzene EC: 202-436-9 95-63-6 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.

Symptoms: Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, dryness, cracking

Eye contact

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Symptoms: No known significant effects or critical hazards. No specific data.

Ingestion

If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: Can cause central nervous system (CNS) depression. No specific data.

Immediate Medical Attention

Seek immediate medical advice for eye contact and ingestion.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Storage temperature: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Precautions should be taken to minimise exposure to atmospheric humidity or water. CO₂ will be formed, which, in closed containers, could result in pressurisation.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
>37.78°C
Flash Point
Closed cup: 24°C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Highest known value: 1.5 kPa (11.3 mm Hg) (at 20°C) (n-butyl acetate). Weighted average: 1.15 kPa (8.63 mm Hg) (at 20°C)
Vapor Density
Highest known value: 5.5 (Air = 1) (2-butoxyethyl acetate). Weighted average: 4.27 (Air = 1)
Relative Density
0.98
Bulk Density
0
Density
---
Flammability
---
Upper Explosive Limit
9%
Lower Explosive Limit
1%
Explosive Limits
---
Auto Ignition Temperature
Lowest known value: 340°C (644°F) (2-butoxyethyl acetate).
Decomposition Temperature
Not available.
Solubility
Insoluble in the following materials: cold water.
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): >0.21 cm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

In a fire, hazardous decomposition products may be produced. Refer to protective measures listed in sections 7 and 8.

Incompatible

oxidising agents, strong alkalis, strong acids, amines, alcohols, water. Uncontrolled exothermic reactions occur with amines and alcohols.

Decomposition

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen, hydrogen cyanide, monomeric isocyanates.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT RELATED MATERIAL
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SELEMIX 9-080 ACRYLIC HARDENER?

The signal word is warning.

What is the physical form of SELEMIX 9-080 ACRYLIC HARDENER?

SELEMIX 9-080 ACRYLIC HARDENER is a liquid. with colourless. color. It has characteristic. odor.

What is the solubility of SELEMIX 9-080 ACRYLIC HARDENER?

Insoluble in the following materials: cold water.

What is SELEMIX 9-080 ACRYLIC HARDENER used for?

Industrial applications. Hardener.

What are the hazard statements for SELEMIX 9-080 ACRYLIC HARDENER?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapour.
  • H317: May cause an allergic skin reaction.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of SELEMIX 9-080 ACRYLIC HARDENER?

The melting point is Not available. and the boiling point is >37.78°C.