Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- 9-070 DIRECT HARDENER
- Product Code
- 1.991.5070/E5
Regulatory Identifiers
- CAS Number
- N/A
Identified Uses
Industrial applications. Hardener.
Manufacturers & Suppliers
PPG Industries Italia S.r.l.
manufacturer
Via Comasina, 121, 20161 Milano, Italy
PPG Industries (UK) Ltd.
manufacturer
Needham Road, Stowmarket, Suffolk, IP14 2AD, UK
+44 (0) 1449 773 338
PPG Industries (UK) Ltd. Customer Services and Sales Group
distributor
Needham Road, Stowmarket, Suffolk, IP14 2AD
+44 (0) 1449 773993
Emergency Contacts
PPG Industries Italia S.r.l.
+39 02 6404.1
0800-1700
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS07
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Hexamethylene diisocyanate, oligomers EC: 500-060-2 | 28182-81-2 | 25 - 50% | Yes |
| n-butyl acetate EC: 204-658-1 | 123-86-4 | 25 - 50% | Yes |
| 2-butoxyethyl acetate EC: 203-933-3 | 112-07-2 | 5 - 10% | Yes |
| 2-methoxy-1-methylethyl acetate EC: 203-603-9 | 108-65-6 | 5 - 10% | Yes |
| Solvent naphtha (petroleum), light arom. Nota(s) P EC: 265-199-0 | 64742-95-6 | 1 - 5% | Yes |
Notes
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section. SUB codes represent substances without registered CAS Numbers.
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Symptoms: Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.
Symptoms: Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, dryness, cracking.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.
Symptoms: No known significant effects or critical hazards. No specific data.
If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.
Symptoms: Can cause central nervous system (CNS) depression. No specific data.
Immediate Medical Attention
Seek immediate medical advice for eye contact and ingestion.
Medical Treatment
No specific treatment.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use dry chemical, CO₂, water spray (fog) or foam.
Do not use water jet.
Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is harmful to aquatic life with long lasting effects.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Firefighter Protection
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. The contaminated area should be cleaned immediately with a suitable decontaminant.
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Put on appropriate personal protective equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
Store between 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Precautions should be taken to minimise exposure to atmospheric humidity or water. CO2 will be formed, which, in closed containers, could result in pressurisation.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
Store and use away from heat, sparks, open flame or any other ignition source. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. When prolonged or frequently repeated contact may occur, a glove with a protection class of 6 (breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30 minutes according to EN 374) is recommended. Gloves: butyl rubber
Safety glasses with side shields. Use eye protection according to EN 166.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Wear a respirator conforming to EN140. Filter type: organic vapour (Type A) and particulate filter P3
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is stable.
No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous reactions will not occur.
In a fire, hazardous decomposition products may be produced. Refer to protective measures listed in sections 7 and 8.
Keep away from: oxidising agents, strong alkalis, strong acids, amines, alcohols, water. Uncontrolled exothermic reactions occur with amines and alcohols.
Depending on conditions, decomposition products may include the following materials: Cyanate and isocyanate. carbon oxides nitrogen oxides hydrogen cyanide
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste Codes
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN1263
- Shipping Name
- PAINT
- Transport Class
- 3
- Packing Group
- III
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for 9-070 DIRECT HARDENER?
The signal word is warning.
What is the physical form of 9-070 DIRECT HARDENER?
9-070 DIRECT HARDENER is a liquid. with colourless. color. It has characteristic. odor.
What is the solubility of 9-070 DIRECT HARDENER?
Insoluble in the following materials: cold water.
What is 9-070 DIRECT HARDENER used for?
Industrial applications. Hardener.
What are the hazard statements for 9-070 DIRECT HARDENER?
This substance has 6 hazard statements:
- H226: Flammable liquid and vapour.
- H317: May cause an allergic skin reaction.
- H332: Harmful if inhaled.
- H335: May cause respiratory irritation.
- H336: May cause drowsiness or dizziness.
- H412: Harmful to aquatic life with long lasting effects.
What is the melting point of 9-070 DIRECT HARDENER?
The melting point is May start to solidify at the following temperature: -51.3 to -28.4°C (-60.3 to -19.1°F) This is based on data for the following ingredient: Hexamethylene diisocyanate, oligomers. Weighted average: -67.54°C (-89.6°F) and the boiling point is >37.78°C.