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Safety Data Sheet EN

SIGMADUR 580 HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMADUR 580 HARDENER
Product Code
00141219

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional applications, Used by spraying. Coating.

Manufacturers & Suppliers

P

PPG Coatings SPRL/BVBA

manufacturer

Tweemontstraat 104, B-2100 Deurne, Belgium

+32-33606311

Emergency Contacts

PPG Coatings SPRL/BVBA

+31 20 4075210

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P235 Keep cool.
P261 Avoid breathing vapour.
P280 Wear protective gloves.
P282 Wear eye or face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hexamethylene diisocyanate, oligomers EC: 500-060-2 28182-81-2 75 - 90% Yes
n-butyl acetate EC: 204-658-1 123-86-4 15% Yes
Solvent naphtha (petroleum), light arom. EC: 265-199-0 64742-95-6 5 - 10% Yes
hexamethylene-di-isocyanate EC: 212-485-8 822-06-0 0.5% Yes

Occupational exposure limits, if available, are listed in Section 8. SUB codes represent substances without registered CAS Numbers.

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: respiratory tract irritation, coughing

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.

Symptoms: Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, dryness, cracking

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Symptoms: No known significant effects or critical hazards.

Ingestion

If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: No known significant effects or critical hazards.

Immediate Medical Attention

Seek immediate medical attention (for eyes). In case of inhalation of decomposition products in a fire, symptoms may be delayed.

Medical Treatment

The exposed person may need to be kept under medical surveillance for 48 hours.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.

Storage

Storage temperature: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use non-sparking tools. Take precautionary measures against electrostatic discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Gloves: butyl rubber

Eyes

Safety glasses with side shields.

Respiratory

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Odor
Amine-like.
Solidification Point
---
Boiling Point
>37.78°C
Evaporation Rate
Not available.
Softening Point
---
Vapor Density
Highest known value: 4 (Air = 1) (n-butyl acetate).
Colour Intensity
---
Bulk Density
---
Metal Corrosion
---
Vapor Pressure
Highest known value: 1.5 kPa (11.3 mm Hg) (at 20°C) (n-butyl acetate). Weighted average: 0.85 kPa (6.38 mm Hg) (at 20°C)
Ph
Not available.
Crystallisation Point
---
Flammability
Not available.
Voc Content
---
Colour
Colourless.
Solubility In Fat
---
Freezing Point
Not available.
Properties Status
---
Cloud Point
---
Solubility In Water
Insoluble in the following materials: cold water.
Form
---
State Under Standard Conditions
---
Odor Threshold
Not available.
Dynamic Viscosity
---
Decomposition Temperature
Not available.
Kinematic Viscosity
Kinematic (room temperature): >4 cm²/s, Kinematic (40°C): >0.21 cm²/s
Solubility
Insoluble in the following materials: cold water.
Physical State
Liquid.
Lower Explosive Limit
1.29%
Melting Point
Not available.
Relative Density
1.13
Upper Explosive Limit
7.6%
Explosive Limits
---
Partition Coefficient
Not available.
Physical State Data
liquid
Molecular Weight
---
Density
---
Auto Ignition Temperature
370°C
Relative Evaporation Rate
---
Appearance
---
Flash Point
55.7°C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

In a fire, hazardous decomposition products may be produced. Refer to protective measures listed in sections 7 and 8.

Incompatible

Keep away from: oxidising agents, strong alkalis, strong acids, amines, alcohols, water. Uncontrolled exothermic reactions occur with amines and alcohols.

Decomposition

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen, hydrogen cyanide, monomeric isocyanates.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

08 01 11* waste paint and varnish containing organic solvents or other dangerous substances EWC
15 01 06 mixed packaging EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT RELATED MATERIAL
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SIGMADUR 580 HARDENER?

The signal word is warning.

What is the physical form of SIGMADUR 580 HARDENER?

SIGMADUR 580 HARDENER is a liquid. with colourless. color. It has amine-like. odor.

What is the solubility of SIGMADUR 580 HARDENER?

Insoluble in the following materials: cold water.

What is SIGMADUR 580 HARDENER used for?

Professional applications, Used by spraying. Coating.

What are the hazard statements for SIGMADUR 580 HARDENER?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapour.
  • H317: May cause an allergic skin reaction.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of SIGMADUR 580 HARDENER?

The melting point is Not available. and the boiling point is >37.78°C.