NextSDS Logo
Safety Data Sheet EN

SIGMACOVER 350 HARDENER

Keep this SDS organized and up to date

Add this SDS to your NextSDS library and keep all its safety information in one place.

Add to my SDS library for free
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMACOVER 350 HARDENER
Product Form
Liquid
Product Code
00445202

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Coating. Professional applications, Used by spraying.

Uses advised against

Product is not intended, labelled or packaged for consumer use.

Manufacturers & Suppliers

P

PPG Coatings (Thailand) Co., Ltd.

manufacturer

15 Rama 9 Road, Kwaeng Huamark, Khet Bangkapi, Bangkok 10240 Thailand

662-319-4190 #224

Emergency Contacts

CHEMTREC

001-800-13-203-9987

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 5
Acute Tox. Cat. 4
Skin Corr. Cat. 1
Eye Dam. Cat. 1
Skin Sens. Cat. 1A
STOT SE Cat. 3
Aquatic Acute Cat. 3
Aquatic Chronic Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H312 May be harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.
H413 Harmful to aquatic life.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241 Use explosion-proof electrical, ventilating or lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing vapor.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405 Store locked up.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

Still copying SDS data manually?Free

You don't have to. NextSDS reads this SDS and adds the information to your library automatically.

Let NextSDS do it for me
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
benzyl alcohol 100-51-6 10 - 20% No
reaction product: bisphenol-A-(epichlorohydrin); epoxy resin 25068-38-6 10 - 20% No
2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 3 - 5% No
3,6-diazaoctanethylenediamin 112-24-3 3 - 5% No
ethylbenzene 100-41-4 1 - 3% No
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and triethylenetetramine 68082-29-1 25 - 50% No
xylene 1330-20-7 10 - 20% No
2-methylpropan-1-ol 78-83-1 10 - 20% No

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Notes

SUB codes represent substances without registered CAS Numbers.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Causes severe burns. May be harmful in contact with skin. Defatting to the skin. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, dryness, cracking, blistering may occur

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: May be harmful if swallowed. Corrosive to the digestive tract. Causes burns. Adverse symptoms may include the following: stomach pains

Immediate Medical Attention

Seek immediate medical attention. If swallowed, seek medical advice immediately and show this container or label.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.

Storage

Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Clear.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not available.
Ph
insoluble in water.
Melting Point
Not available.
Boiling Point
>37.78°C (>100°F)
Flash Point
Closed cup: 33°C (91.4°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Relative Density
0.95
Bulk Density
0.95
Density
---
Flammability
liquid
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Stable under recommended storage and handling conditions (see Section 7).
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Not soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
>21 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products.

Incompatible

Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids.

Decomposition

Depending on conditions, decomposition products may include the following materials: carbon oxides nitrogen oxides halogenated compounds

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Product/ingredient name | Result | Species | Exposure Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and triethylenetetramine | EC10 1.78 mg/l | Algae | 72 hours

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | 2-methylpropan-1-ol | Acute EC50 1100 mg/l | Daphnia | 48 hours |

12.1 Toxicity

Chronic NOEC 0.3 mg/l Daphnia 21 days

12.1 Toxicity

Product/ingredient name: 2,4,6-tris (dimethylaminomethyl)phenol, Result: Acute LC50 >100 mg/l, Species: Daphnia, Exposure: 48 hours

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | ethylbenzene | Acute LC50 >100 mg/l | Fish | 96 hours | | | Acute EC50 1.8 mg/l Fresh water | Daphnia | 48 hours | | | Chronic NOEC 1 mg/l Fresh water | Daphnia - Ceriodaphnia dubia | - |

12.2 Persistence and degradability

reaction product: bisphenol-A-(epichlorohydrin); epoxy resin | OECD 301F | 5 % - 28 days | - | -

12.2 Persistence and degradability

2,4,6-tris (dimethylaminomethyl)phenol | OECD Ready Biodegradability - Closed Bottle Test | 4 % - Not readily - 28 days | - | -

12.2 Persistence and degradability

Product/ingredient name: ethylbenzene | Test: - | Result: 79 % - Readily - 10 days | Dose: - | Inoculum: -

12.1 Toxicity

There are no data available on the mixture itself.

12.2 Persistence and degradability

There are no data available on the mixture itself.

12.3 Bioaccumulative potential

There are no data available on the mixture itself.

12.4 Mobility in soil

There are no data available on the mixture itself.

12.5 Results of PBT and vPvB assessment

There are no data available on the mixture itself.

12.6 Endocrine disrupting properties

There are no data available on the mixture itself.

12.7 Other adverse effects

There are no data available on the mixture itself.

12.2 Persistence and degradability

Biodegradability: Not readily

The substance is not readily biodegradable.

12.1 Toxicity

12.2 Persistence and degradability

Biodegradability: Readily

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.2 Persistence and degradability

Biodegradability: Readily

12.2 Persistence and degradability

reaction product: bisphenol-A-(epichlorohydrin); epoxy resin | - | - | Not readily

12.1 Toxicity

12.2 Persistence and degradability

2,4,6-tris (dimethylaminomethyl)phenol | - | - | Not readily |

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

Product/ingredient name: xylene, LogP_ow: 3.12, BCF: 7.4 to 18.5, Potential: Low

12.1 Toxicity

Not available.

12.2 Persistence and degradability

Not available.

12.3 Bioaccumulative potential

Product/ingredient name: 2-methylpropan-1-ol, LogP_ow: 1, BCF: -, Potential: Low

12.4 Mobility in soil

Not available.

12.5 Results of PBT and vPvB assessment

Not available.

12.6 Endocrine disrupting properties

Not available.

12.7 Other adverse effects

Not available.

12.3 Bioaccumulative potential

Product/ingredient name: benzyl alcohol, LogP_ow: 0.87, BCF: -, Potential: Low

12.3 Bioaccumulative potential

reaction product: bisphenol-A-(epichlorohydrin); epoxy resin | 2.64 to 3.78 | 31 | Low

12.3 Bioaccumulative potential

Product/ingredient name: 2,4,6-tris(dimethylaminomethyl)phenol, LogP_ow: 0.219, BCF: -, Potential: Low

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | 3,6-diazaoctanethylenediamin | -1.66 to -1.4 | - | Low |

12.1 Toxicity

Not available.

12.2 Persistence and degradability

Not available.

12.3 Bioaccumulative potential

Product/ingredient name: ethylbenzene, LogP_ow: 3.6, BCF: 79.43, Potential: Low

12.4 Mobility in soil

Soil/Water partition coefficient : Not available.

12.5 Results of PBT and vPvB assessment

Not available.

12.6 Endocrine disrupting properties

Not available.

12.7 Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3469
Shipping Name
PAINT, FLAMMABLE, CORROSIVE
Transport Class
3 (8)
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

No known specific national and/or regional regulations applicable to this product (including its ingredients).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SIGMACOVER 350 HARDENER?

The signal word is danger.

What is the physical form of SIGMACOVER 350 HARDENER?

SIGMACOVER 350 HARDENER is a liquid. with clear. color. It has characteristic. odor.

What is SIGMACOVER 350 HARDENER used for?

Coating. Professional applications, Used by spraying.

What are the hazard statements for SIGMACOVER 350 HARDENER?

This substance has 8 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H312: May be harmful if swallowed or in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H411: Toxic to aquatic life with long lasting effects.
  • H413: Harmful to aquatic life.

What is the melting point of SIGMACOVER 350 HARDENER?

The melting point is Not available. and the boiling point is >37.78°C (>100°F).