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Safety Data Sheet EN

103HDII

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
103HDII
Product Form
Mixture
Product Code
37740

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Motor oil.

Manufacturers & Suppliers

T

TOTAL BELGIUM

distributor

Handelsstraat, 93, Rue du Commerce B-1040 BRUSSEL - BRUXELLES België - Belgique

+32 (0)22 889 933

T

TOTAL LUBRIFIANTS

manufacturer

562 Avenue du Parc de L'ile 92029 Nanterre Cedex FRANCE

+33 (0)1 41 35 40 00

Emergency Contacts

Emergency Contact

+44 1235 239670

Teleserv S.O.S Total Belgium

+32 (0)78 15 51 51

On duty staff in Ertvelde (Lub)

+32 (0)475 66 07 77

Bruxelles - (NOH) - Brussel, Hopital Militaire Reine Astrid - Militair Hospitaal Koningin Astrid

+32 (0)2 264 48 48

Antwerpen - Anvers, Algemeen centrum Ziekenhuis

+32 (0)3 217 71 11

Gent - Gand, Centre Universitaire UZ Gand-Universitair Ziekenhuis UZ Gent

+32 (0)9 240 34 90

Leuven - Louvain, U.Z. Leuven

+32 (0)16 34 87 50

Loverval, Hôpital Saint Joseph et Sainte Thérèse, section I.M.T.R

+32 (0)71 44 80 00

Luik - Liège, CHU Liège domaine Universitaire du Sart Tilman

+32 (0)4 366 72 94

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Distillates (petroleum), hydrotreated heavy paraffinic EC: 265-157-1 64742-54-7 30 - 40% Yes
Distillates (petroleum), hydrotreated light paraffinic EC: 265-158-7 64742-55-8 3 - 5% Yes
Benzenepropanoic acid, 3,5-bis(1,1-dimethyl-ethyl)-4-hydroxy-C7-C9 branched alkyl ester EC: 406-040-9 125643-61-0 1 - 2.5% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts EC: 283-392-8 84605-29-8 1 - 2.5% Yes
Benzene, sulfonic acid, mono-C16-24-alkyl derivatives, calcium salts EC: 274-263-7 70024-69-0 0.1 - 1% Yes
O,O,O-triphenyl phosphorothioate EC: 209-909-9 597-82-0 0.1 - 0.3% Yes
Tetrapropenyl phenol EC: 310-154-3 121158-58-5 0.025 - 0.1% Yes

Product containing mineral oil with less than 3% DMSO extract as measured by IP 346.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casualty to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration.

Symptoms: Inhalation of vapours in high concentration may cause irritation of respiratory system.

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash contaminated clothing before reuse.

Symptoms: Not classified based on available data. May produce an allergic reaction.

Eye contact

Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing.

Symptoms: Not classified based on available data. The supplier of some components contained within this formulation has indicated that the classification as irritant is not required.

Ingestion

Clean mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or poison control centre immediately.

Symptoms: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Immediate Medical Attention

Call a physician or poison control centre immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly dangerous if inhaled in confined spaces or at high concentration. Combustion products include sulphur oxides ( SO2 and SO3 ) and Hydrogen sulphide H2S. Phosphorous oxides. Nitrogen oxides (NOx). Mercaptans. Zinc oxides.

Instructions

Cool containers / tanks with water spray.

Firefighter Protection

Wear self-contained breathing apparatus and protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch or walk through spilled material. Contaminated surfaces will be extremely slippery.

Environmental

Do not allow material to contaminate ground water system. Prevent entry into waterways, sewers, basements or confined areas.

Cleanup methods

Dispose of contents/container in accordance with local regulation.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing.

Storage

Store at room temperature. Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep container tightly closed. Preferably keep in the original container. Otherwise, reproduce all the statutory information from the labels onto the new container. Do not remove the hazard labels of the containers (even if they are empty).

Hygiene

Ensure the application of strict rules of hygiene by the personnel exposed to the risk of contact with the product. When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Regular cleaning of equipment, work area and clothing is recommended. Do not use abrasives, solvents or fuels. Do not dry hands with rags that have been contaminated with product. Do not put product contaminated rags into workwear pockets.

Fire prevention

Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Apply technical measures to comply with the occupational exposure limits. Ensure adequate ventilation, especially in confined areas. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.

Hands

Hydrocarbon-proof gloves. Fluorinated rubber. Nitrile rubber. In case of prolonged contact with the product, it is recommended to wear gloves complying with EN 420 and EN 374 standards, protecting at least for 480 minutes and having a thickness of 0,38 mm at least. These values are indicative only. The level of protection is provided by the material of the glove, its technical characteristics, its resistance to the chemicals to be handled, the appropriateness of its use and its replacement frequency. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.

Eyes

If splashes are likely to occur, wear:. Safety glasses with side-shields. EN 166.

Respiratory

None under normal use conditions. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN 14387). Type A/P1. Warning ! filters have a limited use duration. The use of breathing apparatus must comply strictly with the manufacturer's instructions and the regulations governing their choices and uses.

Skin/Body

Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing. Type 4/6.

Environmental

The product should not be allowed to enter drains, water courses or the soil.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear
Colour
yellow to amber
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
No information available
Ph
Not applicable
Melting Point
No information available
Boiling Point
No information available
Flash Point
> 220 °C Cleveland Open Cup (COC)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
No information available
Vapor Density
No information available
Relative Density
0.854 - 0.874 @ 15 °C
Bulk Density
---
Density
854 - 874 kg/m3 @ 15 °C
Flammability
---
Upper Explosive Limit
No information available
Lower Explosive Limit
No information available
Explosive Limits
---
Auto Ignition Temperature
No information available
Decomposition Temperature
No information available
Solubility
---
Partition Coefficient
No information available
Solubility In Water
Insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
78 mm2/s @ 40 °C ISO 3104
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

None under normal processing.

Hazardous reactions

No dangerous reaction known under conditions of normal use.

Avoid

Keep away from open flames, hot surfaces and sources of ignition. Keep away from heat and sparks.

Incompatible

Strong oxidising agents.

Decomposition

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. Phosphorous oxides. Nitrogen oxides (NOx). Mercaptans. Combustion products include sulphur oxides ( SO2 and SO3 ) and Hydrogen sulphide H2S. Zinc oxides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.2. Persistence and Degradability

General Information No information available.

12.3. Bioaccumulative potential

Product Information No information available. logPow No information available Component Information . Chemical Name | log Pow

12.1. Toxicity

Not classified based on available data. This product contains one or more components that have a branched alkylphenol impurity which is very toxic to aquatic life (disclosed in section 3). Components containing the impurity have been tested and are not toxic to aquatic life. Therefore, the data in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity. #### **Acute aquatic toxicity - Product Information** No information available. #### **Acute aquatic toxicity - Component Information** |**Chemical Name**|**Toxicity to algae**|**Toxicity to daphnia and** **other aquatic** **invertebrates.**|**Toxicity to fish**|**Toxicity to** **microorganisms**| |---|---|---|---|---|

The product is not classified as toxic to aquatic life based on testing of components, despite the presence of a branched alkylphenol impurity.

12.1 Toxicity

Chemical Name: Distillates (petroleum), hydrotreated heavy paraffinic 64742-54-7. Toxicity to algae: EL50 (48h) > 100 mg/l (Pseudokirchnerella subcapitata - OECD 201). Toxicity to daphnia and other aquatic invertebrates: EL50 (48h) > 10000 mg/l (Daphnia magna - OECD 202). Toxicity to fish: LL50 (96h) > 100 mg/l (Oncorhynchus mykiss - OECD 203).

12.1 Toxicity

Distillates(petroleum), hydrotreated light paraffinic 64742-55-8: EL50(72h)> 100 mg/l (Pseudokirchneriella subcapitata-OCDE 201); EL50(48h)> 10000 mg/L (Daphnia magna - OCDE 202); LL50(96h)> 100 mg/L (Oncorhynchus mykiss - OCDE 203)

12.1 Toxicity

Benzenepropanoicacid, 3,5-bis (1,1-dimethyl-ethyl)-4-hydroxy-C7-C9 branched alkyl ester 125643-61-0: EC50 (72 h) > 3 mg/l Scenedesmus (OECD201); EC50 (24 h) > 100 mg/l Daphnia magna (OECD 202); LC50 (96 h) > 74 mg/l Brachydanio rerio (OECD 203)

12.1 Toxicity

Toxicity to algae: ErC50 (72h) 24 mg/l (Desmodesmus subspicatus - OECD 201); Toxicity to daphnia and other aquatic invertebrates: EL50 (48h) 23 mg/l (Daphnia magna - OECD 202); Toxicity to fish: LL50 (96h) 4.5 mg/l (Oncorhynchus mykiss - OECD 203)

12.1 Toxicity

Benzene, sulfonic acid, mono-C16-24-alkyl derivatives, calcium salts 70024-69-0: EC50 (72h) > 1000 mg/l (Pseudokirchnerella subcapitata - static); EC50 (48h) > 1000 mg/l (WAF - Daphnia magna - static); LL50 (96h) > 10000mg/l (WAF - Cyprinodon variegatus - OECD 203)

12.1 Toxicity

EC50(72h) >100 mg/l (Scenedesmus quadricauda); EC50(48h) >100 mg/l (Daphnia Magna); LC50(96h) >100 mg/l (Zebra Fish); EC50(3h) >100 mg/l (sludge)

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

EbC50 (72h) 0.15 mg/l (Scenedesmus subspicatus - OECD 201); EC50(48h) 0.037 mg/l (Daphnia magna - static - OECD 202); EL50(96h) 40 mg/l Pimephales promelas semi-static (OECD 203)

12.1 Toxicity

Distillates (petroleum), hydrotreated heavy paraffinic 64742-54-7: NOEL (21d) 10 mg/l (Daphnia magna - QSAR Petrotox); NOEL (14/28d) > 1000 mg/l (Oncorhynchus mykiss - QSAR Petrotox)

12.1 Toxicity

Chemical Name | Toxicity to algae | Toxicity to daphnia and other aquatic invertebrates. | Toxicity to fish | Toxicity to microorganisms Distillates (petroleum), hydrotreated light paraffinic 64742-55-8 | | NOEL (21d) 10 mg/l (Daphnia magna - OCDE 211) | NOEL (14/28d) >1000 mg/l (Oncorhynchus mykiss - QSAR Petrotox) |

12.1 Toxicity

NOEC (21d) <= 0.01 mg/l Daphnia magna semi static (OECD 211)

12.1 Toxicity

NOEC(21d) >5.5 mg/l (Daphnia Magna)

12.1 Toxicity

Tetrapropenyl phenol 121158-58-5: NOEC(21d) 0.0037 mg/l (Daphnia magna - semi-static-OECD 211)

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.3 Bioaccumulative potential

|**Chemical Name**|**log Pow**| |Distillates (petroleum),hydrotreatedheavy paraffinic-64742-54-7|-|

12.3 Bioaccumulative potential

Benzenepropanoicacid, 3,5-bis (1,1-dimethyl-ethyl)-4-hydroxy-C7-C9 branched alkylester - 125643-61-0 log Pow: 9.2

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

log Pow: 0.56

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

Tetrapropenylphenol - 121158-58-5 log Pow: 7.14

12.4. Mobility insoil

Soil Given its physical and chemical characteristics, the product generally shows low soil mobility. Air Loss by evaporation is limited. Water The product is insoluble and floats on water.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment No information available.

No information available.

12.6. Other adverse effects

General Information No information available.

No information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations. Where possible recycling is preferred to disposal or incineration.

Disposal

Should not be released into the environment. Do not empty into drains.

Waste Codes

13 02 05 According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

European Union

Chemical Safety Assessment Not performed

No information available

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 103HDII?

The signal word is no signal word.

What is the physical form of 103HDII?

103HDII is a liquid appearing as clear with yellow to amber color. It has characteristic odor.

What is 103HDII used for?

Motor oil.

What is the melting point of 103HDII?

The melting point is No information available and the boiling point is No information available.