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Safety Data Sheet EN

NYTRO® GEMINI X

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
NYTRO® GEMINI X
Product Form
Liquid

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Distribution of substance - Industrial Formulation and (re)packing of substances and mixtures - Industrial Use in functional fluids - Industrial Use in functional fluids - Professional Lubrication at high energy conditions in metal working operations - Industrial Lubrication at high energy conditions in metal working operations - Professional

Uses advised against

This product must not be used in applications other than those recommended in Section 1, without first seeking the advice of the supplier.

Manufacturers & Suppliers

Nynas AB logo

Nynas AB

manufacturer

P.O. Box 10700 SE-121 29 Stockholm SWEDEN

+46 8 602 12 00

http://www.nynas.com

N

Nynas NV

national supplier

Pegasuslaan 5 1831 Diegem BELGIUM

Emergency Contacts

Emergency Contact

+44 (0) 1235 239 670

24 hour service

Belgian Poison Centre

070 245 245

24 hour service

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS08 - Serious health hazard

GHS08

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P301 IF SWALLOWED:
P310 Immediately call a POISON CENTER or physician.
P331 Do NOT induce vomiting.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Distillates (petroleum), hydrotreated light naphthenic EC: 265-156-6 64742-53-6 50 - 100% Yes
Distillates (petroleum), hydrotreated light paraffinic EC: 265-158-7 64742-55-8 50% Yes
Distillates (petroleum), hydrotreated heavy paraffinic EC: 265-157-1 64742-54-7 50% Yes
2,6-di-tert-butyl-p-cresol EC: 204-881-4 128-37-0 0.4% Yes

Regulation (EC) No. 1272/2008 [CLP] Annex VI Nota L applies to the base oil(s) in this product. Nota L - The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If casualty is unconscious and: If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Maintain an open airway.

Symptoms: difficulty breathing

Skin contact

Wash with soap and water. Remove contaminated clothing and shoes. Handle with care and dispose of in a safe manner.

Symptoms: skin irritation, swelling or redness

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: irritation, blurred vision or swelling

Ingestion

Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: aspiration

Immediate Medical Attention

Accidental high pressure injection through the skin requires immediate medical attention. Do not wait for symptoms to develop. Seek professional medical attention or send the casualty to a hospital. If unconscious, place in recovery position and get medical attention immediately.

Medical Treatment

Due to low viscosity there is a risk of aspiration if the product enters the lungs. Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical,CO₂,water spray (fog) or foam.

Unsuitable media

Do not use direct water jets on the burning product; they could cause splattering and spread the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst. This substance will float and can be reignited on surface water.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid breathing vapour or mist. Keep non-involved personnel away from the area of spillage. Alert emergency personnel. Except in case of small spillages, the feasibility of any actions should always be assessed and advised, if possible, by a trained, competent person in charge of managing the emergency. Stop leak if safe to do so. Avoid direct contact with the product. Stay upwind/keep distance from source. In case of large spillages, alert occupants in downwind areas.

Small spill

Normal antistatic working clothes are usually adequate.

Large spill

Alert occupants in downwind areas. Full body suit of chemically resistant and thermal resistant material should be used.

Environmental

Water polluting material. May be harmful to the environment if released in large quantities. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Cleanup methods

Collect spilled product by absorbing with specific floating absorbents. Collect the product by skimming or other suitable mechanical means.

Materials: specific floating absorbents

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Prevent the risk of slipping. Take precautionary measures against static discharge. Avoid splash filling of bulk volumes when handling hot liquid product. Empty containers retain product residue and can be hazardous.

Storage

Storage area layout, tank design, equipment and operating procedures must comply with the relevant regional, national or local legislation. Storage installations should be designed with adequate bunds in case of leaks or spills. Cleaning, inspection and maintenance of internal structure of storage tanks must be done only by properly equipped and qualified personnel as defined by national, local or company regulations. Store locked up. Protect from sunlight.

Hygiene

Ensure that proper housekeeping measures are in place. Contaminated materials should not be allowed to accumulate in the workplaces and should never be kept inside the pockets. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash hands thoroughly after handling. Change contaminated clothes at the end of working shift.

Fire prevention

Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Mechanical ventilation and local exhaust will reduce exposure via the air. Use oil resistant material in construction of handling equipment. Store under recommended conditions and if heated, temperature control equipment should be used to avoid overheating.

Hands

4 - 8 hours (breakthrough time): nitrile rubber

Eyes

Recommended: Safety glasses with side shields.

Respiratory

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary.

Skin/Body

Wear protective clothing if there is a risk of skin contact. Change contaminated clothes at the end of working shift. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Light yellow
Colour Intensity
---
Form
---
Odor
Odourless/Light petroleum.
Odor Threshold
Not applicable.
Ph
Not applicable.
Melting Point
-51°C
Boiling Point
>250°C
Flash Point
Closed cup: >140°C [Pensky-Martens.]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
<0,01 kPa [room temperature]
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,87 g/cm³ [15°C]
Flammability
Not available.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
>270°C
Decomposition Temperature
>280°C
Solubility
---
Partition Coefficient
Not available.
Solubility In Water
Insoluble in water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): 0,09 cm²/s (9 cSt)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Oxidising agent.

Incompatible

Keep away from extreme heat and oxidizing agents.

Decomposition

Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates, gases, including carbon monoxide, H2S, SOx (sulfur oxides) or sulfuric acid and unidentified organic and inorganic compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product/ingredient name: Distillates (petroleum), hydrotreated light naphthenic Result: Acute LL50 >10000 mg/l, Acute LL50 >100 mg/l, Acute NOEL >100 mg/l Species: Aquatic invertebrates., Fish, Algae Exposure: 96 hours, 96 hours, 72 hours

12.1 Toxicity

|12.1 Toxicity||||| |**Product/ingredient name**|**Result**||**Species**|**Exposure**| |Distillates (petroleum), hydrotreated light paraffinic|Chronic NOEL 10 mg/l Acute IC50 >100 mg/l||Aquatic invertebrates. Algae|21 days 48 hours|

12.1 Toxicity

Acute LC50 >100 mg/l Fish 96 hours; Acute LL50 >10000 mg/l Aquatic invertebrates 96 hours; Acute LL50 >100 mg/l Fish 96 hours; Acute NOEL >100 mg/l Algae 72 hours; Chronic NOEL 10 mg/l Aquatic invertebrates 21 days

12.1 Toxicity

Product/ingredient name: Distillates (petroleum), hydrotreated heavy paraffinic Result: Acute EL50 >10000 mg/l, Species: Aquatic invertebrates, Exposure: 96 hours Result: Acute LL50 >100 mg/l, Species: Fish, Exposure: 96 hours Result: Acute NOEL >100 mg/l, Species: Algae, Exposure: 72 hours Result: Chronic NOEL 10 mg/l, Species: Aquatic invertebrates, Exposure: 21 days

12.1 Toxicity

Product/ingredient name: 2,6-di-tert-butyl-p-cresol. Acute EC50 0,61 mg/l (Daphnia - Magna, 48 hours). Acute IC50 >0,4 mg/l (Algae - Desmodesmus Subspicatus, 72 hours). Chronic NOEC 0,316 mg/l (Daphnia - Magna, 21 days). Conclusion/Summary: Harmful to aquatic life with long lasting effects.

Harmful to aquatic life with long lasting effects.

12.2 Persistence and degradability

Product/ingredient name: 2,6-di-tert-butyl-p-cresol. Test: OECD 301C 301C Ready Biodegradability - Modified MITI Test (I). Result: 4,5 % - 28 days.

12.2 Persistence and degradability

|**Product/ingredient name**|**Aquatic half-life**||**Photolysis**||**Biodegradability**| |Distillates (petroleum), hydrotreated light naphthenic

12.2 Persistence and degradability

|**Product/ingredient name**|**Aquatic half-life**||**Photolysis**||**Biodegradability**| Distillates (petroleum), hydrotreated light paraffinic

12.2 Persistence and degradability

|**Product/ingredient name**|**Aquatic half-life**||**Photolysis**||**Biodegradability**| Distillates (petroleum), hydrotreated heavy paraffinic

12.2 Persistence and degradability

|**Product/ingredient name**|**Aquatic half-life**||**Photolysis**||**Biodegradability**| 2,6-di-tert-butyl-p-cresol|-

12.2 Persistence and degradability

Inherent Inherent Inherent Not readily | Conclusion/Summary Inherently biodegradable.

Inherently biodegradable.

12.3 Bioaccumulative potential

|**Product/ingredient name**|**LogPow**|**BCF**|**Potential**|

12.3 Bioaccumulative potential

|**Product/ingredient name**|**LogPow**|**BCF**|**Potential**| |Distillates (petroleum), hydrotreated light naphthenic|

12.3 Bioaccumulative potential

|**Product/ingredient name**|**LogPow**|**BCF**|**Potential**| Distillates (petroleum), hydrotreated light paraffinic

12.3 Bioaccumulative potential

|**Product/ingredient name**|**LogPow**|**BCF**|**Potential**| Distillates (petroleum), hydrotreated heavy paraffinic|2 to 6

12.3 Bioaccumulative potential

|**Product/ingredient name**|**LogPow**|**BCF**|**Potential**| |2,6-di-tert-butyl-p-cresol|5,1|>500|high|

12.4 Mobility in soil

Mobility High mobility in soil predicted, based on log Kow > 3.0.

12.5 Results of PBT and vPvB assessment

Not applicable. Not applicable.

12.6 Other adverse effects

Insoluble in water. Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Where possible (e.g. in the absence of relevant contamination), recycling of used substance is feasible and recommended. This substance can be burned or incinerated, subject to national/local authorizations, relevant contamination limits, safety regulations and air quality legislation. Contaminated or waste substance (not directly recyclable): Disposal can be carried out directly, or by delivery to qualified waste handlers.

Disposal

Disposal can be carried out directly, or by delivery to qualified waste handlers.

Waste Codes

13 03 07* mineral-based non-chlorinated insulating and heat transmission oils EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

ADR

always transport in closed containers that are user upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

always transport in closed containers that are user upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

always transport in closed containers that are user upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for NYTRO® GEMINI X?

The signal word is danger.

What is the physical form of NYTRO® GEMINI X?

NYTRO® GEMINI X is a liquid. with light yellow color. It has odourless/light petroleum. odor.

What is NYTRO® GEMINI X used for?

Distribution of substance - Industrial Formulation and (re)packing of substances and mixtures - Industrial Use in functional fluids - Industrial Use in functional fluids - Professional Lubrication at high energy conditions in metal working operations - Industrial Lubrication at high energy conditions in metal working operations - Professional

What are the hazard statements for NYTRO® GEMINI X?

This substance has 2 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of NYTRO® GEMINI X?

The melting point is -51°C and the boiling point is >250°C.