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Safety Data Sheet EN

ULTRAZOL® 9012FM

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ULTRAZOL® 9012FM

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Gasoline additive

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Carc. Cat. 2 H351
STOT SE Cat. 3 H335
STOT SE Cat. 3 H336
Asp. Tox. Cat. 1 H304
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER/doctor if you feel unwell.
P331 Do NOT induce vomiting.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hydrocarbons, C10, aromatics, >1% naphthalene EC: 919-284-0 --- 25 - 50% Yes
2-Ethylhexan-1-ol EC: 203-234-3 --- 20 - 50% Yes
Phenol, (dimethylamino)methyl-, polyisobutylene derivs. --- 10 - 25% Yes
2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol EC: 620-540-6 --- 5 - 10% Yes
Benzene, 1,2,4-trimethyl- EC: 202-436-9 --- 2.5 - 5% Yes
Naphthalene EC: 202-049-5 --- 2.5 - 5% Yes
1,3,5-trimethylbenzene EC: 203-604-4 --- 1 - 2.5% Yes
1,2,3-Trimethylbenzene EC: 208-394-8 --- 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air and keep at rest in a position comfortable for breathing.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. If skin irritation occurs, get medical attention. Launder contaminated clothing before reuse.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion

Do NOT induce vomiting. If vomiting occurs naturally, the casualty should lean forward to reduce the risk of aspiration. Rinse mouth. Immediately call a POISON CENTER/doctor.

Symptoms: Aspiration of material due to vomiting can cause chemical pneumonitis which can be fatal.

Immediate Medical Attention

Immediately call a POISON CENTER/doctor.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Vapors may cause a flash fire or ignite explosively. Prevent buildup of vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. Material creates a special hazard because it floats on water.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Vapours are heavier than air and will tend to accumulate in low areas. Avoid use in confined areas without adequate ventilation. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin. Avoid contact with eyes. Use personal protective equipment as required.

Storage

Keep cool. Store in a well-ventilated place.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Launder contaminated clothing before reuse.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Electrically bond and ground all containers and equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air. Adequate ventilation should be provided so that exposure limits are not exceeded. Mechanical ventilation or local exhaust ventilation is required.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Viton. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Wear tight-fitting goggles or face shield. Eye protection should meet the standards set out in EN 166.

Respiratory

Use respirator with an organic vapor cartridge if exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Use respirator with a combination organic vapor and dust/mist cartridge. Use respirator if irritation is experienced or if the recommended exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Gloves, coveralls, apron, boots as necessary to minimize contact. Chemical resistant boots. Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Amber to brown
Colour Intensity
---
Form
liquid
Odor
Aromatic hydrocarbons
Odor Threshold
No data available.
Ph
No data available.
Melting Point
---
Boiling Point
No data available.
Flash Point
70 °C (PMCC)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
No data available.
Relative Density
0.883 - 0.923 (15.6 °C)
Bulk Density
---
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Excessive heat. Contact with acids. Strong oxidizing agents. Strong caustic agents. Heat, sparks, flames.

Incompatible

Strong oxidizing agents. Strong acids. Aluminum. Lead and lead alloys Oxidizing agents, Reactive metals, Sodium or Calcium Hypochlorite. Materials reactive with hydroxyl compounds.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

12.1 Ecotoxicity ### Fish Hydrocarbons, C10, aromatics, >1% naphthalene 2-Ethylhexan-1-ol Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- LC 50 (Rainbow Trout, 4 Days): 2 mg/l

12.1 Ecotoxicity

### Fish 2-Ethylhexan-1-ol Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- LC 50 (Rainbow Trout, 4 Days): 2 mg/l LC 50 (Fathead Minnow, 4 d): 28.2 mg/l

12.1 Ecotoxicity

Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- LC 50 (Rainbow Trout, 4 Days): 2 mg/l LC 50 (Fathead Minnow, 4 d): 28.2 mg/l LC 50 (Golden Orfe, 4 d): 17.1 mg/l

12.1 Ecotoxicity

### Fish 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- LC 50 (Rainbow Trout, 4 Days): 2 mg/l LC 50 (Fathead Minnow, 4 d): 28.2 mg/l LC 50 (Golden Orfe, 4 d): 17.1 mg/l NOEC (Golden Orfe, 4 d): 14 mg/l

12.1 Ecotoxicity

Fish ++ Benzene, 1,2,4-trimethyl- LC 50 (Rainbow Trout, 4 Days): 2 mg/l LC 50 (Fathead Minnow, 4 d): 28.2 mg/l LC 50 (Golden Orfe, 4 d): 17.1 mg/l NOEC (Golden Orfe, 4 d): 14 mg/l LC 50 (Fathead Minnow, 4 d): 31 mg/l LC 50 (Zebra Fish, 4 d): 0.1 mg/l LC 50 (Fathead Minnow, 4 Days): 7.72 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Hydrocarbons, C10, aromatics, >1% naphthalene 2-Ethylhexan-1-ol Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- ++ 1,3,5-trimethylbenzene EC 50 (Water flea (Daphnia magna), 2 d): 3 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates 2-Ethylhexan-1-ol Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- ++ 1,3,5-trimethylbenzene EC 50 (Water flea (Daphnia magna), 2 d): 3 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- ++ 1,3,5-trimethylbenzene EC 50 (Water flea (Daphnia magna), 2 d): 3 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l

12.1 Ecotoxicity

12.1 Ecotoxicity ### Aquatic Invertebrates 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ Benzene, 1,2,4-trimethyl- ++ 1,3,5-trimethylbenzene EC 50 (Water flea (Daphnia magna), 2 d): 3 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l EC 50 (Water Flea (Daphnia Magna), 2 d): 0.043 mg/l EC 10 (Water Flea (Daphnia Magna), 21 d): 0.0107 mg/l

12.1 Ecotoxicity

## 12.1 Ecotoxicity ### Aquatic Invertebrates ++ Benzene, 1,2,4-trimethyl- ++ 1,3,5-trimethylbenzene EC 50 (Water flea (Daphnia magna), 2 d): 3 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l EC 50 (Water Flea (Daphnia Magna), 2 d): 0.043 mg/l EC 10 (Water Flea (Daphnia Magna), 21 d): 0.0107 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 3.6 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates ++ 1,3,5-trimethylbenzene EC 50 (Water flea (Daphnia magna), 2 d): 3 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 39 mg/l EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l EC 50 (Water Flea (Daphnia Magna), 2 d): 0.043 mg/l EC 10 (Water Flea (Daphnia Magna), 21 d): 0.0107 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 3.6 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 6 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Hydrocarbons, C10, aromatics, >1% naphthalene 2-Ethylhexan-1-ol Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ 1,3,5-trimethylbenzene EC 50 (Green algae (Selenastrum capricornutum), 4 d): 1.1 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants 2-Ethylhexan-1-ol Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ 1,3,5-trimethylbenzene EC 50 (Green algae (Selenastrum capricornutum), 4 d): 1.1 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): 16.6 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Phenol, (dimethylamino)methyl-, polyisobutylene derivs. 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ 1,3,5-trimethylbenzene EC 50 (Green algae (Selenastrum capricornutum), 4 d): 1.1 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): 16.6 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): > 450 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol ++ 1,3,5-trimethylbenzene EC 50 (Green algae (Selenastrum capricornutum), 4 d): 1.1 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): 16.6 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): > 450 mg/l EC 50 (Algae (Pseudokirchneriella subcapitata), 3 d): 0.0538 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 3 d): 0.0156 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants ++ 1,3,5-trimethylbenzene EC 50 (Green algae (Selenastrum capricornutum), 4 d): 1.1 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): 16.6 mg/l EC 50 (Green algae (Selenastrum capricornutum), 4 d): > 450 mg/l EC 50 (Algae (Pseudokirchneriella subcapitata), 3 d): 0.0538 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 3 d): 0.0156 mg/l EC 50 (Green algae (Scenedesmus quadricauda), 2 Days): 25 mg/l

Toxicity

2-Ethylhexan-1-ol EC 50 (Pseudomonas putida, 0.1 d): 540 mg/l EC 50 (Sludge, 0.5 d): > 100 mg/l

Toxicity to microorganisms

Phenol, (dimethylamino)methyl-, polyisobutylene derivs. EC 50 (Sludge, 0.1 d): > 1,000 mg/l

Toxicity

2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol EC 50 (Sludge, 3 h): 167 mg/l

12.2 Persistence and Degradability

Biodegradation

12.2 Persistence and Degradability

Biodegradation Hydrocarbons, C10, aromatics, >1% naphthalene Oxygen depletion 58 % (28 d, OECD TG 301 F)

12.2 Persistence and Degradability

## Biodegradation 2-Ethylhexan-1-ol Dissolved organic carbon (DOC) 95 % (5 d, OECD TG 302 B) Oxygen depletion 100 % (14 d, OECD TG 301 C)

12.2 Persistence and Degradability

## Biodegradation Phenol, (dimethylamino)methyl-, polyisobutylene derivs. Dissolved organic carbon (DOC) 20.7 % (28 d, Inherent Sludge)

12.2 Persistence and degradability

## Biodegradation 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol Oxygen depletion 63 % (28 d, OECD TG 301 D)

12.3 Bioaccumulative Potential

## Bioconcentration Factor (BCF) No data available

No data available

12.3 Bioaccumulative Potential

Bioconcentration Factor (BCF) 2-Ethylhexan-1-ol Bioconcentration Factor (BCF): 25.35 (calculated)

12.3 Bioaccumulative Potential

Bioconcentration Factor (BCF) 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol Fish, Bioconcentration Factor (BCF): 110.2 (calculated)

12.3 Bioaccumulative Potential

Partition Coefficient n-octanol / water (log Kow) 2-Ethylhexan-1-ol Log Kow: 2.9 (Measured)

12.3 Bioaccumulative Potential

## Partition Coefficient n-octanol / water (log Kow) 2,2'-(C16-18 (evennumbered, C18 unsaturated) alkyl imino) diethanol Log Kow: 3.6

12.3 Bioaccumulative Potential

## Partition Coefficient n-octanol / water (log Kow) ++ Benzene, 1,2,4-trimethyl- Log Kow: 3.63 (calculated)

12.4 Mobility:

2-Ethylhexan-1-ol soil - 1.42

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other Adverse Effects:

No data available.

No data available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Ethoxylated amine, Naphthalene)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ULTRAZOL® 9012FM?

The signal word is danger.

What is the physical form of ULTRAZOL® 9012FM?

ULTRAZOL® 9012FM is a liquid with amber to brown color. It has aromatic hydrocarbons odor.

What is ULTRAZOL® 9012FM used for?

Gasoline additive

What are the hazard statements for ULTRAZOL® 9012FM?

This substance has 7 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • H410: Very toxic to aquatic life with long lasting effects.