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Safety Data Sheet EN

4-ADPA

CAS 101-54-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4-ADPA
Product Code
P3408603
Chemical Name
4-Aminodiphenylamine

Regulatory Identifiers

CAS Number
101-54-2 Check regulations →
REACH No.
01-2119486402-39-0000

Identified Uses

Chemical intermediate, Monomer

Uses advised against

None known.

Manufacturers & Suppliers

Flexsys Chemicals Belgium NV logo

Flexsys Chemicals Belgium NV

manufacturer

Scheldelaan 460, Haven 627 2040 Antwerpen

http://www.FLEXSYS.com

Emergency Contacts

CHEMTREC

+1 703-741-5970

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust.
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Substance name : 4-Aminodiphenylamine CAS-No. : 101-54-2

Chemical Name CAS Number Concentration Hazardous
N-(4-aminophenyl)aniline EC: 202-951-9 101-54-2 90 - 100% No

Notes

Flexsys is committed to the safety, health and environment of our employees, our customers, and the communities we operate within. As part of this commitment, Flexsys' Safety Data Sheets (SDS) are prepared in accordance with all applicable national and local regulations. The compositions of our documents reflect these requirements which include, but are not limited to, requirements under the Globally Harmonized System of Classification and Labeling (GHS). These compositions commonly involve the use of ranges versus specific analytical values. If you require a composition that is more specific , please refer to the Certificate of Analysis, sales specification, or contact your Customer Service Representative.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air.

Skin contact

Wash off with soap and water. Wash contaminated clothing before re-use. Thoroughly clean shoes before reuse.

Symptoms: Rash, May cause an allergic skin reaction.

Eye contact

Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: Causes eye irritation.

Immediate Medical Attention

If symptoms persist, call a physician. Get medical attention if symptoms occur. If eye irritation persists: Get medical advice/ attention. Seek medical advice.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Dry chemical, Water spray

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire. Do NOT use water jet.

Specific hazards

None known.

Firefighter Protection

Wear an approved positive pressure self-contained breathing for firefighters apparatus in addition to standard fire fighting gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear appropriate personal protective equipment.

Environmental

Avoid release to the environment.

Cleanup methods

Sweep up or vacuum up spillage and collect in suitable container for disposal.

Materials: non-combustible absorbent material (e.g. sand, earth, diatomaceous earth, vermiculite)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing dust. Do not get in eyes. Avoid contact with skin, eyes and clothing. Do not swallow. Ensure adequate ventilation. Wash thoroughly after handling.

Storage

Keep tightly closed.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.

Fire prevention

None known.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation (typically 10 air changes per hour) should be sufficient to control airborne levels. Ensure adequate ventilation.

Hands

Wear suitable gloves.

Eyes

Wear safety glasses with side shields (or goggles). Face-shield Always wear eye protection when the potential for inadvertent eye contact with the product cannot be excluded.

Respiratory

Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
molten
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
dark blue
Colour Intensity
---
Form
---
Odor
aromatic
Odor Threshold
not determined
Ph
8,9
Melting Point
70 - 76 °C
Boiling Point
354 °C (1.013 hPa)
Flash Point
193 °C Method: Tag closed cup
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
not determined
Vapor Pressure
0,0000017 hPa (25 °C)
Vapor Density
---
Relative Density
1,1 (15 °C)
Bulk Density
---
Density
1,09 g/cm3 (20 °C)
Flammability
The product is not flammable.
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
log Pow: 1,82 Method: QSAR model
Solubility In Water
503,8mg/l (20 °C)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
not determined
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None reasonably foreseeable.

Hazardous reactions

None known.

Avoid

None known.

Incompatible

Strong oxidizing agents

Decomposition

Carbon dioxide (CO2) Carbon monoxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish : LC50 (Danio rerio (zebra fish)): 1,17 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0,29 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae/aquatic : ErC50 (Scenedesmus subspicatus): 3,75 mg/l plants Exposure time: 72 h ErC10 (Scenedesmus subspicatus): 1,41 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity): Remarks: No data available Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): NOEC: 0,04 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea)

12.1 Toxicity

N-(4-aminophenyl)aniline: Toxicity to fish: LC50 (Danio rerio (zebra fish)): 1,17 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 0,29 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants: ErC50 (Scenedesmus subspicatus): 3,75 mg/l Exposure time: 72 h ErC10 (Scenedesmus subspicatus): 1,41 mg/l Exposure time: 72 h M-Factor (Acute aquatic tox- icity): 1 Toxicity to fish (Chronic tox- icity): NOEC: Remarks: No data available Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity): NOEC: 0,04 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) M-Factor (Chronic aquatic toxicity): 1

12.2 Persistence and degradability

Product: Biodegradability : Remarks: Inherently biodegradable Biochemical Oxygen De: Remarks: No data available mand (BOD) Chemical Oxygen Demand : Remarks: No data available (COD)

The product is inherently biodegradable. Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) data are not available.

12.2 Persistence and degradability

N-(4-aminophenyl)aniline: Biodegradability : Remarks: Inherently biodegradable Biochemical Oxygen De: Remarks: No data available Chem (COD) ical Oxygen Demand : Remarks: No data available

12.3 Bioaccumulative potential

N-(4-aminophenyl)aniline: Bioaccumulation : Bioconcentration factor (BCF): 7 Method: calculated Remarks: Does not accumulate in organisms. Partition coefficient: n-octanol/water : log Pow: 1,82 Method: QSAR model

12.4 Mobility in soil

Distribution among environ: log Koc: 2,72 mental compartments Method: Estimation of the Adsorption Coefficient (Koc) on Soil and on Sewage Sludge using High Performance Liquid Chromatography (HPLC) Components: N-(4-aminophenyl)aniline: Distribution among environ: log Koc: 2,72 mental compartments Method: Estimation of the Adsorption Coefficient (Koc) on Soil and on Sewage Sludge using High Performance Liquid Chromatography (HPLC)

12.5 Results of PBT and vPvB assessment

Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Product: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Components: N-(4-aminophenyl)aniline: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with local regulations.

Disposal

Dispose of in accordance with local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3257
Shipping Name
ELEVATED TEMPERATURE LIQUID, N.O.S. (4-Aminodiphenylamine)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 4-ADPA?

The signal word is warning.

What is the physical form of 4-ADPA?

4-ADPA is a molten with dark blue color. It has aromatic odor.

What is 4-ADPA used for?

Chemical intermediate, Monomer

What are the hazard statements for 4-ADPA?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of 4-ADPA?

The melting point is 70 - 76 °C and the boiling point is 354 °C (1.013 hPa).