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Safety Data Sheet EN

Frostox® HT12

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Frostox® HT12
Product Code
10330

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Radiator anti-freeze

Manufacturers & Suppliers

H

HAERTOL Chemie GmbH

manufacturer

Havelstr. 21 39126 Magdeburg

+49 391 2800 231

Emergency Contacts

Emergency Contact

+49 6132 / 84463

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
STOT RE Cat. 2 H373

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P314 Get medical advice/ attention if you feel unwell.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethylene glycol EC: 203-473-3 107-21-1 90 - 100% Yes
Disodium sebacate EC: 241-300-3 17265-14-4 1 - 10% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air. Get medical attention if symptoms occur.

Skin contact

Wash with water and soap as a precaution. Get medical attention if symptoms occur.

Eye contact

Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.

Ingestion

If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Get medical attention. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person.

Symptoms: Harmful if swallowed.

Immediate Medical Attention

Get medical attention if symptoms occur or if irritation develops and persists.

Medical Treatment

Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, Alcohol-resistant foam, Carbon dioxide (CO2), Dry chemical

Unsuitable media

None known.

Specific hazards

Exposure to combustion products may be a hazard to health.

Instructions

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations.

Large spill

For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container.

Environmental

Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Soak up with inert absorbent material. Clean up remaining materials from spill with suitable absorbent.

Materials: inert absorbent material, suitable absorbent

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid inhalation of vapour or mist. Do not swallow. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment

Storage

Keep in properly labelled containers. Store in accordance with the particular national regulations. Keep in a dry place.

Hygiene

Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.

Hands

Material: butyl-rubber, Break through time: > 30 min, Glove thickness: 0,7 mm, Directive: DIN EN 374, Protective index: Class 2; Material: Nitrile rubber, Break through time: > 30 min, Glove thickness: 0,4 mm, Directive: DIN EN 374, Protective index: Class 2. Remarks: Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer.

Eyes

Wear the following personal protective equipment: Safety glasses Equipment should conform to DIN EN 166

Respiratory

Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Filter type: Combined particulates and organic vapour type (A-P)

Skin/Body

Skin should be washed after contact.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
customer specific
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
No data available
Ph
8,4
Melting Point
No data available
Boiling Point
> 170 °C Method: ASTM D 1120-72
Flash Point
> 110 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
0,2 hPa (20 °C)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,125 g/cm3 (20 °C)
Flammability
Not applicable
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
Not applicable
Solubility In Water
in all proportions
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
20 - 30 mm2/s (20 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Not classified as a reactivity hazard.

Hazardous reactions

Can react with strong oxidizing agents.

Avoid

None known.

Incompatible

Oxidizing agents

Decomposition

No hazardous decomposition products are known.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Ethylene glycol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 72.860 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l aquatic invertebrates Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): 6.500 - 13.000 mg/l Exposure time: 96 h Toxicity to fish (Chronic tox: NOEC: 15.380 mg/l Exposure time: 7 d Species: Pimephales promelas (fathead minnow) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): NOEC: 8.590 mg/l Exposure time: 7 d Species: Ceriodaphnia dubia (water flea)

12.1 Toxicity

Disodium sebacate: Toxicity to fish: LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates: EL50 (Acartia tonsa): > 10 - 100 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Method: ISO 14669 and PARCOM method Remarks: Based on data from similar materials Toxicity to algae/aquatic plants: NOELR (Skeletonema costatum (marine diatom)): > 1 - 10 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Method: ISO 10253 Remarks: Based on data from similar materials EL50 (Skeletonema costatum (marine diatom)): > 10 - 100 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Method: ISO 10253 Remarks: Based on data from similar materials

12.2 Persistence and degradability

Components:

12.2 Persistence and degradability

Biodegradability: Result: Readily biodegradable. Biodegradation: 90 - 100 % Exposure time: 10 d Method: OECD Test Guideline 301A

12.2 Persistence and degradability

Biodegradability: Result: Readily biodegradable. Biodegradation: 89 % Exposure time: 28 d Method: OECD Test Guideline 306

12.3 Bioaccumulative potential

|**Components:**|| |**Ethylene glycol:**|| |Bioaccumulation|: Species: Leuciscus idus (Golden orfe) Bioconcentration factor (BCF): 10| |Partition coefficient: n- octanol/water|: log Pow: -1,93|

12.3 Bioaccumulative potential

|**Components:**|| |**Disodium sebacate:**|| |Partition coefficient: n- octanol/water|: log Pow: -4,9|

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

Not relevant

12.6 Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with local regulations.

Disposal

According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Take note of Law on the protection of mothers at work, in education and in studies (Maternity Protection Act - MuSchG). Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Frostox® HT12?

The signal word is warning.

What is the physical form of Frostox® HT12?

Frostox® HT12 is a liquid appearing as liquid with customer specific color. It has characteristic odor.

What is Frostox® HT12 used for?

Radiator anti-freeze

What are the hazard statements for Frostox® HT12?

This substance has 2 hazard statements:

  • H302: Harmful if swallowed.
  • H373: May cause damage to organs through prolonged or repeated exposure.

What is the melting point of Frostox® HT12?

The melting point is No data available and the boiling point is > 170 °C Method: ASTM D 1120-72.