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Safety Data Sheet EN

ethylene glycol

CAS 107-21-1
EC 203-473-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ethylene glycol
Product Code
50361
Chemical Name
ethylene glycol
Synonyms
1,2-ethanediol; ethane-1,2-diol; ethanediol; glycol; MEG

Regulatory Identifiers

CAS Number
107-21-1 Check regulations →
EC Number
203-473-3 Check regulations →
REACH No.
01-2119456816-28-0026

Identified Uses

ES01 Manufacture of substance ES02 Distribution of substance ES03 Use as an intermediate ES04 Use as process chemical ES05 Formulation & (re)packing of substances and mixtures ES06 Production of polymers ES07 Use in coatings ES08 Use in coatings ES09 Use in coatings ES10 Use in Cleaning Agents ES11 Use in Cleaning Agents ES12 Use in Cleaning Agents ES13 Lubricants ES14 Metal working fluids/rolling oils ES15 Metal working fluids/rolling oils ES16 Use in agrochemicals ES17 Functional Fluids ES18 Functional Fluids ES19 Functional Fluids ES20 Use in/as de-icing/anti-icing applications/agents ES21 Use in/as de-icing/anti-icing applications/agents ES22 Use in laboratories ES23 Water treatment ES24 Use in adhesives and sealants ES25 Production of polymers, filled polymers, foams, coatings, adhesives, sealants ES26 Production of polymers ES27 Use in agrochemicals ES28 Water treatment ES29 Use in oil field drilling and production operations

Uses advised against

Consumer: PC 29

Manufacturers & Suppliers

I

INEOS N.V.

global supplier

Haven 1053 - Nieuwe Weg 1, B-2070 Zwijndrecht

+32 3 250 91 11

I

INEOS N.V.

manufacturer

Haven 1053 - Nieuwe Weg 1, B-2070 Zwijndrecht

+32 3 250 91 11

I

INEOS Chemicals Lavera SAS

manufacturer

Avenue de la bienfaisance BP6, FR-13117 Lavera

+33 4 42 35 80 00

I

INEOS Manufacturing Deutschland GmbH

manufacturer

Alte Strasse 201, D-50769 Köln

+49 221 35 55 22 22

Emergency Contacts

BIG

+32 14 58 45 45

24h/24h

EN, FR, DE, NL

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
STOT RE Cat. 2 H373

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H373 May cause damage to organs (kidneys) through prolonged or repeated exposure if swallowed.

Precautionary Statements

P260 Do not breathe vapours/mist.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P330 Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
ethanediol EC: 203-473-3 107-21-1 99.5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Symptoms: Irritation of the respiratory tract. Dry/sore throat. Irritation of the nasal mucous membranes.

Skin contact

Rinse with water. Soap may be used. Remove clothing before washing. Take victim to a doctor if irritation persists.

Eye contact

Rinse with water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. Take victim to a doctor/medical service if irritation persists.

Symptoms: ON CONTINUOUS EXPOSURE/CONTACT: Irritation of the eye tissue. Redness of the eye tissue. Lacrimation.

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Victim is fully conscious: immediately induce vomiting. Induce vomiting by giving a 0.9 % saline solution. Give activated charcoal. Consult a doctor/medical service if you feel unwell.

Symptoms: AFTER INGESTION OF HIGH QUANTITIES: Feeling of weakness. Central nervous system depression. Body temperature fall. Body temperature rise. Gastrointestinal complaints. Difficulty in swallowing. Headache. Dizziness. Narcosis. Drunkenness. Disturbed tactile sensibility. Disturbed motor response. Visual disturbances. Disturbances of consciousness. Brain affection. Accelerated heart action. Low arterial pressure. Change in the haemogramme/blood composition. Rapid respiration. Cramps/uncontrolled muscular contractions.

Immediate Medical Attention

Depending on the victim's condition: doctor/hospital. Respiratory problems: consult a doctor/medical service. Take victim to a doctor if irritation persists. Take victim to an ophthalmologist if irritation persists. Take victim to a doctor/medical service if irritation persists. Consult a doctor/medical service if you feel unwell.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray. Polyvalent foam. Alcohol-resistant foam. BC powder. Carbon dioxide.

Unsuitable media

Container may slop over if solid jet (water/foam) is applied.

Specific hazards

Upon combustion: CO and CO2 are formed. Reacts on exposure to temperature rise with (some) bases. Reacts on exposure to water and heat with (some) metals.

Instructions

Cool tanks/drums with water spray/remove them into safety.

Firefighter Protection

Gloves. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. Heat/fire exposure: compressed air/oxygen apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Contain released product, pump into suitable containers. Plug the leak, cut off the supply.

Cleanup methods

Scoop absorbed substance into closing containers. Clean contaminated surfaces with an excess of water.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use earthed equipment. Keep away from naked flames/heat. Finely divided: spark- and explosionproof appliances. Finely divided: keep away from ignition sources/sparks. Gas/vapour heavier than air at 20°C. Observe normal hygiene standards. Keep container tightly closed. Remove contaminated clothing immediately.

Storage

Keep container tightly closed.

Hygiene

Observe normal hygiene standards. Remove contaminated clothing immediately.

Fire prevention

Keep away from naked flames/heat. Keep away from ignition sources/sparks.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use earthed equipment. Keep away from naked flames/heat. Finely divided: spark- and explosionproof appliances. Finely divided: keep away from ignition sources/sparks. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection.

Hands

Gloves. - materials (excellent resistance) Butyl rubber, natural rubber, neoprene, nitrile rubber, polyethylene, PVC, tetrafluoroethylene, viton, polyethylene/ethylenevinylalcohol, chlorinated polyethylene, polyurethane, PVA.

Eyes

Safety glasses.

Respiratory

Wear gas mask with filter type A if conc. in air > exposure limit.

Skin/Body

Protective clothing.

Environmental

See headings 6.2, 6.3 and 13

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colourless
Colour
Colourless
Colour Intensity
---
Form
---
Odor
Odourless
Odor Threshold
No data available
Ph
No data available
Melting Point
-13 °C
Boiling Point
197.4 °C; 1013 hPa
Flash Point
111 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
ether; No data available
Vapor Pressure
0.123 hPa; 25 °C
Vapor Density
---
Relative Density
1.1; 20 °C
Bulk Density
---
Density
1130 kg/m³
Flammability
Combustible
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
398 °C
Decomposition Temperature
No data available
Solubility
water; Complete
Partition Coefficient
-1.36
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.0161 Pa.s; 25 °C
Kinematic Viscosity
Not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

Temperature above flashpoint: higher fire/explosion hazard. Substance has neutral reaction.

Hazardous reactions

Reacts on exposure to water and heat with (some) metals. Violent to explosive reaction with (some) acids.

Avoid

Use earthed equipment. Keep away from naked flames/heat. Finely divided: spark- and explosionproof appliances. Finely divided: keep away from ignition sources/sparks.

Incompatible

Combustible materials, oxidizing agents, (strong) acids, (strong) bases, water/moisture.

Decomposition

Upon combustion: CO and CO2 are formed.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

| | Parameter | Method | Value | Duration | Species | Test design | Fresh/salt water | Value determination | | --- | --- | --- | --- | --- | --- | --- | --- | --- | | Acute toxicity fishes | LC50 | EPA 600/4-90/027 | 72860 mg/l | 96 h | Pimephales promelas | Static system | Fresh water | Experimental value | | Acute toxicity invertebrates | EC50 | OECD 202 | >100 mg/l | 48 h | Daphnia magna | Static system | Fresh water | Experimental value | | Toxicity algae and other aquatic plants | EC50 | EPA 600/9-78-018 | 6500 mg/l - 13000 mg/l | 96 h | Pseudokirchnerie Ila subcapitata | | | Experimental value; Growth rate | | Long-term toxicity fish | NOEC | EPA 600/4-90/027 | 15380 mg/l | 7 day(s) | Pimephales promelas | | | Experimental value | | Long-term toxicity invertebrates | NOEC | EPA 600/4-90/027 | 8590 mg/l | 7 day(s) | Ceriodaphnia sp. | | Fresh water | Experimental value | | Toxicity aquatic micro-organisms | EC20 | ISO 8192 | >1995 mg/l | 30 minutes | Activated sludge | Static system | Fresh water | Read-across |

12.2. Persistence and degradability

ethylene glycol ### Biodegradation water

12.2. Persistence and degradability

| Method | Value | Duration | Value determination | | --- | --- | --- | --- | | OECD 301A: DOC Die-Away Test | 90% - 100% | 10 day(s) | Experimental value |

12.2. Persistence and degradability

| Method | Value | Conc. OH-radicals | Value determination | | --- | --- | --- | --- | | SRC AOP v1.92 | 46.3 day(s) | 500000 /cm³ | Calculated value |

12.3. Bioaccumulative potential

| Method | Remark | Value | Temperature | Value determination | | --- | --- | --- | --- | --- | | | | -1.36 | | |

12.4. Mobility in soil

ethylene glycol ### (log) Koc | Parameter | Method | Value | Value determination | | --- | --- | --- | --- | | log Koc | SRC PCKOCWIN v1.66 | 0 | Calculated value | ### Volatility (Henry's Law constant H) | Value | Method | Temperature | Remark | Value determination | | --- | --- | --- | --- | --- | | 0.1327 Pa.m³/mol | SRC HENRYWIN v3.10 | 25 °C | | Calculated value | ### Percent distribution | Method | Fraction air | Fraction biota | Fraction sediment | Fraction soil | Fraction water | Value determination | | --- | --- | --- | --- | --- | --- | --- | | Other | 0.03 % | | 0 % | 0 % | 100 % | Calculated value | Conclusion Low potential for adsorption in soil

Low potential for adsorption in soil

12.5. Results of PBT and vPvB assessment

Substance does not meet the criteria of PBT, nor the criteria of vPvB according to Annex XIII of Regulation (EC) No 1907/2006, so is neither PBT nor vPvB.

The substance does not meet the criteria for PBT or vPvB according to Annex XIII of Regulation (EC) No 1907/2006.

12.6. Other adverse effects

ethylene glycol Fluorinated greenhouse gases (Regulation (EU) No 517/2014) Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014) Ozone-depleting potential (ODP) Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009) Ground water Ground water pollutant

The substance is not included in the list of fluorinated greenhouse gases, is not classified as dangerous for the ozone layer, but is identified as a ground water pollutant.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycle by distillation. Remove to an authorized waste incinerator for solvents with energy recovery.

Disposal

Remove waste in accordance with local and/or national regulations.

Waste Codes

07 01 04* wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals: other organic solvents, washing liquids and mother liquors EWC
15 01 10* packaging containing residues of or contaminated by dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is ethylene glycol known by?

ethylene glycol is also known as: 1,2-ethanediol; ethane-1,2-diol; ethanediol; glycol; MEG

What is the hazard signal word for ethylene glycol?

The signal word is warning.

What is the physical form of ethylene glycol?

ethylene glycol is a liquid appearing as colourless with colourless color. It has odourless odor.

What is the solubility of ethylene glycol?

water; Complete

What is ethylene glycol used for?

ES01 Manufacture of substance ES02 Distribution of substance ES03 Use as an intermediate ES04 Use as process chemical ES05 Formulation & (re)packing of substances and mixtures ES06 Production of polymers ES07 Use in coatings ES08 Use in coatings ES09 Use in coatings ES10 Use in Cleaning Agents ES11 Use in Cleaning Agents ES12 Use in Cleaning Agents ES13 Lubricants ES14 Metal working fluids/rolling oils ES15 Metal working fluids/rolling oils ES16 Use in agrochemicals ES17 Functional Fluids ES18 Functional Fluids ES19 Functional Fluids ES20 Use in/as de-icing/anti-icing applications/agents ES21 Use in/as de-icing/anti-icing applications/agents ES22 Use in laboratories ES23 Water treatment ES24 Use in adhesives and sealants ES25 Production of polymers, filled polymers, foams, coatings, adhesives, sealants ES26 Production of polymers ES27 Use in agrochemicals ES28 Water treatment ES29 Use in oil field drilling and production operations

What are the hazard statements for ethylene glycol?

This substance has 2 hazard statements:

  • H302: Harmful if swallowed.
  • H373: May cause damage to organs (kidneys) through prolonged or repeated exposure if swallowed.

What is the melting point of ethylene glycol?

The melting point is -13 °C and the boiling point is 197.4 °C; 1013 hPa.