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Safety Data Sheet EN

KPA 3277

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
KPA 3277

Regulatory Identifiers

CAS Number
N/A
UFI Code
0VTV-R4KC-Q00D-G7RQ

Identified Uses

Additive for Off-Highway.

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) EC: 224-235-5 --- 10 - 20% Yes
Calcium branched alkyl phenate sulphide (overbased) --- 5 - 10% Yes
Benzene, polypropene derivatives, sulfonated, calcium salts --- 1 - 5% Yes
2-tetradecyloxirane, reaction products with boric acid EC: 701-392-2 --- 1 - 5% Yes
Dibutylphosphonate EC: 217-316-1 --- 1 - 5% Yes
Triphenylphosphite EC: 202-908-4 --- 0.25 - 1% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.1 - 0.3% Yes
O,O,O-triphenyl phosphorothioate EC: 209-909-9 --- 0.01 - 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Wash with soap and water. If skin irritation or rash occurs: Get medical attention. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. If irritation occurs, get medical assistance. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

A solid stream of water will spread the burning material. Material creates a special hazard because it floats on water. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. See Section 8 of the SDS for Personal Protective Equipment.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

K

KPA 3541

---

K

KPA 2845

---

K

KPA 2485

---

K

KPA 2346

UFI: RYMU-34SP-000K-2F5Y

K

KPA 3155

UFI: 9WHQ-1484-Q005-26RG

K

KPA 2277(3001) bulk

---

P

PK (HL1-003)

---

K

Kane Ace PA121, PA210, PA211, PA220, PA310, PA131, PA600, PA610, PA630, PA650

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse. Avoid environmental contamination. Avoid inhalation of vapors upon opening container. Keep container closed when not in use and use with adequate ventilation. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures. Use grounding and bonding connection when transferring material. In case of spills, beware of slippery floors and surfaces.

Storage

Store away from incompatible materials. See section 10 for incompatible materials. Odorous and toxic fumes may form from the decomposition of this product. Do not store product at temperature in excess of 45°C (113°F) for extended periods of time, 1 week or more; or, using a heat source, such as steam, at a temperature in excess of 100°C (212°F).

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

Fire prevention

Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark amber
Colour
Dark amber
Colour Intensity
---
Form
liquid
Odor
Mild
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
115 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
0.963 (15.6 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
440 mm2/s (40 °C);
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources, or oxidizing materials.

Incompatible

Strong oxidizing agents. Halogens and halogenated compounds. Contact with acids.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide , sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decompositon may generate phosphorus oxides and other phosphorus containing compounds.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Fish

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Fish |Mineral oil|LC 50 (Fathead Minnow, 4 d): > 100 mg/l|

12.1 Toxicity

Fish |zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate)|LC 50 (Rainbow Trout, 4 d): 4.4 mg/l|

12.1 Toxicity

Fish |Calcium branched alkyl phenate sulphide (overbased)|LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l|

12.1 Toxicity

Fish |2-tetradecyloxirane, reaction products with boric acid|LC 50 (Rainbow Trout, 4 d): > 100 mg/l|

12.1 Toxicity

Fish |Dibutyl phosphonate|LC 50 (Zebra Fish, 96 h): 63.4 mg/l|

12.1 Toxicity

Fish |Phenol, dodecyl-, branched|LC 50 (Fathead Minnow, 4 d): 40 mg/l|

12.1 Toxicity

Fish |++ O,O,O-triphenyl phosphorothioate|LC 50 (Zebra Fish, 4 d): > 100 mg/l No toxicity at solubility limit. NOEC (Rainbow Trout, 97 d): 0.0017 mg/l|

12.1 Toxicity

|**Aquatic Invertebrates** Mineral oil|EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l|

12.1 Toxicity

|**Aquatic Invertebrates** |zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate)|EC 50 (Water flea (Daphnia magna), 2 d): 75 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l|

12.1 Toxicity

|Aquatic Invertebrates |Calcium branched alkyl phenate sulphide (overbased)|EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l|

12.1 Toxicity

|**Aquatic Invertebrates** |2-tetradecyloxirane, reaction products with boric acid|EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 20 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l|

12.1 Toxicity

Aquatic Invertebrates Dibutyl phosphonate | EC 50 (Water Flea (Daphnia Magna), 48 h): 20.8 mg/l

12.1 Toxicity

|**Aquatic Invertebrates** |Triphenyl phosphite|EC 50 (Water flea (Daphnia magna), 2 d): 0.94 mg/l|

12.1 Toxicity

|**Aquatic Invertebrates** |Phenol, dodecyl-, branched|EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l|

12.1 Toxicity

|**Aquatic Invertebrates** |++ O,O,O-triphenyl phosphorothioate|EC 50 (Water Flea (Daphnia Magna), 2 d): > 100 mg/l No toxicity at solubility limit. NOEC (Water Flea (Daphnia Magna), 21 d): > 5.5 mg/l No toxicity at solubility limit.|

12.1 Toxicity

Toxicity to Aquatic Plants Mineral oil|EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants zinc bis[O,O-bis(2-ethylhexyl)] EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 410 mg/l bis(dithiophosphate) NOEC (Green algae (Scenedesmus quadricauda), 3 d): 220 mg/l Calcium branched alkyl phenate EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 sulphide (overbased) mg/l 2-tetradecyloxirane, reaction EC 50 (Green algae (selenastrum capricomutum), 3 d): > 100 mg/l products with boric acid Dibutyl phosphonate EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): 14.4 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): 3 mg/l Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l ++ O,O,O-triphenyl EC 50 (Green algae (Scenedesmus quadricauda), 3 d): > 100 mg/l phosphorothioate

12.1 Toxicity

Toxicity to microorganisms: EC 50 (Pseudomonas putida, 0.1 d): 380 mg/l

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Toxicity to microorganisms: Calcium branched alkyl phenate sulphide (overbased) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Toxicity

Toxicity to microorganisms 2-tetradecyloxirane, reaction products with boric acid: EC 50 (Sludge, 0.1 d): > 10,000 mg/l

Toxicity

Toxicity to microorganisms: Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

Toxicity

Toxicity to microorganisms: O,O,O-triphenyl phosphorothioate EC 50 (Sludge, 3 h): > 100 mg/l

12.2 Persistence and Degradability Biodegradation

Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable. zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) OECD TG 301 D, < 5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability Biodegradation

Calcium branched alkyl phenate OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. sulphide (overbased) Inherent Sludge, 38.8 %, 28 d 2-tetradecyloxirane, reaction Miscellaneous, 17.3 %, 28 d, Not readily degradable. products with boric acid Miscellaneous, 26.7 %, 28 d, Not readily degradable. Triphenyl phosphite OECD TG 301 D, 0.14 %, 28 d, Not readily degradable. Phenol, dodecyl-, branched Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable. ++ O,O,O-triphenyl OECD TG 301 B, 17.8 - 19.3 %, 28 d, Not readily degradable. phosphorothioate OECD TG 302 C, 59.9 - 66.8 %, 28 d

12.3 Bioaccumulative potential Bioconcentration Factor (BCF)

Calcium branched alkyl phenate Bioconcentration Factor (BCF): 2.2 sulphide (overbased) Phenol, dodecyl-, branched Bioconcentration Factor (BCF): 794.33 (Measured) ++ O,O,O-triphenyl Fish, Bioconcentration Factor (BCF): 2,551 (Flow Through) phosphorothioate

12.1 Toxicity

Not provided

12.2 Persistence and degradability

Not provided

12.3 Bioaccumulative potential

zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) Log Kow: 3.6 (Measured) Calcium branched alkyl phenate sulphide (overbased) Log Kow: 11.08 (Measured) 2-tetradecyloxirane, reaction products with boric acid Log Kow: 9.4 (calculated) Dibutyl phosphonate Log Kow: estimated 1.81 25 °C Triphenyl phosphite Log Kow: 6.62 25 °C (calculated) Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.4 Mobility in soil

Not provided

12.5 Results of PBT and vPvB assessment

Not provided

12.6 Endocrine disrupting properties

Not provided

12.7 Other adverse effects

Not provided

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

Product: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties:

This substance/mixture contains components considered to have endocrine disrupting properties for environment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Phenol, dodecyl-, branched: The substance is considered to have endocrine disrupting properties according to REACH Article 57(f) for the environment.

The substance is considered to have endocrine disrupting properties according to REACH Article 57(f) for the environment.

12.7 Other adverse effects

This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects.

The product contains an impurity (alkylated phenol) that is highly toxic to aquatic organisms, but the component (calcium phenate) itself is classified as Aquatic Chronic 4. The product is classified as toxic to aquatic life with long lasting effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Aryl thiophosphate, Zinc alkyldithiophosphate)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for KPA 3277?

The signal word is warning.

What is the physical form of KPA 3277?

KPA 3277 is a liquid appearing as dark amber with dark amber color. It has mild odor.

What is KPA 3277 used for?

Additive for Off-Highway.

What are the hazard statements for KPA 3277?

This substance has 2 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H411: Toxic to aquatic life with long lasting effects.