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Safety Data Sheet EN

B125353 (AL-0014)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
B125353 (AL-0014)

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Heavy Duty Diesel

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Distillates (petroleum), hydrotreated heavy paraffinic EC: 265-157-1 --- 10 - 20% Yes
Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, C7-9-branched alkyl esters EC: 406-040-9 --- 10 - 25% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC: 283-392-8 --- 1 - 3% Yes
Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC: 253-249-4 --- 1 - 5% Yes
Calcium branched alkyl phenate sulphide --- 1 - 5% Yes
Mineral oil --- 20 - 50% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.01 - 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Wash with soap and water. Launder contaminated clothing before reuse.

Eye contact

Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses.

Ingestion

Treat symptomatically.

Immediate Medical Attention

Get medical attention if symptoms occur (skin contact) or get medical attention (ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

When heated, hazardous gases may be released including: sulfur dioxide. Material creates a special hazard because it floats on water. Water may cause splattering.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Ventilate area if spilled in confined space or other poorly ventilated areas.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures. Use grounding and bonding connection when transferring material. In case of spills, beware of slippery floors and surfaces. Keep container closed when not in use and use with adequate ventilation. Wear appropriate personal protective equipment.

Storage

Keep container closed when not in use.

Hygiene

Observe good industrial hygiene practices.

Fire prevention

Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Butyl rubber. Use caution when opening manway covers of storage and transportation containers. 3-nitroaniline crystals may be present on the interior surface of these openings. 3-nitroaniline is toxic by dermal exposure. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

If contact is likely, safety glasses with side shields are recommended. Eye protection should meet the standards set out in EN 166.

Respiratory

Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Consult with an industrial hygienist to determine the appropriate respiratory protection for your specific use of this material. A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

In areas contaminated with 3-nitroaniline crystals, all workers involved in confined space clean-up operations should wear full body protection and air-supplied respirators. Long sleeve shirt is recommended.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark brown
Colour
Dark brown
Colour Intensity
---
Form
liquid
Odor
Mild
Odor Threshold
No data available.
Ph
No data available.
Melting Point
---
Boiling Point
No data available.
Flash Point
154 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
No data available.
Relative Density
0.881 - 0.921 (15.6 °C)
Bulk Density
---
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
4,257.4 mPa.s (20 °C); 50 mPa.s (115.6 °C)
Kinematic Viscosity
1,270 mm2/s (40 °C); 95 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources, or oxidizing materials. Excessive heat.

Incompatible

Halogens and halogenated compounds. Strong acids. Oxidizing agents. Strong oxidizing agents. Strong bases.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish

12.1 Ecotoxicity

Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts LC 50 (Rainbow Trout, 4 d): 4.5 mg/l LC 50 (Sheepshead Minnow, 4 d): 46 mg/l NOEC (Rainbow Trout, 4 d): 1.8 mg/l

12.1 Ecotoxicity

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) LC 50 (Zebra Fish, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Calcium branched alkyl phenate sulphide LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Ecotoxicity

Fish Phenol, dodecyl-, branched LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Toxicity

Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Toxicity

Aquatic Invertebrates Distillates (petroleum), hydrotreated heavy paraffinic EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Toxicity

EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l NOEC (Water flea (Daphnia magna), 2 d): 10 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Toxicity

EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Calcium branched alkyl phenate sulphide EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

Aquatic Invertebrates

Phenol, dodecyl-, branched EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l

12.1 Toxicity

Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Toxicity

EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 21 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 10 mg/l

Toxicity to Aquatic Plants

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Green algae (Selenastrum capricornutum), 3 d): 600 mg/l

Toxicity to Aquatic Plants

Calcium branched alkyl phenate sulphide EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

12.1 Toxicity

Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l

12.1 Toxicity

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Sludge, 0.1 d): > 10,000 mg/l

Toxicity to microorganisms

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Toxicity

Toxicity to microorganisms Calcium branched alkyl phenate sulphide EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Toxicity

Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.2 Persistence and Degradability

Biodegradation

12.2 Persistence and Degradability

Biodegradation Mineral oil Carbon dioxide generation 31 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Biodegradation Distillates (petroleum), hydrotreated heavy paraffinic Oxygen depletion 31 % (28 d, OECD TG 301 F)

12.2 Persistence and Degradability

### Biodegradation Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts Carbon dioxide generation 1.5 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Biodegradation Reaction products of Benzeneamine, N-phenyl- with nonene (branched) Carbon dioxide generation 0 % (28 d, OECD TG 301 B)

12.2 Persistence and Degradability

Biodegradation Calcium branched alkyl phenate sulphide Carbon dioxide generation 4.7 - 10.8 % (28 d, OECD TG 301 B) Dissolved organic carbon (DOC) 38.8 % (28 d, Inherent Sludge)

12.2 Persistence and Degradability

Biodegradation Phenol, dodecyl-, branched Dissolved organic carbon (DOC) 10 % (56 d, Miscellaneous) Carbon dioxide generation 25 % (28 d, OECD TG 301 B)

12.3 Bioaccumulative Potential

Bioconcentration Factor (BCF) | Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, C7-9-branched alkyl esters | Bioconcentration Factor (BCF): 260 |

12.3 Bioaccumulative Potential

Bioconcentration Factor (BCF) | Reaction products of Benzeneamine, N-phenyl- with nonene (branched) | Bioconcentration Factor (BCF): 1,584.89 (Measured) |

12.3 Bioaccumulative Potential

Bioconcentration Factor (BCF) | Calcium branched alkyl phenate sulphide | Bioconcentration Factor (BCF): 2.2 |

12.3 Bioaccumulative Potential

Bioconcentration Factor (BCF) | Phenol, dodecyl-, branched | Bioconcentration Factor (BCF): 794.33 (Measured) |

12.3 Bioaccumulative Potential

Partition Coefficient n-octanol / water (log Kow) Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts Log Kow: 0.56 (Measured)

12.3 Bioaccumulative Potential

Partition Coefficient n-octanol / water (log Kow) Calcium branched alkyl phenate sulphide Log Kow: 11.08 (Measured)

12.3 Bioaccumulative Potential

Partition Coefficient n-octanol / water (log Kow) Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.4 Mobility

No data available

12.5 Results of PBT and vPvB assessment

No data available

2.6 Other Adverse Effects:

This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity.

The product contains an alkylated phenol impurity classified as Aquatic Acute 1 and Aquatic Chronic 1, and a component (calcium phenate) classified as Aquatic Chronic 4. The text advises against using the alkylphenol impurity classification for the overall product classification.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for B125353 (AL-0014)?

The signal word is no signal word.

What is the physical form of B125353 (AL-0014)?

B125353 (AL-0014) is a liquid appearing as dark brown with dark brown color. It has mild odor.

What is B125353 (AL-0014) used for?

Heavy Duty Diesel

What are the hazard statements for B125353 (AL-0014)?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.