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Safety Data Sheet EN

R14653A/606531

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
R14653A/606531

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Passenger Car Oils

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL LIMITED logo

LUBRIZOL LIMITED

manufacturer

THE KNOWLE, NETHER LANE HAZELWOOD, DERBYSHIRE, DE56 4AN GB

(44) 01332-842211

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-trans-butyl-4-hydroxyphenyl)propionate EC: 406-040-9 --- 10 - 25% Yes
Mineral oil --- 20 - 50% Yes
Calcium branched alkyl phenate sulphide (overbased) --- 5 - 10% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC: 283-392-8 --- 3 - 5% Yes
Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC: 253-249-4 --- 1 - 5% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.01 - 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Wash with soap and water. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses.

Ingestion

Treat symptomatically. Get medical attention.

Immediate Medical Attention

Hazards: No data available.

Medical Treatment

Treatment: Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

No unusual fire or explosion hazards noted.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

6

606531 R14653A

UFI: TN0M-G04X-E00S-53HS

R

R15381A

UFI: ATHT-S04A-Y95V-JW7V

R

R10059A

---

R

R10776A

---

6

606865 - R14084A

---

6

606713 R14046A

---

R

R14994A

UFI: 1UWM-67H3-EP2H-TYWS

R

R12276A

UFI: GA8H-A6FU-EPGW-63E1

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container closed when not in use and use with adequate ventilation. Observe good industrial hygiene practices. Wear appropriate personal protective equipment.

Storage

Keep container closed when not in use.

Hygiene

Observe good industrial hygiene practices.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

If contact is likely, safety glasses with side shields are recommended. Eye protection should meet the standards set out in EN 166.

Respiratory

Use respirator with an organic vapor cartridge if exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Long sleeve shirt is recommended.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Dark amber
Colour Intensity
---
Form
liquid
Odor
Characteristic
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
168 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
0.939 - 0.979 (15.6 °C)
Bulk Density
---
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
2900 mm2/s (40 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Excessive heat.

Incompatible

Strong acids. Strong oxidizing agents. Strong bases. Strong mineral acids and strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Calcium branched alkyl phenate sulphide (overbased) LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Ecotoxicity

Fish Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts LC 50 (Rainbow Trout, 4 d): 4.5 mg/l LC 50 (Sheepshead Minnow, 4 d): 46 mg/l

12.1 Ecotoxicity

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) LC 50 (Zebra Fish, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Phenol, dodecyl-, branched LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Ecotoxicity

Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Ecotoxicity

### Aquatic Invertebrates Calcium branched alkyl phenate sulphide (overbased) EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Ecotoxicity

### Aquatic Invertebrates Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Phenol, dodecyl-, branched EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Calcium branched alkyl phenate sulphide (overbased) EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 21 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 10 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Green algae (Selenastrum capricornutum), 3 d): 600 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Calcium branched alkyl phenate sulphide (overbased) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Sludge, 0.1 d): > 10,000 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Ecotoxicity

**Toxicity to microorganisms** Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.2 Persistence and Degradability

Biodegradation

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Calcium branched alkyl phenate sulphide (overbased) OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. Inherent Sludge, 38.8 %, 28 d

12.2 Persistence and Degradability

Biodegradation Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts OECD TG 301 B, 1.5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Reaction products of Benzeneamine, N-phenyl- with nonene (branched) OECD TG 301 B, 0 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phenol, dodecyl-, branched Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable.

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF)

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-trans-butyl-4-hydroxyphenyl)propionate Bioconcentration Factor (BCF): 260

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) Calcium branched alkyl phenate sulphide (overbased) Bioconcentration Factor (BCF): 2.2

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) Phenol, dodecyl-, branched Bioconcentration Factor (BCF): 794.33 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Calcium branched alkyl phenate sulphide (overbased) Log Kow: 11.08 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts Log Kow: 0.56 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Reaction products of Benzeneamine, N-phenyl- with nonene (branched) Log Kow: > 7 Experimental result, Weight of Evidence study

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine Disruption:

Product: This substance/mixture contains components considered to have endocrine disrupting properties for environment, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Phenol, dodecyl-, branched The substance is considered to have endocrine disrupting properties according to REACH Article 57(f) for the environment.

The substance/mixture contains components with endocrine disrupting properties for the environment, specifically Phenol, dodecyl-, branched.

12.7 Other adverse effects

Product: Harmful to aquatic life with long lasting effects. SDS_GB - R14653A/606531 Lubrizol Version: 1.2 Revision Date: 18.08.2021 Calcium branched alkyl phenate sulphide (overbased) This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity.

The product is classified as harmful to aquatic life with long-lasting effects. Although it contains an alkylated phenol impurity that is highly toxic (Aquatic Acute 1/Chronic 1), the calcium phenate component itself is classified as Aquatic Chronic 4, which determines the product's overall classification.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for R14653A/606531?

The signal word is no signal word.

What is the physical form of R14653A/606531?

R14653A/606531 is a liquid with dark amber color. It has characteristic odor.

What is R14653A/606531 used for?

Passenger Car Oils

What are the hazard statements for R14653A/606531?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.