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Safety Data Sheet EN

Rokopol G690

CAS 25791-96-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Rokopol G690
Chemical Name
Polyether polyol, Glycerol, propoxylated
Synonyms
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.,.alpha.',.alpha."-1,2,3-propanetriyltris[.omega.-hydroxy-; Poly[oxy(methyl-1,2-ethanediyl)], α,α',α"-1,2,3-propanetriyltris [ω-hydroxy-; 1,2,3-Propanetriol, methyloxirane polymer; 1,2,3-Propanetriol, polymer with methyloxirane; Poly(oxypropylene) glycerol triether; glycerol poly (oxypropylene)triol

Regulatory Identifiers

CAS Number
25791-96-2 Check regulations →

Identified Uses

For the production of rigid polyurethane foams, one-component foams and other polyurethane-based materials.

Uses advised against

Not determined.

Manufacturers & Suppliers

P

PCC Rokita SA

manufacturer

ul. Sienkiewicza 4, 56-120 Brzeg Dolny, Poland

+48 71 794 3881

Emergency Contacts

PCC Rokita SA

+48 71 794 2555

available 24h/day

PCC Rokita SA

+48 71 794 2441

available 24h/day

PCC Rokita SA

+48 71 794 2690

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Polyether polyol, Glycerol, propoxylated 25791-96-2 100% No
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene EC: 270-128-1 68411-46-1 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur.

Symptoms: No specific data.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.

Symptoms: No specific data.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

Symptoms: No specific data.

Ingestion

Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Symptoms: No specific data.

Immediate Medical Attention

Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguish fire with dispersed water jets, foam and dry powder or carbon dioxide extinguisher.

Unsuitable media

Avoid heavy hose streams.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Absorb with an inert material and place in an appropriate waste disposal container.

Materials: inert material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8).

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Wear suitable gloves tested to EN374. In case of long-term direct exposure, protective gloves made of nitrile or nitrile rubber with a thickness > 0.2 mm, and a penetration time ≥ 30 min. should be used. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colourless to yellow
Colour
Colourless to yellow
Colour Intensity
---
Form
---
Odor
Mild. Characteristic.
Odor Threshold
---
Ph
Lack of data.
Melting Point
Lack of data.
Boiling Point
Lack of data.
Flash Point
Open cup: >230°C (>446°F) [Product does not sustain combustion.]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Lack of data.
Vapor Density
Lack of data.
Relative Density
Lack of data.
Bulk Density
---
Density
1,03 g/cm³ [25°C (77°F)]
Flammability
Lack of data.
Upper Explosive Limit
Lack of data.
Lower Explosive Limit
Lack of data.
Explosive Limits
---
Auto Ignition Temperature
Lack of data.
Decomposition Temperature
Lack of data.
Solubility
acetone: Easily soluble, methanol: Easily soluble, water: Very slightly soluble
Partition Coefficient
-1,82 to -0,73 [Estimated. (similar material)]
Solubility In Water
Lack of data.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Dynamic (room temperature): 225 to 275 mPa·s [ASTM D 4878]
Kinematic Viscosity
Lack of data.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see Section 7).

Reactivity

Not considered to be reactive.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Darkens in contact with air and light. Avoid temperature above 40 °C

Incompatible

oxidizing agents, strong alkalis, acids, monomeric isocyanates

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Product/ingredient name Polyether polyol, Glycerol, propoxylated Result Acute - LC50 - Fresh water OECD 203 [Fish, Acute Toxicity Test] Fish - Leuciscus idus >1000 mg/l - (similar material) [96 hours] Acute - EC50 - Fresh water OECD 202 [Daphnia sp. Acute Immobilization Test and Reproduction Test] Daphnia - Daphnia magna >100 mg/l - (similar material) [48 hours] Chronic - NOEC - Fresh water OECD 211 [Daphnia Magna Reproduction Test] Daphnia - Daphnia magna ≥10 mg/l - (similar material) [21 days] Acute - EC50 - Fresh water OECD 201 [Alga, Growth Inhibition Test] Algae - Desmodesmus subspicatus >100 mg/l - (similar material) [72 hours] EC10 - Fresh water EU C.11 [Activated Sludge, Respiration Inhibition Test] Micro-organism - Activated sludge - Photobacterium phosphoreum >10000 mg/l - (similar material) [3 hours]

12.2 Persistence and degradability

Conclusion/Summary [Product] : This product has not been tested for biodegradation.

This product has not been tested for biodegradation.

12.3 Bioaccumulative potential

Product/ingredient name | LogPow | BCF | Potential

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Polyether polyol, Glycerol, propoxylated | -1.82 to -0.73 | <100 [Estimated. With a logKow ≤3, the substance can be considered to have a low potential for bioaccumulation.] | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogPow | BCF | Potential | | --- | --- | --- | --- | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene | ≥5 | 1730 [METI guideline (concentration test on chemical substances in fish)] | High |

12.4 Mobility in soil

Soil/Water partition coefficient | Product/ingredient name | logKoc | Koc | | --- | --- | --- | | Polyether polyol, Glycerol, propoxylated | 3,199 | 1581,2 | Results of PMT and vPvM assessment | Product/ingredient name | PMT | P | M | T | vPvM | vP | vM | | --- | --- | --- | --- | --- | --- | --- | --- | | Polyether polyol, Glycerol, propoxylated | No | N/A | No | No | No | N/A | No | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene | No | N/A | No | Yes | No | N/A | No | Mobility : Not tested. LogKoc Estimated. Based on available literature data (similar material) Conclusion/Summary : The product does not meet the criteria to be considered as a PMT or vPvM.

The product does not meet the criteria to be considered as a PMT or vPvM. Mobility was not tested, and LogKoc was estimated based on available literature data.

12.5 Results of PBT and vPvB assessment

Regulation (EC) No. 1907/2006 [REACH] According to the results of its assessment, this substance is not a PBT or a vPvB. Regulation (EC) No. 1272/2008 [CLP] | Product/ingredient name | PBT | P | B | T | vPvB | vP | vB | | --- | --- | --- | --- | --- | --- | --- | --- | | Polyether polyol, Glycerol, propoxylated | No | N/A | No | No | No | N/A | No | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene | No | N/A | No | Yes | No | N/A | No | Conclusion/Summary : The product does not meet the criteria to be considered as a PBT or vPvB.

The product does not meet the criteria to be considered as a PBT or vPvB.

12.6 Endocrine disrupting properties

Conclusion/Summary [Product] : The product does not contain components included in the list established in accordance with Article 59(1) for having endocrine disrupting properties, and identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration ≥ 0.1% (w/w).

The product does not contain components included in the list established in accordance with Article 59(1) for having endocrine disrupting properties, and identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration ≥ 0.1% (w/w).

12.7 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional or local authority requirements.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

16 03 06 organic wastes other than those mentioned in 16 03 05 EWC
15 01 02 plastic packaging EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Rokopol G690 known by?

Rokopol G690 is also known as: Poly[oxy(methyl-1,2-ethanediyl)], .alpha.,.alpha.',.alpha."-1,2,3-propanetriyltris[.omega.-hydroxy-; Poly[oxy(methyl-1,2-ethanediyl)], α,α',α"-1,2,3-propanetriyltris [ω-hydroxy-; 1,2,3-Propanetriol, methyloxirane polymer; 1,2,3-Propanetriol, polymer with methyloxirane; Poly(oxypropylene) glycerol triether; glycerol poly (oxypropylene)triol

What is the hazard signal word for Rokopol G690?

The signal word is no signal word.

What is the physical form of Rokopol G690?

Rokopol G690 is a liquid. appearing as colourless to yellow with colourless to yellow color. It has mild. characteristic. odor.

What is the solubility of Rokopol G690?

acetone: Easily soluble, methanol: Easily soluble, water: Very slightly soluble

What is Rokopol G690 used for?

For the production of rigid polyurethane foams, one-component foams and other polyurethane-based materials.

What is the melting point of Rokopol G690?

The melting point is Lack of data. and the boiling point is Lack of data..