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Safety Data Sheet EN

GENAMIN PA-SH RT

CAS 90640-32-7
EC 292-550-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GENAMIN PA-SH RT
Product Code
10957210284
Chemical Name
C16-18-(even numbered) alkyl amines
Synonyms
Amines, hydrogenated tallow alkyl

Regulatory Identifiers

CAS Number
90640-32-7 Check regulations →
EC Number
292-550-5 Check regulations →

Identified Uses

Anticaking agent/collecter for flotation

Manufacturers & Suppliers

C

Clariant Produkte (Deutschland) GmbH

manufacturer

65926 Frankfurt am Main

+49 69 305 18000

Emergency Contacts

Emergency Contact

00800-5121 5121

24 h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410
Asp. Tox. Cat. 1 H304

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to organs (Gastrointestinal tract, Liver, Immune system) through prolonged or repeated exposure if swallowed.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe mist or vapours.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
P331 Do NOT induce vomiting.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Substance name : EC-No. : 292-550-5 - : C16-18-(even numbered) alkyl amines (Synonym: Amines, hydrogenated tallow alkyl CAS NR. 61788-45-2)

Chemical Name CAS Number Concentration Hazardous
Amines, C16-18-alkyl EC: 292-550-5 90640-32-7 90 - 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove to fresh air.

Skin contact

Wash off immediately with plenty of water.

Symptoms: Causes skin irritation.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Symptoms: Causes serious eye damage.

Immediate Medical Attention

Get medical advice/ attention if inhaled. Consult a physician for skin and eye contact. Get medical attention immediately if swallowed.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray jet, Foam, Carbon dioxide (CO2), Dry powder

Specific hazards

In case of fire hazardous decomposition products may be produced such as: Nitrogen oxides (NOx)

Firefighter Protection

Wear suitable protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Do not allow to enter drains or waterways

Cleanup methods

Allow to solidify. Take up mechanically. Pick up with binding agent (eg sand, sawdust). Rinse away rest with plenty of water or dilute acetic acid

Materials: binding agent (eg sand, sawdust), water, dilute acetic acid

—

Related Products

Similar products with comparable safety profiles

G

GENOMER* 5695

---

G

GENOMER* 6043/M22

---

G

GENAPOL LA 090

CAS: 68551-12-2

G

Genonex

---

D

DIMETHYLAMINOPROPYLAMINE (DMAPA)

CAS: 109-55-7

C

CGNA10

---

E

ETHYLENEAMINE S 1107

---

E

ETHYLENEAMINE S 1107

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only in well-ventilated areas. Handle and open container with care.

Storage

Keep container tightly closed and in a well-ventilated place.

Hygiene

Wash hands before breaks and at the end of workday. Use protective skin cream before handling the product. Take off immediately all contaminated clothing and wash it before reuse.

Fire prevention

Observe the general rules of industrial fire protection

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Break through time: 480 min; Glove thickness: 0,7 mm; Remarks: Long-term exposure Impervious butyl rubber gloves. Break through time: 30 min; Glove thickness: 0,4 mm; Remarks: For short-term exposure (splash protection): Nitrile rubber gloves. These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.

Eyes

Safety glasses

Respiratory

not required under normal use In the case of dust or aerosol formation use respirator with an approved filter. Suitable mask with particle filter P3 (European Norm 143) Applicable national Regulations must be observed. Take note of the limitations regarding wear-time, in conjunction with the Regulations for the use of Respiratory Protective Equipment.

Skin/Body

Wear suitable protective clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
molten
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
white to yellow
Colour Intensity
---
Form
---
Odor
amine-like
Odor Threshold
---
Ph
11,5 Method: DIN EN 1262 Ethanol/Water 1:1
Melting Point
approx. 39 °C Method: ISO 3016
Boiling Point
300 °C (13 hPa)
Flash Point
approx. 168 °C Method: DIN/ISO 2592 (open cup)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
approx. 0,0079 Pa (20 °C) Method: OECD Test Guideline 104
Vapor Density
---
Relative Density
---
Bulk Density
approx. 420 kg/m3Method: ISO 60
Density
approx. 0,8 g/cm3 (60 °C) Method: DIN 51757
Flammability
---
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
no data available
Decomposition Temperature
Heating rate: 3 K/min Method: DTA No decomposition up to 400 °C.
Solubility
---
Partition Coefficient
log Pow: approx. 7,6 Method: Calculated from the solubilities
Solubility In Water
< 1 µg/l Method: calculated
Solubility In Fat
126 g/l(20 °C) Solvent: 1-octanol
Molecular Weight
---
Voc Content
---
Metal Corrosion
Not applicable
Dynamic Viscosity
approx. 3 mPa.s (60 °C)
Kinematic Viscosity
no data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

See section 10.3. "Possibility of hazardous reactions"

Hazardous reactions

Reactions with acids.

Avoid

Keep away from strong acids.

Incompatible

not known

Decomposition

Nitrogen oxides (NOx)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish: LC50 (Danio rerio (zebra fish)): 0,88 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 0,13 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 NOEC (Daphnia magna (Water flea)): 0,013 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Remarks: River-water test Toxicity to algae/aquatic plants: EC50 (Desmodesmus subspicatus (green algae)): 0,12 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to microorganisms: EC50 : 490 mg/l Method: OECD Test Guideline 209

12.1 Toxicity

Amines, C16-18-alkyl: Toxicity to fish: LC50 (Danio rerio (zebra fish)): 0,84 mg/l End point: mortality Exposure time: 96 h Test Type: semi-static test Analytical monitoring: yes Method: OECD Test Guideline 203 GLP: yes Remarks: By analogy with a product of similar composition. Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 0,32 mg/l End point: Immobilization Exposure time: 48 h Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 202 GLP: yes Remarks: By analogy with a product of similar composition. Toxicity to algae/aquatic plants: ErC50 (Desmodesmus subspicatus (green algae)): 0,12 mg/l End point: Growth rate Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 GLP: yes. M-Factor (Acute aquatic toxicity): 10. Toxicity to microorganisms: EC50 (activated sludge): 490,1 mg/l End point: Bacteria toxicity (respiration inhibition) Exposure time: 3 h Test Type: static test Analytical monitoring: no Method: OECD Test Guideline 209 GLP: no. Toxicity to fish (Chronic toxicity): Remarks: no data available. Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): NOEC: 0,01 mg/l End point: Reproduction rate Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Method: OECD Test Guideline 211 GLP: yes Remarks: By analogy with a product of similar composition. M-Factor (Chronic aquatic toxicity): 10. Toxicity to soil dwelling organisms: Test Type: Other LC50: > 1.000 mg/kg Exposure time: 14 d End point: mortality Species: Eisenia fetida (earthworms) Method: OECD Test Guideline 207 GLP:yes Remarks: By analogy with a product of similar composition. Sediment toxicity: NOEC: 188 mg/kg dry weight (d.w.) Analytical monitoring: yes Sediment: Artificial sediment Exposure duration: 28 d Species: Chironomus tentans Method: OECD Test Guideline 218 GLP: yes. Ecotoxicology Assessment: Acute aquatic toxicity: Very toxic to aquatic life. Chronic aquatic toxicity: Very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability

Components: Amines, C16-18-alkyl: Biodegradability : Test Type: aerobic Inoculum: activated sludge Result: Readily biodegradable. Biodegradation: 75 % Exposure time: 28 d Method: OECD Test Guideline 301D

12.3 Bioaccumulative potential

Product: Bioaccumulation : Bioconcentration factor (BCF): 173 Components: Amines, C16-18-alkyl: Bioaccumulation : Bioconcentration factor (BCF): 173 Method: Other Remarks: By analogy with a product of similar composition Partition coefficient: n- : log Pow: 4,33 (25 °C) octanol/water

12.4 Mobility in soil

Distribution among : Remarks: Kp approx. 700 l/kg environmental compartments highly adsorbing

12.5 Results of PBT and vPvB assessment

Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Components: Amines, C16-18-alkyl: Assessment : The substance is not identified as a PBT or as a vPvB substance.

The product and its components are not considered to be PBT or vPvB at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

The product should not be allowed to enter drains, water courses or the soil.

The product should not be allowed to enter drains, water courses or the soil.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

In accordance with local authority regulations, take to special waste incineration plant

Disposal

In accordance with local authority regulations, take to special waste incineration plant

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3077
Shipping Name
Environmentally hazardous substance, solid, n.o.s., molten
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Apart from the data/regulations specified in this chapter, no further information is available concerning safety, health and environmental protection.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is GENAMIN PA-SH RT known by?

GENAMIN PA-SH RT is also known as: Amines, hydrogenated tallow alkyl

What is the hazard signal word for GENAMIN PA-SH RT?

The signal word is danger.

What is the physical form of GENAMIN PA-SH RT?

GENAMIN PA-SH RT is a molten with white to yellow color. It has amine-like odor.

What is GENAMIN PA-SH RT used for?

Anticaking agent/collecter for flotation

What are the hazard statements for GENAMIN PA-SH RT?

This substance has 5 hazard statements:

  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H373: May cause damage to organs (Gastrointestinal tract, Liver, Immune system) through prolonged or repeated exposure if swallowed.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of GENAMIN PA-SH RT?

The melting point is approx. 39 °C Method: ISO 3016 and the boiling point is 300 °C (13 hPa).