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Safety Data Sheet EN

CGL-BHT/FAME

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CGL-BHT/FAME
Product Code
CN 3811900

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Antioxidant

Uses advised against

None known.

Manufacturers & Suppliers

C

Cargill NV

manufacturer

Moervaartkaai 1,B-9042 Gent, Belgium

+32 9 342 22 50

Emergency Contacts

Emergency Contact

+32 9 342 22 50

Belgian Center Antipoison

+32 02 264 96 30

Emergency Contact

112

Available 24 hours a day.

National Poisons Control Center

070 245 245

Available 24 hours a day.

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Aquatic Acute Cat. 1 H400
Aquatic Chronic H410

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P234 Store away from incompatible materials.
P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Fatty acids, vegetable-oil, Methyl ester EC: 273-606-8 68990-52-3 50 - 80% No
2,6-Di-tert-butyl-p-cresol EC: 204-881-4 128-37-0 20 - 50% Yes

This product contains as well Fatty acids, vegetable-oil, Methyl ester which consists mainly of saturated and unsaturated fatty acids methyl ester (chain length C16-C18, origin: vegetable oils). It may as well may contain residuals of glycerol and partial glycerides (total < 3.5%) and traces of methanol (< 0.2%).

Notes

All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. The full text for all H-statements is displayed in section 16. This product contains as well Fatty acids, vegetable-oil, Methyl ester which consists mainly of saturated and unsaturated fatty acids methyl ester (chain length C16-C18, origin: vegetable oils). It may as well may contain residuals of glycerol and partial glycerides (total < 3.5%) and traces of methanol (< 0.2%).

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.

Skin contact

Remove and isolate contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Subsequent cleansing with polyethyleneglycol 400, then again with water and soap. In case of contact with hot or molten product, cool rapidly with water. Do not attempt to remove molten product from skin because skin will tear easily.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Remove contact lenses, if present and easy to do.

Ingestion

Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Never give anything by mouth to a victim who is unconscious or is having convulsions.

Immediate Medical Attention

Get medical attention if irritation develops and persists. In case of contact with hot or molten product, seek immediate medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam. Powder. Carbon dioxide (CO2).

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Porous material such as rags, paper, insulation, or organic clay may spontaneously combust when wetted with this material.

Instructions

Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials.

Firefighter Protection

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unnecessary personnel away. Keep away from open flames, hot surfaces and sources of ignition. Ensure adequate ventilation. Wear appropriate protective equipment and clothing during clean-up. Local authorities should be advised if significant spillages cannot be contained.

Small spill

Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Large spill

Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.

Environmental

Avoid discharge into drains, water courses or onto the ground.

Cleanup methods

Following product recovery, flush area with water. Clean surface thoroughly to remove residual contamination.

Materials: absorbent material (e.g. cloth, fleece)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid prolonged exposure. Avoid breathing mist or vapour. Wear appropriate personal protective equipment. Wash thoroughly after handling. Avoid contact with skin, eyes and clothing.

Storage

Store in a dry place. Store in original tightly closed container.

Hygiene

Wash thoroughly after handling. Observe good industrial hygiene practices.

Fire prevention

Do not handle, store or open near an open flame, sources of heat or sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations. Recommended: (< 1 hour) Polyvinyl chloride - PVC, Natural rubber - NR

Eyes

Wear safety glasses with side shields (or googles) in accordance with EN 166.

Respiratory

If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the case of vapor formation use a respirator with an approved filter. Respirator with a vapor filter (EN 141) Respirator with ABEK-filter.

Skin/Body

Wear suitable protective clothing.

Environmental

Environmental manager must be informed of all major releases.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Yellowish.
Colour Intensity
---
Form
Liquid.
Odor
Not available.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
> 101,0 °C (> 213,8 °F) ENISO 27919
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
---
Relative Density
Not available.
Bulk Density
---
Density
885 - 889 kg/m3 at 15 °C (Air =1)
Flammability
Not applicable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
255 °C (491 °F)
Decomposition Temperature
Not available.
Solubility
Insoluble.
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.

Hazardous reactions

No dangerous reaction known under conditions of normal use.

Avoid

Contact with incompatible materials.

Incompatible

Strong oxidising agents.

Decomposition

At thermal decomposition temperatures, carbon monoxide and carbon dioxide.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Very toxic to aquatic life with long lasting effects.

12.1. Toxicity

Very toxic to aquatic life with long lasting effects. Components Species Test results 2,6-Di-tert-butyl-p-cresol (CAS 128-37-0) Aquatic Acute Algae IC50 Algae > 0,4 mg/l, 72 Hours Desmodesmus subspicatus EU C3. Crustacea EC50 Daphnia magna 0,61 mg/l, 48 Hours OECD 202 Daphnia sp.Acute Immobilization test Fish LC0 Danio rerio >= 0,57 mg/l, 96 Hours EU C.1 Other EC50 Activated sludge > 10000 mg/l, 3 Hours Chronic Crustacea NOEC Daphnia magna 0,316 mg/l, 21 days OECD 202 Daphnia sp.Acute Immobilization test

The substance is classified as very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability

Not provided.

12.3 Bioaccumulative potential

Not provided.

12.4 Mobility in soil

Not provided.

12.5 Results of PBT and vPvB assessment

Not provided.

12.6 Endocrine disrupting properties

Not provided.

12.7 Other adverse effects

Not provided.

12.1. Toxicity

Very toxic to aquatic life with long lasting effects. Components Species Test results Fatty acids, vegetable-oil, Methyl ester (CAS 68990-52-3) Aquatic Acute Fish LC50 Fish 100000 mg/l OECD 203

12.2. Persistence and degradability

All methyl esters of fatty acids are readily biodegradable in water, soil and sediments. They pass the 10 days windows with 62% of degradation. Half life in the three compartments is less than 2 -3 days. In some case even less than 1 day. Method: ISO 10712.

All methyl esters of fatty acids are readily biodegradable in water, soil and sediments.

12.2. Persistence and degradability

2,6-di-tert-butyl-p-cresol was not readily biodegradable (4.5 % - Not readily - 28 days) in an OECD 301C Ready Biodegradability -Modified MITI Test.

12.2. Persistence and degradability

All methyl esters of fatty acids are readily biodegradable in water, soil and sediments. They pass the 10 days windows with 62% of degradation. Half life in the three compartments is less than 2 -3 days. In some case even less than 1 day. Method: ISO 10712.

The substance is readily biodegradable in water, soil, and sediments, passing the 10-day window with 62% degradation. Half-life in the three compartments is less than 2-3 days.

12.2 Persistence and degradability

2,6-di-tert-butyl-p-cresol was not readily biodegradable (4.5 % - Not readily - 28 days) in an OECD 301C Ready Biodegradability -Modified MITI Test.

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

BCF = 3 Bioaccumulation of C16 -C18, C18 -unstd., Methyl ester has been tested in Mytilus Edulis following OECD Guideline 305.A 6.2 at 25°C. Method OECD 107.

12.3. Bioaccumulative potential

2,6-di-tert-butyl-p-cresol has a LogPow = 5.1.

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

Not a PBT or vPvB substance or mixture.

The substance is not considered to be a PBT or vPvB substance.

12.6. Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Waste Codes

Not assigned The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
Environmentally hazardous substances, liquid, n.o.s. (2,6-Di-tert-butyl-p-cresol)
Transport Class
9
Packing Group
III
ADR

Read safety instructions, SDS and emergency procedures before handling.

IMDG

Read safety instructions, SDS and emergency procedures before handling.

IATA

Read safety instructions, SDS and emergency procedures before handling.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation) as amended. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended.

Chemical Safety Assessment Not performed

Follow national regulation for work with chemical agents.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for CGL-BHT/FAME?

The signal word is warning.

What is the physical form of CGL-BHT/FAME?

CGL-BHT/FAME is a liquid. with yellowish. color. It has not available. odor.

What is the solubility of CGL-BHT/FAME?

Insoluble.

What is CGL-BHT/FAME used for?

Antioxidant

What are the hazard statements for CGL-BHT/FAME?

This substance has 1 hazard statement:

  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of CGL-BHT/FAME?

The melting point is Not available. and the boiling point is Not available..