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Safety Data Sheet EN

FAME

CAS 67762-38-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
FAME
Product Code
002D5895
Synonyms
B100, B99, Fatty Acid Methyl Esters

Regulatory Identifiers

CAS Number
67762-38-3 Check regulations →
REACH No.
01-2119471664-32-0092

Identified Uses

Fuel additive component. Please refer to section 16 and/or the annexes for the registered uses under REACH.

Uses advised against

This product must not be used in applications other than those listed in Section 1 without first seeking the advice of the supplier.

Manufacturers & Suppliers

S

Shell Trading Rotterdam B.V.

manufacturer

Weena 70 3012 CM Rotterdam Netherlands

+31 10 441 5000

Emergency Contacts

Emergency Contact

+44 (0) 1235 239 670

24 hours per day, 7 days per week

National Poison Information Centre (NVIC)

+31(0)88 755 8000

24 hrs a day and 7 days a week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Contains methyl and ethyl esters from lipid sources.

Chemical Name CAS Number Concentration Hazardous
Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel) EC: 267-015-4 67762-38-3 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment.

Symptoms: If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever.

Skin contact

Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention.

Symptoms: Skin irritation signs and symptoms may include a burning sensation, redness, or swelling.

Eye contact

If persistent irritation occurs, obtain medical attention. Flush eye with copious quantities of water. Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision.

Ingestion

In general no treatment is necessary unless large quantities are swallowed, however, get medical advice.

Immediate Medical Attention

Call a doctor or poison control center for guidance.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable media

Do not use direct water jets on the burning product as they could cause a steam explosion and spread of the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

Specific hazards

A complex mixture of airborne solid and liquid particulates and gases (smoke).

Instructions

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Keep adjacent containers cool by spraying with water. If the fire cannot be extinguished the only course of action is to evacuate immediately.

Firefighter Protection

Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Shut off leaks, if possible without personal risks. Attempt to disperse the gas or to direct its flow to a safe location for example by using fog sprays.

Environmental

Prevent from spreading or entering into waterways, sewers, basements or confined areas.

Cleanup methods

Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly.

Materials: absorbent such as clay, sand or other suitable material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure that all local regulations regarding handling and storage facilities are followed. Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. When using do not eat or drink. Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires.

Storage

Keep container tightly closed and in a cool, well-ventilated place. Use properly labeled and closable containers. Protect from light.

Hygiene

Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.

Fire prevention

Properly dispose of any contaminated rags or cleaning materials in order to prevent fires.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated.

Hands

Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for >480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same but recognize that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model.

Eyes

If material is handled such that it could be splashed into eyes, protective eyewear is recommended. Approved to EU Standard EN166.

Respiratory

No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for the combination of organic gases and vapours and particles meeting EN14387 and EN143 [Filter type A/P for use against certain organic gases and vapours with a boiling point >65°C (149°F) and for use against particles].

Skin/Body

Skin protection is not ordinarily required beyond standard work clothes. It is good practice to wear chemical resistant gloves.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Undyed
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
Data not available
Ph
Not applicable
Melting Point
Data not available
Boiling Point
200 - 380 °C Method: Unspecified
Flash Point
>= 101 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Data not available
Vapor Pressure
0,425 kPa (25,0 °C) Method: Unspecified
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
860 - 900 kg/m3 (15,0 °C) Method: Unspecified
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
ca. 261 °C
Decomposition Temperature
Data not available
Solubility
---
Partition Coefficient
log Pow: Typical 6,2 (25 °C)
Solubility In Water
Data not available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
3,5 - 5 mm2/s (40,0 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of use.

Reactivity

Reacts with strong oxidising agents.

Hazardous reactions

Reacts with strong oxidising agents.

Avoid

Extremes of temperature and direct sunlight. In certain circumstances product can ignite due to static electricity.

Incompatible

Strong oxidising agents. Strong bases.

Decomposition

Hazardous decomposition products are not expected to form during normal storage. Combustion produces carbon monoxide, carbon dioxide along with thick smoke.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to daphnia and other aquatic invertebrates : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to algae/aquatic plants : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to fish (Chronic toxicity) : Remarks: Data not available Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : Remarks: Data not available Toxicity to microorganisms : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l

12.1 Toxicity

Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel): Toxicity to fish : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to daphnia and other aquatic invertebrates : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to algae/aquatic plants : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to microorganisms : Remarks: Practically non toxic: LL/EL/IL50 > 100 mg/l Toxicity to fish (Chronic toxicity) : Remarks: Data not available Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : Remarks: Data not available

12.2 Persistence and degradability

Product: Biodegradability : Remarks: Readily biodegradable. Components: Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel): Biodegradability : Remarks: Readily biodegradable. Not Persistent per IMO criteria. International Oil Pollution Compensation (IOPC) Fund definition: "A non-persistent oil is oil, which, at the time of shipment, consists of hydrocarbon fractions, (a) at least 50% of which, by volume, distills at a temperature of 340°C (645°F) and (b) at least 95% of which, by volume, distills at a temperature of 370°C (700°F) when tested by the ASTM Method D-86/78 or any subsequent revision thereof."

12.3 Bioaccumulative potential

Product: Bioaccumulation : Remarks: Does not have the potential to bioaccumulate significantly. Components:

Does not have the potential to bioaccumulate significantly.

12.3 Bioaccumulative potential

Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel): Bioaccumulation : Remarks: Does not have the potential to bioaccumulate significantly.

Does not have the potential to bioaccumulate significantly.

12.4 Mobility in soil

Product: Mobility : Remarks: If product enters soil, one or more constituents will be highly mobile and may contaminate groundwater. Components: Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel): Mobility : Remarks: If product enters soil, one or more constituents will be highly mobile and may contaminate groundwater.

12.5 Results of PBT and vPvB assessment

Assessment : The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and hence is not considered to be PBT or vPvB..

The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and hence is not considered to be PBT or vPvB.

12.6 Endocrine disrupting properties

no data available

12.7 Other adverse effects

Product: Additional ecological information : Will exert oxygen demand when significant quantities enter water-courses and may cause damage to aquatic life. Components: Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel): Additional ecological information : Will exert oxygen demand when significant quantities enter water-courses and may cause damage to aquatic life.

The product and the component Fatty acids, C16-18 and C18-unsatd., Me esters (FAME, Biodiesel) are noted to exert oxygen demand when significant quantities enter water-courses and may cause damage to aquatic life.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recover or recycle if possible. Waste product should not be allowed to contaminate soil or ground water, or be disposed of into the environment. Waste arising from a spillage or tank cleaning should be disposed of in accordance with prevailing regulations, preferably to a recognised collector or contractor.

Disposal

Recover or recycle if possible. Waste arising from a spillage or tank cleaning should be disposed of in accordance with prevailing regulations, preferably to a recognised collector or contractor.

Waste Codes

06 10 99 wastes not otherwise specified EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is FAME known by?

FAME is also known as: B100, B99, Fatty Acid Methyl Esters

What is the hazard signal word for FAME?

The signal word is no signal word.

What is the physical form of FAME?

FAME is a liquid with undyed color. It has characteristic odor.

What is FAME used for?

Fuel additive component. Please refer to section 16 and/or the annexes for the registered uses under REACH.

What is the melting point of FAME?

The melting point is Data not available and the boiling point is 200 - 380 °C Method: Unspecified.