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Safety Data Sheet EN

DL 521M

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DL 521M

Regulatory Identifiers

CAS Number
N/A

Identified Uses

For industrial use. Typically used as a binder.

Manufacturers & Suppliers

T

TRINSEO BELGIUM B.V.B.A.

manufacturer

HAVENLAAN 7, 3980 TESSENDERLO, BELGIUM

+31 115 67 2601

Emergency Contacts

Emergency Contact

+(32)-28083237

Belgium Poison Center

070/245.245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Styrene-butadiene based polymer --- 45 - 55% No
Water EC: 231-791-2 7732-18-5 40 - 50% No
3-(1,1-Dimethylethyl)-4-hydroxy-5-methylbenzenepropanoic acid, 1,1'-[1,2-Ethanediybis(oxy-2,1-ethanediyl)] ester EC: 253-039-2 36443-68-2 0.1 - 0.25% Yes
Sodium acrylate EC: 231-209-7 7446-81-3 0.1 - 0.15% Yes
1,2-benzisothiazol-3(2H)-one EC: 220-120-9 2634-33-5 0.02% Yes
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) 55965-84-9 0.0015% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Wash off with plenty of water.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion

No emergency medical treatment necessary.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam

Specific hazards

This material will not burn until the water has evaporated. Residue can burn. Upon burning, the dry product generates dense black smoke.

Instructions

If protective equipment is not available or not used, fight fire from a protected location or safe distance.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves)

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Cleanup methods

Recover spilled material if possible. If unable to recover, then proceed with appropriate cleanup methods. Collect in suitable and properly labeled containers. Water may be used for final cleaning of affected area.

Materials: Clay. Sand. Sawdust. Vermiculite.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid prolonged or repeated contact with skin. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.

Storage

Store between 4.4°C (40°F) and 43.3°C (110°F). May coagulate if frozen at 0°C (32°F). Material may develop bacteria odor on long term storage.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35mm. Other glove materials with a thickness of less than 0.35mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. In misty atmospheres, use an approved particulate respirator. Use the following CE approved air-purifying respirator: Particulate filter, type P2 (meeting standard EN 143).

Skin/Body

Wear clean, body-covering clothing.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dispersion
Colour
White
Colour Intensity
---
Form
---
Odor
Characteristic
Odor Threshold
No test data available
Ph
6,9 - 8,5 Method: Estimated.
Melting Point
0 °C Method: Literature (water)
Boiling Point
100 °C Method: Literature (based on water)
Flash Point
Method: Not applicable, closed cup water based product
Freezing Point
0 °C Method: Literature (water)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
17,5 mmHg (20 °C) Method: Literature (water)
Vapor Density
---
Relative Density
0,95 - 1,10 Method: Estimated.
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
No test data available
Lower Explosive Limit
No test data available
Explosive Limits
---
Auto Ignition Temperature
Method: Not applicable water based product
Decomposition Temperature
No test data available
Solubility
---
Partition Coefficient
No bioconcentration of the polymeric component is expected because of its high molecular weight. Latex dispersions will color water a milky white.
Solubility In Water
completely miscible Method: Visual
Solubility In Fat
---
Molecular Weight
Technically not possible to determine molecular weight
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
< 500 cSt Method: Estimated.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

Polymerization will not occur.

Avoid

Can coagulate if frozen. The dry resin is combustible.

Incompatible

Addition of chemicals, such as acids or multivalent metal salts, may cause coagulation.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials..

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

### Styrene-butadiene based polymer **Acute toxicity to fish** No relevant data found.

12.1 Toxicity

### 3-(1,1-Dimethylethyl)-4-hydroxy-5-methylbenzenepropanoic acid, 1,1'-[1,2-Ethanediybis(oxy-2,1-ethanediyl)] ester **Acute toxicity to fish** Toxicity to aquatic species occurs at concentrations above material's water solubility. **Acute toxicity to aquatic invertebrates** Toxicity to aquatic species occurs at concentrations above material's water solubility. NOEC, Daphnia magna (Water flea), 24 Hour, > 55 mg/l, Method Not Specified. **Acute toxicity to algae/aquatic plants** Toxicity to aquatic species occurs at concentrations above material's water solubility. EC50, alga Scenedesmus sp., 72 Hour, > 100 mg/l, Method Not Specified. **Toxicity to bacteria** IC50, activated sludge, 3 Hour, > 100 mg/l **Chronic toxicity to fish** NOEC, Fish, 32 Days, 0,0088 mg/l **Chronic toxicity to aquatic invertebrates** NOEC, Daphnia magna, 21 Days, 0,00055 mg/l

12.1 Toxicity

Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species). LC50, Oncorhynchus mykiss (rainbow trout), flow-through test, 96 Hour, 27 mg/l **Acute toxicity to algae/aquatic plants** EbC50, Pseudokirchneriella subcapitata (green algae), Biomass, 0,17 mg/l EC50, Desmodesmus subspicatus (green algae), 72 Hour, Growth rate inhibition, 0,205 mg/l **Chronic toxicity to aquatic invertebrates** NOEC, Daphnia magna (Water flea), flow-through test, 21 d, number of offspring, 19 mg/l NOEC, Daphnia magna (Water flea), flow-through test, 21 d, Immobilization, 3,8 mg/l

12.1 Toxicity

1,2-benzisothiazol-3(2H)-one Acute toxicity to algae/aquatic plants ErC50, Pseudokirchneriella subcapitata (green algae), static test, 72 Hour, 0,8 mg/l, OECD Test Guideline 201 or Equivalent NOEC, Pseudokirchneriella subcapitata (green algae), static test, 72 Hour, Growth rate, 0,21 mg/l, OECD Test Guideline 201 or Equivalent ErC50, diatom Skeletonema costatum, static test, 72 Hour, 0,36 mg/l, OECD Test Guideline 201 or Equivalent NOEC, diatom Skeletonema costatum, static test, 72 Hour, Growth rate, 0,15 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria EC50, Bacteria (active sludge), Respiration inhibition of activated sludge, 3 Hour, 28,52 mg/l

12.1 Toxicity

Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species). LC50, Oncorhynchus mykiss (rainbow trout), flow-through test, 96 Hour, 0,19 mg/l, OECD Test Guideline 203 or Equivalent LC50, Daphnia magna (Water flea), flow-through test, 48 Hour, 0,16 mg/l, OECD Test Guideline 202 or Equivalent EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, 0,027 mg/l, OECD Test Guideline 201 or Equivalent NOEC, Skeletonema costatum (marine diatom), static test, 72 Hour, Growth rate, 0,0014 mg/l Chronic toxicity to fish NOEC, Rainbow trout (Oncorhynchus mykiss), flow-through, 14 d, 0,05 mg/l Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna, flow-through test, 21 d, 0,1 mg/l

12.2 Persistence and degradability

Biodegradability: Although the polymers are not biodegradable, they would likely be removed in biological wastewater treatment plants by adsorption to biosolids.

The polymers are not biodegradable but are expected to be removed in biological wastewater treatment plants through adsorption to biosolids.

12.3 Bioaccumulative potential

Bioaccumulation: No bioconcentration of the polymeric component is expected because of its high molecular weight. Latex dispersions will color water a milky white.

No bioconcentration is expected due to the high molecular weight of the polymeric component.

12.4 Mobility in soil

No data available.

No data available.

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Endocrine disrupting potential : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

No relevant data found.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Contact the authorized waste disposal services.

Disposal

Any disposal practice must be in compliance with all local and national laws and regulations.

Waste Codes

Not specified The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product contains only components that have been either registered, are exempt from registration, are regarded as registered or are not subject to registration according to Regulation (EC) No. 1907/2006 (REACH). Polymers are exempted from registration under REACH.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DL 521M?

The signal word is no signal word.

What is the physical form of DL 521M?

DL 521M is a liquid appearing as dispersion with white color. It has characteristic odor.

What is DL 521M used for?

For industrial use. Typically used as a binder.

What are the hazard statements for DL 521M?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of DL 521M?

The melting point is 0 °C Method: Literature (water) and the boiling point is 100 °C Method: Literature (based on water).