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Safety Data Sheet EN

DESCALING LIQUID

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DESCALING LIQUID
Product Code
571653

Regulatory Identifiers

CAS Number
N/A

Identified Uses

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation.

Uses advised against

Not Applicable

Manufacturers & Suppliers

Wilhelmsen Ships Service AS logo

Wilhelmsen Ships Service AS

manufacturer

Strandveien 20 Lysaker 1366 Norway

+47 67 58 40 00

http://www.wilhelmsen.com/

Wilhelmsen Ships Service AS logo

Wilhelmsen Ships Service AS

manufacturer

Willem Barentszstraat 50 Rotterdam Netherlands

+31 10 4877 777

http://www.wilhelmsen.com

Emergency Contacts

Giftinformasjonssentralen - 24 timer

+47 22591300

24 timer

American Chemistry Council 24hrs - Chemtrec

+1 703 527 3887

24hrs

American Chemistry Council 24hrs - Chemtrec

(800) 424 9300

Dutch nat. poison centre

+ 31 30 274 88 88

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Symptoms: Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).

Skin contact

Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor.

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

Immediate Medical Attention

Transport to hospital or doctor without delay. Urgent hospital treatment is likely to be needed.

Medical Treatment

Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorised by him/her.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray or fog, Foam, Dry chemical powder, BCF (where regulations permit), Carbon dioxide.

Specific hazards

None known.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Use fire fighting procedures suitable for surrounding area. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Firefighter Protection

Wear full body protective clothing with breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

See section 8

Small spill

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.

Large spill

Chemical Class: acidic compounds, inorganic For release onto land: recommended sorbents listed in order of priority. Sorbent types: foamed glass - pillows, expanded mineral - particulate, foamed glass - particulate

Environmental

See section 12

Cleanup methods

Wipe up. Place in a suitable, labelled container for waste disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Contains low boiling substance: Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately. ▶ Check for bulging containers. ▶ Vent periodically ▶ Always release caps or seals slowly to ensure slow dissipation of vapours ▶ Avoid all personal contact, including inhalation. ▶ Wear protective clothing when risk of exposure occurs. ▶ Use in a well-ventilated area. ▶ WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material. ▶ Avoid smoking, naked lights or ignition sources. ▶ Avoid contact with incompatible materials. ▶ When handling, DO NOT eat, drink or smoke.

Storage

Store in original containers. ▶ Keep containers securely sealed. ▶ Store in a cool, dry, well-ventilated area. ▶ Store away from incompatible materials and foodstuff containers. ▶ Protect containers against physical damage and check regularly for leaks. ▶ Observe manufacturer's storage and handling recommendations contained within this SDS.

Hygiene

When handling, DO NOT eat, drink or smoke.

Fire prevention

Avoid smoking, naked lights or ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure.

Hands

Elbow length PVC gloves. When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

Eyes

Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories; spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is a danger of splashing, or if the material may be under pressure. ▶ Chemical goggles. whenever there is a danger of the material coming in contact with the eyes; goggles must be properly fitted. ▶ Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; these afford face protection. ▶ Alternatively a gas mask may replace splash goggles and face shields. ▶ Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.

Respiratory

Alternatively a gas mask may replace splash goggles and face shields.

Skin/Body

Overalls. PVC Apron. PVC protective suit may be required if exposure severe.

Environmental

See section 12

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid, pale yellow, soluble in water
Colour
---
Colour Intensity
---
Form
---
Odor
---
Odor Threshold
---
Ph
1
Melting Point
---
Boiling Point
~100-760 °C
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
105.5
Vapor Density
1.26
Relative Density
---
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Contact with alkaline material liberates heat

Reactivity

See section 7.2

Hazardous reactions

See section 7.2

Avoid

See section 7.2

Incompatible

alkaline material

Decomposition

See section 5.3

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

| hydrogen chloride | ENDPOINT | TEST DURATION (HR) | SPECIES | VALUE | SOURCE | | | LC50 | 96 | Fish | 70.057mg/L | 3 | | | EC50 | 96 | Algae or other aquatic plants | 344.947mg/L | 3 | | | NOEC | 0.08 | Fish | 10mg/L | 4 |

12.2. Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | --- | --- | --- |

12.2. Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | hydrogen chloride | LOW | LOW |

12.3. Bioaccumulative potential

| Ingredient | Bioaccumulation | | --- | --- |

12.3. Bioaccumulative potential

| Ingredient | Bioaccumulation | | hydrogen chloride | LOW (LogKOW = 0.5392) |

12.4. Mobility in soil

| Ingredient | Mobility | | --- | --- | | hydrogen chloride | LOW (KOC = 14.3) |

12.5. Results of PBT and vPvB assessment

| | P | B | T | | --- | --- | --- | --- | | Relevant available data | Not Applicable | Not Applicable | Not Applicable | | PBT Criteria fulfilled? | Not Applicable | Not Applicable | Not Applicable |

12.6. Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1789
Shipping Name
HYDROCHLORIC ACID
Transport Class
8
Packing Group
II
ADR

Hazard identification (Kemler) 80

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Hydrogen Chloride (7647-01-0) is found on various regulatory lists including EU IOELVs, ECICS, EINECS, and IARC monographs. This safety data sheet is in compliance with Directives 98/24/EC, 92/85/EEC, 94/33/EC, 2008/98/EC, 2010/75/EU; Commission Regulation (EU) 2015/830; and Regulation (EC) No 1272/2008.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DESCALING LIQUID?

The signal word is danger.

What is the physical form of DESCALING LIQUID?

DESCALING LIQUID is a liquid appearing as liquid, pale yellow, soluble in water .

What is DESCALING LIQUID used for?

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation.

What are the hazard statements for DESCALING LIQUID?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.