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Safety Data Sheet EN

DESCALING LIQUID

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DESCALING LIQUID
Product Code
571653
Chemical Name
Not Applicable
Synonyms
Pr No: 16178 (Norway)

Regulatory Identifiers

CAS Number
N/A
UFI Code
AY52-MNT5-X10Y-KT0V

Identified Uses

Industrial descaling and cleaning agent. This product is not intended for use as a biocidal product (e.g., disinfectant, sanitizer, or any antimicrobial application) or removal for sea squirts.

Uses advised against

No specific uses advised against are identified.

Manufacturers & Suppliers

Wilhelmsen Ships Service AS logo

Wilhelmsen Ships Service AS

distributor

Willem Barentszstraat 50 Rotterdam 3165AB Netherlands

+31 10 4877 777

https://www.wilhelmsen.com

Emergency Contacts

Centre Antipoisons

32070 245 245

24hrs - Chemwatch

+31-10-4877700

24hrs

Dutch nat. poison centre

+ 31 88 7558561

Dutch nat. poison centre

+ 31 10 4877700

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P234 Keep only in original packaging.
P260 Do not breathe mist/vapours/spray.
P264 Wash all exposed external body areas thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
hydrogen chloride EC: 231-595-7 7647-01-0 30 - 35% Yes

Notes

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; [e] Substance identified as having endocrine disrupting properties

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Symptoms: Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).

Skin contact

Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor.

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Irrigation should last at least 20-30 minutes. DO NOT use neutralising agents or any other additives.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

Immediate Medical Attention

Transport to hospital or doctor without delay.

Medical Treatment

Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling. Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Immediate dilution (milk or water) within 30 minutes post ingestion is recommended. Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Specific hazards

Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. May emit corrosive, poisonous fumes. May emit acrid smoke. Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Prevent, by any means available, spillage from entering drains or water course. Use fire fighting procedures suitable for surrounding area. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Firefighter Protection

Wear full body protective clothing with breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Minor Spills: Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal. Major Spills: Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling.

Small spill

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.

Large spill

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling.

Environmental

See section 12

Cleanup methods

Wipe up. Collect recoverable product into labelled containers for recycling.

Materials: sand, earth, inert material, vermiculite

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Check for bulging containers. Vent periodically. Always release caps or seals slowly to ensure slow dissipation of vapours. Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. WARNING: To avoid violent reaction. ALWAYS add material to water and NEVER water to material. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. DO NOT allow clothing wet with material to stay in contact with skin.

Storage

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks.

Hygiene

When handling, DO NOT eat, drink or smoke. DO NOT allow clothing wet with material to stay in contact with skin.

Fire prevention

Avoid smoking, naked lights or ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard 'physically' away from the worker and ventilation that strategically 'adds' and 'removes' air in the work environment.

Hands

Elbow length PVC gloves. The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when making a final choice.

Eyes

Safety glasses with unperforated side shields. Chemical goggles. Whenever there is a danger of the material coming in contact with the eyes; goggles must be properly fitted. [AS/NZS 1337.1, EN166 or national equivalent]. Full face shield (20 cm, 8 in minimum). Alternatively a gas mask may replace splash goggles and face shields.

Respiratory

Type B-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the 'Exposure Standard' (or ES), respiratory protection is required.

Skin/Body

Overalls. PVC Apron. PVC protective suit may be required if exposure severe. When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

Environmental

See section 12

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Partition Coefficient
Not Available
Upper Explosive Limit
Not Applicable
Physical State Data
liquid
Bulk Density
---
Odor
Not Available
Relative Density
1.16
Flammability
Not Applicable
Boiling Point
100 °C
Solubility In Water
Miscible
Relative Evaporation Rate
---
Softening Point
---
Vapor Pressure
105.5 kPa
Melting Point
-30 °C
Colour Intensity
---
Properties Status
---
Dynamic Viscosity
---
Solubility
Miscible
Lower Explosive Limit
Not Applicable
Explosive Limits
---
Molecular Weight
Not Applicable
State Under Standard Conditions
---
Decomposition Temperature
Not Applicable
Flash Point
Not Applicable
Solubility In Fat
---
Odor Threshold
Not Available
Freezing Point
-30 °C
Appearance
Liquid, pale yellow, soluble in water
Crystallisation Point
---
Physical State
Liquid
Cloud Point
---
Kinematic Viscosity
Not Applicable
Ph
1
Colour
pale yellow
Metal Corrosion
---
Auto Ignition Temperature
Not Applicable
Voc Content
Not Applicable
Form
Liquid
Evaporation Rate
Not Available BuAC = 1
Density
---
Solidification Point
---
Vapor Density
1.26
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Contact with alkaline material liberates heat

Reactivity

See section 7.2

Hazardous reactions

See section 7.2

Avoid

See section 7.2

Incompatible

See section 7.2

Decomposition

See section 5.3

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda-ash or soda-lime followed by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material).

Disposal

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1789
Shipping Name
HYDROCHLORIC ACID
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC, - 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Chemical Safety Assessment Not performed

Not Applicable

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is DESCALING LIQUID known by?

DESCALING LIQUID is also known as: Pr No: 16178 (Norway)

What is the hazard signal word for DESCALING LIQUID?

The signal word is danger.

What is the physical form of DESCALING LIQUID?

DESCALING LIQUID is a liquid appearing as liquid, pale yellow, soluble in water with pale yellow color. It has not available odor.

What is the solubility of DESCALING LIQUID?

Miscible

What is DESCALING LIQUID used for?

Industrial descaling and cleaning agent. This product is not intended for use as a biocidal product (e.g., disinfectant, sanitizer, or any antimicrobial application) or removal for sea squirts.

What are the hazard statements for DESCALING LIQUID?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.

What is the melting point of DESCALING LIQUID?

The melting point is -30 °C and the boiling point is 100 °C.