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Safety Data Sheet EN

CLR BRANDS® – CALCIUM, LIME, RUST

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CLR BRANDS® – CALCIUM, LIME, RUST
Synonyms
CLR BRANDS® – CALCIUM, LIME & RUST REMOVER

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from Hard Surfaces

Uses advised against

Incompatible with strong oxidizing agents, metals (except stainless steel and chrome), acids, bases, and bleach.

Manufacturers & Suppliers

J

Jelmar, LLC

manufacturer

5550 W. Touhy Ave. Skokie, IL 60077 USA

1(847) 675-8400

Emergency Contacts

Emergency Contact

1(800) 323-5497

8:30 A.M. – 4:30 P.M. CST Monday – Friday

Chemtrec

1(800) 424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H319 Causes serious eye irritation.

Precautionary Statements

P102 Keep out of reach of children.
P262 DO NOT get in eyes, on skin or clothing.
P264 Wash skin thoroughly after handling.
P280 Wear eye protection/face protection.
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice.
P362 + P364 Take off contaminated clothing and wash it before reuse.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Mixtures

Chemical Name CAS Number Concentration Hazardous
Lactic Acid 79-33-4 10 - 20% Yes
Lauramine Oxide 1643-20-5 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY.

Skin contact

Immediately rinse thoroughly with water for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse.

Symptoms: skin irritation, redness, discomfort and itching.

Eye contact

Immediately rinse thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Symptoms: stinging, redness, tearing, and blurred vision of the eyes.

Ingestion

If swallowed, DO NOT induce vomiting, drink a glass of water followed with milk. Call POISON CENTER or doctor immediately. NEVER give an unconscious person anything to ingest.

Symptoms: oral burns, vomiting and gastrointestinal disturbance.

Immediate Medical Attention

If eye irritation persists: Get medical advice. If irritation persists, get medical attention. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. Call POISON CENTER or doctor immediately.

Medical Treatment

Provide general supportive measures and treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, dry chemical, alcohol-resistant foam or carbon dioxide.

Unsuitable media

None known.

Specific hazards

Thermal decomposition can lead to irritating gases and vapors.

Instructions

Use water spray to cool fire-exposed containers.

Firefighter Protection

Wear protective NIOSH-approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with skin and eyes. Ensure adequate ventilation. Avoid breathing vapors or mist. Use personal protective equipment, see Section 8. Isolate area and deny entry to unnecessary and unprotected personnel.

Small spill

No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Area may be slippery. Wear rubber gloves.

Large spill

Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Flush residue with large amount of water. Area may be slippery. Dispose of collected material according to local, state, and federal regulations. Avoid direct discharge to sewers and surface waters.

Environmental

Avoid direct discharge to sewers and surface waters.

Cleanup methods

Flush spill area with water; Flush residue with large amount of water.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes, skin, or clothing. Use appropriate personal protective equipment (see Section 8). Use with adequate ventilation. Avoid breathing vapors or mist. Observe good industrial hygiene practices when handling this material. Do not eat, drink, or smoke in work area. Wash hands thoroughly after use. Avoid exposure to excess heat. DO NOT MIX WITH OTHER HOUSEHOLD CLEANERS OR CHEMICALS INCLUDING BLEACH, AS TOXIC FUMES MAY RESULT. Keep out of reach of children.

Storage

Store in cool, well-ventilated area, away from heat. Prevent from freezing. Keep containers tightly closed. Store in original containers in a secure area away from children and pets.

Hygiene

Observe good industrial hygiene practices when handling this material. Do not eat, drink, or smoke in work area. Wash hands thoroughly after use.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
Lime green
Colour Intensity
---
Form
---
Odor
Slightly acidic
Odor Threshold
---
Ph
2.1 – 2.3
Melting Point
N.D.
Boiling Point
99°C/210°F
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
N.D.
Vapor Pressure
N.D.
Vapor Density
---
Relative Density
1.04 – 1.06
Bulk Density
---
Density
---
Flammability
Not Flammable
Upper Explosive Limit
N.A.
Lower Explosive Limit
N.A.
Explosive Limits
---
Auto Ignition Temperature
N.A.
Decomposition Temperature
N.A.
Solubility
100%
Partition Coefficient
N.D.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
N.D.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal storage conditions.

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous reactions

None known.

Avoid

Avoid elevated temperatures. DO NOT MIX WITH OTHER HOUSEHOLD CLEANERS OR CHEMICALS INCLUDING BLEACH, AS TOXIC FUMES MAY RESULT.

Incompatible

Strong oxidizing agents, metals (except stainless steel and chrome), acids, bases, and bleach.

Decomposition

Thermal decomposition can lead to release of irritating gases, vapors and carbon oxides. In the event of fire: see Section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Constituent: Lactic Acid Fish (Oncorhynchus mykiss) 96h LC50: 130 mg/L Crustacea (Daphnia magna) 48h EC50: 130 mg/L Algae (Pseudokirchnerella subcapitata) 72h EC50: 3.5 g/L (growth rate) Microorganisms (Activated Sludge) 3h EC50: >88.2 mg/L

12.1 Toxicity

| Constituent | Organism and Species | Results | | --- | --- | --- | | Lauramine Oxide | Fish (Danio rerio) | 96h LC50: 31.8 mg/L | | | Fish (Pimephales promelas) | 120d LC50: 0.87 mg/L | | | Crustacea (Daphnia magna) | 48h EC50: 3.9 mg/L | | | Crustacea (Daphnia magna) | 21d LC50: 0.96 mg/L | | | Algae (Pseudokirchnerella subcapitata) | 72h EC50: 0.20 mg/L | | | Microorganisms (Pseudomonas putida) | 18h EC10: 24 mg/L |

12.2 Persistence and degradability

Readily biodegradable: 75% (OECD 301B)

12.2 Persistence and degradability

Readily biodegradable: 95.3% (OECD 301B)

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

| Constituent | Log Pow | Bioconcentration Factor (BCF) | | --- | --- | --- | | Lactic Acid | -0.54 | No data |

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

Constituent: Lauramine Oxide, Log Pow: 1.85 @ 20 °C, Bioconcentration Factor (BCF): No data

Mobility in soil

No information available.

PBT and vPvB assessment

Not considered to be PBT or vPvB.

Other Adverse Effects

No information available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

dispose of unused product in a permitted hazardous waste management facility

Disposal

For Industrial use, dispose of unused product in a permitted hazardous waste management facility following all local, state, and federal regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is CLR BRANDS® – CALCIUM, LIME, RUST known by?

CLR BRANDS® – CALCIUM, LIME, RUST is also known as: CLR BRANDS® – CALCIUM, LIME & RUST REMOVER

What is the hazard signal word for CLR BRANDS® – CALCIUM, LIME, RUST?

The signal word is warning.

What is the physical form of CLR BRANDS® – CALCIUM, LIME, RUST?

CLR BRANDS® – CALCIUM, LIME, RUST is a liquid appearing as liquid with lime green color. It has slightly acidic odor.

What is the solubility of CLR BRANDS® – CALCIUM, LIME, RUST?

100%

What is CLR BRANDS® – CALCIUM, LIME, RUST used for?

Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from Hard Surfaces

What are the hazard statements for CLR BRANDS® – CALCIUM, LIME, RUST?

This substance has 2 hazard statements:

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.

What is the melting point of CLR BRANDS® – CALCIUM, LIME, RUST?

The melting point is N.D. and the boiling point is 99°C/210°F.