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Safety Data Sheet EN

EBECRYL® 1200 radiation curing resins

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
EBECRYL® 1200 radiation curing resins

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Coatings & Inks

Manufacturers & Suppliers

Allnex USA Inc. logo

Allnex USA Inc.

manufacturer

9005 Westside Parkway, Alpharetta, Georgia 30009, USA

http://www.allnex.com/contact

Emergency Contacts

Emergency Contact

+1-866-928-0789

Carechem 24 - Allnex29003-NCEC

+1-215-207-0061

24 hours/day

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Repr. Cat. 2
STOT SE Cat. 3
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Aquatic Acute Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
H361 Suspected of damaging fertility or the unborn child
H412 Harmful to aquatic life

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash face, hands and any exposed skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this label).
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use CO2, dry chemical, or foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local and national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Butyl acetate 123-86-4 45 - 50% Yes
Acrylic acid 79-10-7 1% Yes
4-Methoxyphenol 150-76-5 0.2% Yes
Acrylated resin --- 50 - 60% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms.

Skin contact

Remove contaminated clothing and shoes without delay. Wash immediately with plenty of water. Do not reuse contaminated clothing without laundering. Get medical attention if pain or irritation persists after washing or if signs and symptoms of overexposure appear.

Symptoms: pain or irritation

Eye contact

Rinse immediately with plenty of water for at least 15 minutes. Obtain medical advice if there are persistent symptoms.

Ingestion

If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical attention.

Medical Treatment

No specific measures have been identified.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol foam, carbon dioxide or dry chemical to extinguish fires. Water stream may be ineffective.

Unsuitable media

high pressure water jet.

Specific hazards

Keep containers cool by spraying with water if exposed to fire.

Firefighter Protection

Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See SDS Section 8 (Exposure Controls/Personal Protection).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Avoid release to the environment.

Cleanup methods

Sweep up and place in a waste disposal container. Flush spill area with water.

Materials: Inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, sparks and open flame. - No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting and other equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves and eye/face protection. Wash hands thoroughly after handling. Avoid release to the environment. Use only outdoors or in a well-ventilated area. Avoid breathing vapors or spray mist.

Storage

Protect from direct sunlight and all heat sources in order to avoid sintering. Keep away from sources of ignition - refrain from smoking.

Hygiene

Wash hands thoroughly after handling.

Fire prevention

Keep away from heat, sparks and open flame. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Observe the general rules of industrial fire protection.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure.

Eyes

Wear eye/face protection such as chemical splash proof goggles or face shield.

Respiratory

For operations where inhalation exposure can occur use an approved respirator. Recommendations are listed below. Other protective respiratory equipment may be used based on user's own risk assessment. Recommended respirators include those certified by NIOSH. Recommended: Full Face Mask with organic vapor cartridge, Type A filter (BP >65°C)

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
clear liquid
Colour
yellowish
Colour Intensity
---
Form
---
Odor
ester
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
100 - 200 °C
Flash Point
22 °C Setaflash Closed Cup
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 1.33 hPa @ 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1.075 g/cm³
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Viscous liquid
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable.

Reactivity

No information available

Hazardous reactions

May occur. Hazardous polymerization can occur when exposed to direct sunlight. Hazardous exothermic polymerization can occur when heated. Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers

Avoid

Avoid exposure to strong UV sources. Avoid friction with temperature increase as result. Avoid direct contact with heat sources. Avoid temperatures higher than 60°C. Protect from direct sunlight. Take precautionary measures against static discharges.

Incompatible

Avoid free radical producing initiators. Avoid contact with peroxides. Avoid contact with reactive metals. Contact with alkalis. They give an exothermic reaction with the product. Unintentional contact with them should be avoided.

Decomposition

oxides of carbon smoke soot

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

log Kow = 1.3

TOXICITY

Overall Environmental Toxicity: Harmful to aquatic life. The ecological assessment for this material is based on an evaluation of its components.

The product is classified as harmful to aquatic life based on component evaluation.

RESULTS OF PBT AND vPvB ASSESSMENT

Not determined

The PBT and vPvB assessment has not been determined.

12.1 Toxicity

LC50 17 - 19 mg/L - Pimephales promelas (96h) LC50 = 100 mg/L - Lepomis macrochirus (96h) LC50 = 62 mg/L - Leuciscus idus (96h)

12.1 Toxicity

Acrylic acid (79-10-7) | LC50 = 222 mg/L - Brachydanio rerio (96h)

12.1 Toxicity

4-Methoxyphenol (150-76-5) | LC50 = 28.5 mg/L - Oncorhynchus mykiss (96hrs) LC50 = 84.3 mg/L - Pimephales promelas (96hrs)

12.1 Toxicity

EC50 = 72.8 mg/L - Daphnia magna (24h)

12.1 Toxicity

Acrylic acid (79-10-7) | LC50 = 270 mg/L - Daphnia magna (24h) EC50 = 95 mg/L - Daphnia magna (48h)

12.1 Toxicity

EC50 = 3 mg/L - Daphnia magna (48hrs) NOEC = 1.32 mg/L - Daphnia magna (48hrs)

12.1 Toxicity

EC50 = 674.7 mg/L - Desmodesmus subspicatus (72h)

12.2 Persistence and degradability

Not available

12.3 Bioaccumulative potential

Not available

12.4 Mobility in soil

Not available

12.5 Results of PBT and vPvB assessment

Not available

12.6 Endocrine disrupting properties

Not available

12.7 Other adverse effects

Not available

12.1 Toxicity

EC50 = 0.04 mg/L - Desmodesmus subspicatus (72h) EC50 = 0.17 mg/L - Pseudokirchneriella subcapitata (96h)

12.1 Toxicity

4-Methoxyphenol (150-76-5) | EC50 = 54.7 mg/L - Pseudokirchneriella subcapitata (72hrs)

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Partition coefficient: 1.81

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Partition coefficient: 0.38 - 0.46

12.4 Mobility in soil

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

thermal treatment or incineration at EPA approved facilities

Disposal

The Company encourages the recycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1866
Shipping Name
RESIN SOLUTION
Transport Class
3
Packing Group
II
IMDG

Protect against external heat sources higher than +40°C/104°F.

IATA

Protect against external heat sources higher than +40°C/104°F.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for EBECRYL® 1200 radiation curing resins?

The signal word is danger.

What is the physical form of EBECRYL® 1200 radiation curing resins?

EBECRYL® 1200 radiation curing resins is a liquid appearing as clear liquid with yellowish color. It has ester odor.

What is EBECRYL® 1200 radiation curing resins used for?

Coatings & Inks

What are the hazard statements for EBECRYL® 1200 radiation curing resins?

This substance has 6 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H336: May cause drowsiness or dizziness
  • H361: Suspected of damaging fertility or the unborn child
  • H412: Harmful to aquatic life