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Safety Data Sheet EN

Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur

CAS 75-09-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur
Product Code
1.06050
Chemical Name
Dichloromethane

Regulatory Identifiers

CAS Number
75-09-2 Check regulations →
REACH No.
01-2119480404-41-XXXX

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

M

Merck Life Science UK Limited

national supplier

New Road, The Old Brickyard, GILLINGHAM, Dorset, SP8 4XT, UNITED KINGDOM

+44 (0)1747 833-000

Emergency Contacts

CHEMTREC

+44 (0)870 8200418

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Carc. Cat. 2 H351
STOT SE Cat. 3 H336

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing mist or vapours.
P264 Wash skin thoroughly after handling.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Dichloromethane EC: 200-838-9 75-09-2 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Hydrogen chloride gas. Not combustible. Fire may cause evolution of: Hydrogen chloride gas, Phosgene. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Protected from light. Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). - Splash contact - Material: Viton® - Minimum layer thickness: 0.7 mm - Break through time: 120 min - Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M)

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter AX (EN 371) The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
ether-like
Odor Threshold
---
Ph
No data available
Melting Point
Melting point/ range: -95 °C at 1,013 hPa
Boiling Point
40 °C at 1,013 hPa
Flash Point
does not flash
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
584 hPa at 25 °C
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
1.33 g/cm3 at 20 °C
Flammability
---
Upper Explosive Limit
22 % (V)
Lower Explosive Limit
13 % (V)
Explosive Limits
---
Auto Ignition Temperature
605 °C at 1,013 hPa - DIN 51794
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
log Pow: 1.25 at 20 °C - Bioaccumulation is not expected. n-octanol/water
Solubility In Water
13.2 g/l at 25 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.42 mPa.s at 25 °C
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). Contains the following stabiliser(s): 2-methyl-2-butene (0.002 %)

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Alkali metals, nitrogen oxides, nitrogen dioxide, Potassium, sodium azide, perchloric acid, Nitric acid, aluminium chloride, Amines, Oxygen (as liquefied gas), powdered aluminium, sodium, aromatic hydrocarbons, with powdered aluminium. Exothermic reaction with: Alkaline earth metals, Powdered metals, amides, alcoholates, nonmetallic oxides, potassium tert-butanolate, sodium amide, Lithium.

Avoid

no information available

Incompatible

No data available

Decomposition

For Hazardous combustion products in the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

- Toxicity to fish: flow-through test LC50 - Pimephales promelas (fathead minnow) - 193.00 mg/l - 96 h - Remarks: (ECHA) - Toxicity to daphnia and other aquatic invertebrates: static test LC50 - Daphnia magna (Water flea) - 27 mg/l - 48 h (US-EPA) - Toxicity to bacteria: static test EC50 - activated sludge - 2,590 mg/l - 40 min (OECD Test Guideline 209) - Toxicity to: flow-through test LC50 - Pimephales promelas (fathead minnow) - Millipore- 1.06050 The life science business of Merck operates as MilliporeSigma in the US and Canada Merck fish(Chronic toxicity) 471 mg/l - 8 d Remarks: (ECHA)

12.2 Persistence and degradability

Biodegradability aerobic - Exposure time 28 d Result: 68 % - Readily biodegradable. (OECD Test Guideline 301D)

12.3 Bioaccumulative potential

12.3 Bioaccumulative potential

Bioaccumulation Cyprinus carpio (Carp) - 6 Weeks - 250 µg/l (Dichloromethane) Bioconcentration factor (BCF): 2 - 5.4 (OECD Test Guideline 305) Cyprinus carpio (Carp) - 6 Weeks - 25 µg/l (Dichloromethane) Bioconcentration factor (BCF): 6 - 40 (OECD Test Guideline 305)

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

No data available

No data available

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste.

Disposal

Leave chemicals in original containers. No mixing with other waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1593
Shipping Name
DICHLOROMETHANE
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The signal word is warning.

What is the physical form of Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a liquid with colourless color. It has ether-like odor.

What is Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?

Reagent for analysis

What are the hazard statements for Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

This substance has 4 hazard statements:

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.

What is the melting point of Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The melting point is Melting point/ range: -95 °C at 1,013 hPa and the boiling point is 40 °C at 1,013 hPa.