NextSDS Logo
Safety Data Sheet EN

Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur

CAS 67-66-3

Keep this SDS organized and up to date

Add this SDS to your NextSDS library and keep all its safety information in one place.

Add to my SDS library for free
01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur
Product Code
1.02445, 102445
Chemical Name
Chloroform

Regulatory Identifiers

CAS Number
67-66-3 Check regulations →
REACH No.
01-2119486657-20-XXXX

Identified Uses

Reagent for analysis Chemical production

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

Frankfurter Str. 250, D-64271 DARMSTADT

+49 (0)6151 72-0

Emergency Contacts

CHEMTREC (GB)

+(44)-870-8200418

CHEMTREC Ireland

+(353)-19014670

CHEMTREC India

001-803-017-9114

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Carc. Cat. 2 H351
Repr. Cat. 2 H361d
STOT SE Cat. 3 H336
STOT RE Cat. 1 H372

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Still copying SDS data manually?Free

You don't have to. NextSDS reads this SDS and adds the information to your library automatically.

Let NextSDS do it for me
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Chloroform EC: 200-663-8 67-66-3 100% Yes
ethanol EC: 200-578-6 64-17-5 1 - 10% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Immediate Medical Attention

Immediately call in physician for inhalation. Consult a physician for skin contact and ingestion. Call in ophthalmologist for eye contact.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Hydrogen chloride gas. Not combustible. Fire may cause evolution of: Hydrogen chloride gas, Phosgene. Ambient fire may liberate hazardous vapours.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Protected from light. Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M) Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 10 min Material tested: Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
sweet
Odor Threshold
---
Ph
No data available
Melting Point
60,5 - 61,5 °C at 1.013,25 hPa
Boiling Point
60,5 - 61,5 °C at 1.013,25 hPa
Flash Point
- Regulation (EC) No. 440/2008, Annex, A.9 does not flash
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
210 hPa at 20 °C
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
1,49 g/cm³ at 25 °C
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
Distillable in an undecomposed state at normal pressure.
Solubility
organic solvent at 20 °C - miscible
Partition Coefficient
No data available
Solubility In Water
8,7 g/l at 23 °C - OECD Test Guideline 105- soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). Contains the following stabilizer(s): ethanol (1 %)

Reactivity

No data available

Hazardous reactions

Risk of explosion with: Ammonia, Amines, nitrogen oxides, bases, Oxygen, alkali amides, organic nitro compounds, strong alkalis, Fluorine, peroxi compounds, Alkaline earth metals, Alkali metals, Powdered metals, Methanol with alcoholates, Methanol with strong alkalis, Iron in powder form, magnesium in powder form, various alloys, sensitive to shock, Methanol with Sodium hydroxide, Oxygen with alkali compounds, Aluminum in powder form, Acetone with alkali compounds, Potassium sensitive to shock, phosphines, bis(dimethylamino)dimethyl tin, nonmetallic hydrogen compounds, Powdered metals, Light metals, Ketones, mineral acids, Strong oxidizing agents, semimetallic hydrogen compounds, sodium sensitive to shock. Violent reactions possible with:

Avoid

Sensitivity to light, heat-sensitive

Incompatible

Ammonia, Amines, nitrogen oxides, bases, Oxygen, alkali amides, organic nitro compounds, strong alkalis, Fluorine, peroxi compounds, Alkaline earth metals, Alkali metals, Powdered metals, Methanol, alcoholates, Sodium hydroxide, alkali compounds, Aluminum, Acetone, Potassium, phosphines, bis(dimethylamino)dimethyl tin, nonmetallic hydrogen compounds, Light metals, Ketones, mineral acids, Strong oxidizing agents, semimetallic hydrogen compounds, sodium

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to algae static test ErC50 - Chlamydomonas reinhardtii (green algae) - 13,3 mg/l - 72 h (Chloroform) Remarks: (ECHA) (Chloroform) Toxicity to bacteria Remarks: (ECHA) Millipore- 1.02445 The life science business of Merck operates as MilliporeSigma in the US and Canada Page 11 of 15 (Chloroform) Toxicity to fish (Chronic toxicity) flow-through test NOEC - Oryzias latipes - 0,15 mg/l - 9 Months (Chloroform) Remarks: (ECHA)

12.1 Toxicity

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) semi-static test NOEC - Daphnia magna (Water flea) - 6,3 mg/l - 21 d (Chloroform) Remarks: (ECHA)

12.2 Persistence and degradability

No data available

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture does not meet the criteria for PBT or vPvB.

12.6 Endocrine disrupting properties

Assessment: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

No data available

No data available

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1888
Shipping Name
CHLOROFORM
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The signal word is danger.

What is the physical form of Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a liquid with colorless color. It has sweet odor.

What is the solubility of Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

organic solvent at 20 °C - miscible

What is Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?

Reagent for analysis Chemical production

What are the hazard statements for Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

This substance has 8 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H331: Toxic if inhaled.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • H361d: Suspected of damaging the unborn child.
  • H372: Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed.

What is the melting point of Chloroform for analysis EMSURE® ACS,ISO,Reag. Ph Eur?

The melting point is 60,5 - 61,5 °C at 1.013,25 hPa and the boiling point is 60,5 - 61,5 °C at 1.013,25 hPa.