Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur
- Product Code
- 1.06009, 106009
- Chemical Name
- Methanol
Regulatory Identifiers
- CAS Number
- 67-56-1 Check regulations →
- REACH No.
- 01-2119433307-44-XXXX
Identified Uses
Reagent for analysis, Solvent, Chemical production
Manufacturers & Suppliers
Merck KGaA
manufacturer
Frankfurter Str. 250, D-64271 DARMSTADT
+49 (0)6151 72-0
Emergency Contacts
CHEMTREC (GB)
+(44)-870-8200418
CHEMTREC Ireland
+(353)-19014670
CHEMTREC India
001-803-017-9114
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS06
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Methanol EC: 200-659-6 | 67-56-1 | 100% | Yes |
First Aid Measures
Emergency procedures for chemical exposure incidents
Move to fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Fresh air. Make victim drink ethanol (e.g. 1 drinking glass of a 40% alcoholic beverage). Call a doctor immediately (mention methanol ingestion). Only in exceptional cases, if no medical care is available within one hour, induce vomiting (only in fully conscious persons) and make victim drink ethanol again (approx. 0.3 ml of a 40% alcoholic beverage/kg body weight/hour).
Immediate Medical Attention
Call a physician immediately.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water, Foam, Carbon dioxide (CO2), Dry powder
For this substance/mixture no limitations of extinguishing agents are given.
Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at ambient temperatures.
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Firefighter Protection
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.
Do not let product enter drains. Risk of explosion.
Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.
Materials: liquid-absorbent material (e.g. Chemizorb®)
Related Products
Similar products with comparable safety profiles
Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 67-56-1
Dichloromethane for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 75-09-2
Ethanol absolute for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 64-17-5
Ethanol absolute for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 64-17-5
Ethanol absolute for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 64-17-5
Ethanol absolute for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 64-17-5
Ethanol absolute for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 64-17-5
Ethanol absolute for analysis EMSURE® ACS,ISO,Reag. Ph Eur
CAS: 64-17-5
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Keep container tightly closed in a dry and well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label.
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Full contact: Material: butyl-rubber, Minimum layer thickness: 0,7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). Splash contact: Material: Viton®, Minimum layer thickness: 0,7 mm, Break through time: 120 min, Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Flame retardant antistatic protective clothing.
Do not let product enter drains. Risk of explosion.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is chemically stable under standard ambient conditions (room temperature).
Vapors may form explosive mixture with air.
Risk of explosion with: Oxidizing agents, perchloric acid, perchlorates, salts of oxyhalogenic acids, chromium(VI) oxide, halogen oxides, nitrogen oxides, nonmetallic oxides, chromosulfuric acid, chlorates, hydrides, zinc diethyl, halogens, powdered magnesium, hydrogen peroxide, Nitric acid, sulfuric acid, permanganic acid, sodium hypochlorite. Exothermic reaction with: acid halides, Acid anhydrides, Reducing agents, acids, Bromine, Chlorine, Chloroform, magnesium, tetrachloromethane. Risk of ignition or formation of inflammable gases or vapours with: Fluorine, Oxides of phosphorus, Raney-nickel. Generates dangerous gases or fumes in contact with: Alkaline earth metals, Alkali metals.
Warming.
various plastics, magnesium, zinc alloys
In the event of fire: see section 5
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
12.4 Mobility in soil
The substance will not adsorb on soil.
12.5 Results of PBT and vPvB assessment
The substance/mixture does not contain components meeting PBT or vPvB criteria at levels of 0.1% or higher.
12.6 Endocrine disrupting properties
The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.
12.7 Other adverse effects
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
No data available
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 1230
- Shipping Name
- METHANOL
- Transport Class
- 3 (6.1)
- Packing Group
- II
Regulatory Information
Chemical regulations, safety assessments, and compliance status
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
The signal word is danger.
What is the physical form of Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur is a liquid with colorless color. It has characteristic odor.
What is Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur used for?
Reagent for analysis, Solvent, Chemical production
What are the hazard statements for Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
This substance has 3 hazard statements:
- H225: Highly flammable liquid and vapor.
- H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
- H370: Causes damage to organs (Eyes, Central nervous system).
What is the melting point of Methanol for analysis EMSURE® ACS,ISO,Reag. Ph Eur?
The melting point is -97,8 °C - (ECHA) and the boiling point is 64,7 °C at 1.013 hPa - (ECHA).