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Safety Data Sheet EN

BELZONA® 1111 (SUPER METAL) SOLIDIFIER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
BELZONA® 1111 (SUPER METAL) SOLIDIFIER
Product Code
SN2598

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.

Uses advised against

The product should not be used for purposes other than those recommended in the appropriate Instructions For Use (IFU) leaflet.

Manufacturers & Suppliers

B

Belzona Polymerics Limited

manufacturer

Claro Road, Harrogate, HG1 4DS, United Kingdom

+44 1423 567641

Emergency Contacts

ChemTel

+1 813-248-0585

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P260 Do not breathe vapours.
P273 Avoid release to the environment.
P280 Wear protective clothing, gloves, eye and face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
DIETHYLENETRIAMINE EC: 203-865-4 111-40-0 10 - 30% Yes
BENZYL ALCOHOL EC: 202-859-9 100-51-6 5 - 15% Yes
FORMALDEHYDE POLYMER WITH 1,3-BENZENEDIMETHANAMINE AND PHENOL EC: 500-137-0 57214-10-5 --- Yes
M-PHENYLENEBIS(METHYLAMINE) EC: 216-032-5 1477-55-0 --- Yes
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL EC: 202-013-9 90-72-2 --- Yes
TRIMETHYLHEXANE-1,6-DIAMINE EC: 247-134-8 25620-58-0 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth.

Symptoms: Exposure to vapours may result in irritation of the mucous membrane and the respiratory system; in severe cases burns may occur.

Skin contact

Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. If irritation or inflammation persists, seek medical attention.

Symptoms: irritation or inflammation

Eye contact

Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek medical advice.

Symptoms: Contact with eyes may cause severe irritation with corneal injury, which may result in permanent impairment of vision.

Ingestion

If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with plenty of water. Do NOT induce vomiting.

Symptoms: May cause chemical burns in mouth, oesophagus and stomach.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical attention. If accidentally swallowed obtain immediate medical attention.

Medical Treatment

None.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger fires.

Unsuitable media

Do NOT use water jet.

Specific hazards

In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen and ammonia may be produced.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

Appropriate self-contained breathing apparatus may be required.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Exclude non-essential personnel. Keep up-wind of spill to avoid breathing vapours. Do not get on skin or in eyes.

Environmental

Prevent spills from entering drains or sewers.

Cleanup methods

Scrape the majority of the product into a suitable labelled container. Clean surfaces down with a water and detergent mixture.

Materials: water and detergent mixture

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep the container tightly closed when not in use. Vapours may collect in the container headspace during transit or prolonged storage. Avoid the inhalation of vapour when opening the container. Where possible open containers and mix components in a well ventilated place away from the application area. Exclude non-essential personnel. Minimise the number of employees exposed and the duration of their exposure. Do not get on skin or in eyes. Always keep in containers made of the same material as the supply container. Ensure emergency equipment (for fires, spills, leaks, etc.) is readily available.

Storage

Store between 5 °C and 30 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.

Hygiene

Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where necessary, contaminated work clothing and shoes should be removed to prevent cross contamination of surfaces and the risk of inadvertent skin contact and ingestion. Smoking, eating and drinking should be prohibited in areas of storage and use.

Fire prevention

This product is combustible. Exclude sources of heat, sparks and open flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see 'Respiratory protection' below).

Hands

Hand protection should be selected in accordance with EN 374 Protective gloves against chemicals. The breakthrough time of the gloves selected should exceed the expected use period. Where this is not possible gloves should be changed in good time, and in any case before the breakthrough time is exceeded. If any doubt exists, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. SPECIFIC RECOMMENDATIONS Wear protective gloves made of the following material: Neoprene. Nitrile rubber. STANDARD APPLICATIONS Medium-heavy weight gauntlet type gloves that provide wrist protection are suitable. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS Light weight disposable gloves are normally suitable.

Eyes

It is recommended that eye protection, for example safety spectacles or goggles are worn at all times during the handling and use of this material. Eye protection should be selected in accordance with EN 166 Personal eye protection. During subsequent machining, grinding, abrasion or removal of this product appropriate eye protection should be selected according to the type of tools or equipment used.

Respiratory

Respiratory protection is not normally required but it may be required when this product is used in confined spaces or where adequate ventilation cannot be achieved. It is essential that the concentration of the contaminant(s) in the application environment does not exceed the applicable Occupational Exposure Limit(s) (OELs) multiplied by the Assigned Protection Factor (APF) quoted for the respiratory protective equipment selected. Where necessary, it is recommended that respiratory protective equipment that complies with EN 136 (full face mask) or EN 140 (half face mask) should be worn in combination with an organic/inorganic vapours, acid gases and ammonia cartridge (ABEK1). Where the application environment is likely to be contaminated by significant concentrations of dust then the appropriate particulate prefilter (N-, R- or, P-series) should be worn in combination with the above. It is essential that the facepiece is correctly fitted and the filter is changed in accordance with the manufacturer's instructions.

Skin/Body

STANDARD APPLICATIONS Synthetic polyethylene coveralls such as the Tyvek PROTECH® or equivalent coveralls manufactured to EN 13034 Type 6, Protective clothing against liquid chemicals. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS Cotton overalls are normally suitable.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Paste
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Paste.
Colour
Light grey.
Colour Intensity
---
Form
---
Odor
Amine.
Odor Threshold
Not applicable.
Ph
Alkaline.
Melting Point
Not available.
Boiling Point
>100°C/>212°F @ 760 mm Hg
Flash Point
>100°C/>212°F Closed cup.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Low.
Vapor Density
> 1
Relative Density
1.62 - 1.72 @ 20°C/68°F
Bulk Density
---
Density
---
Flammability
Not applicable.
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
Not available.
Solubility In Water
Immiscible with water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see Section 7).

Reactivity

There are no known reactivity hazards associated with this product.

Hazardous reactions

No hazardous reactions expected when stored and handled as recommended.

Avoid

There are no known conditions that are likely to result in a hazardous situation.

Incompatible

oxidising agents and strongly acidic materials

Decomposition

Does not decompose when used and stored as recommended.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Toxicity Based on the individual component data, the product is expected to have experimental LC50/EC50/IC50 values between 1 and 10 mg/l in most sensitive species.

The product is expected to have experimental LC50/EC50/IC50 values between 1 and 10 mg/l in most sensitive species.

12.2. Persistence and degradability

Persistence and degradability Based on the individual component data, the product is not expected to be rapidly biodegradable according to OECD/EC guidelines.

The product is not expected to be rapidly biodegradable according to OECD/EC guidelines.

12.3. Bioaccumulative potential

Bioaccumulative potential Based on the individual component data, the product is expected to bioaccumulate. Partition coefficient Not available.

The product is expected to bioaccumulate.

12.4. Mobility in soil

Mobility There is no data available on the product itself.

There is no data available on the product itself.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment Based on information received from our suppliers no PBT or vPvB substances are intentionally added to this product.

Based on information received from our suppliers no PBT or vPvB substances are intentionally added to this product.

12.6. Other adverse effects

Other adverse effects None known.

None known.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Controlled wastes include non-hazardous industrial and hazardous chemical wastes. All controlled wastes should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. In addition, hazardous chemical wastes should be disposed of in accordance with the Hazardous Waste Regulations.

Disposal

UNREACTED PRODUCT and empty uncleaned containers should be disposed of as hazardous chemical waste. REACTED PRODUCT, contaminated mixing boards, spatulas, applicators, brushes, nominally empty containers and mixing bowls- once fully cured- should be disposed of as non-hazardous waste.

Waste Codes

08 04 09* Hazardous waste pursuant to Directive 91/689/EEC EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3259
Shipping Name
Amines, solid, corrosive, n.o.s. (containing Diethylenetriamine and Formaldehyde oligomeric copolymer mixture)
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The provisions of the Health and Safety at Work Act and the Control of Substances Hazardous to Health Regulations with amendments apply to the use of this product at work. This product may add to the calculation for determining whether a site is within scope of the Control of Major Accident Hazards Regulations.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for BELZONA® 1111 (SUPER METAL) SOLIDIFIER?

The signal word is danger.

What is the physical form of BELZONA® 1111 (SUPER METAL) SOLIDIFIER?

BELZONA® 1111 (SUPER METAL) SOLIDIFIER is a paste appearing as paste. with light grey. color. It has amine. odor.

What is BELZONA® 1111 (SUPER METAL) SOLIDIFIER used for?

Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.

What are the hazard statements for BELZONA® 1111 (SUPER METAL) SOLIDIFIER?

This substance has 3 hazard statements:

  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of BELZONA® 1111 (SUPER METAL) SOLIDIFIER?

The melting point is Not available. and the boiling point is >100°C/>212°F @ 760 mm Hg.