Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- BELZONA® 1111 (SUPER METAL) SOLIDIFIER
- Product Code
- SN2598
Regulatory Identifiers
- CAS Number
- N/A
Identified Uses
Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.
Uses advised against
The product should not be used for purposes other than those recommended in the appropriate Instructions For Use (IFU) leaflet.
Manufacturers & Suppliers
Belzona Polymerics Limited
manufacturer
Claro Road, Harrogate, HG1 4DS, United Kingdom
+44 1423 567641
Emergency Contacts
ChemTel
+1 813-248-0585
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS05
GHS07
GHS09
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| DIETHYLENETRIAMINE EC: 203-865-4 | 111-40-0 | 10 - 30% | Yes |
| BENZYL ALCOHOL EC: 202-859-9 | 100-51-6 | 5 - 15% | Yes |
| FORMALDEHYDE POLYMER WITH 1,3-BENZENEDIMETHANAMINE AND PHENOL EC: 500-137-0 | 57214-10-5 | --- | Yes |
| M-PHENYLENEBIS(METHYLAMINE) EC: 216-032-5 | 1477-55-0 | --- | Yes |
| 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL EC: 202-013-9 | 90-72-2 | --- | Yes |
| TRIMETHYLHEXANE-1,6-DIAMINE EC: 247-134-8 | 25620-58-0 | --- | Yes |
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth.
Symptoms: Exposure to vapours may result in irritation of the mucous membrane and the respiratory system; in severe cases burns may occur.
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. If irritation or inflammation persists, seek medical attention.
Symptoms: irritation or inflammation
Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek medical advice.
Symptoms: Contact with eyes may cause severe irritation with corneal injury, which may result in permanent impairment of vision.
If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with plenty of water. Do NOT induce vomiting.
Symptoms: May cause chemical burns in mouth, oesophagus and stomach.
Immediate Medical Attention
In all cases of doubt, or when symptoms persist, seek medical attention. If accidentally swallowed obtain immediate medical attention.
Medical Treatment
None.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger fires.
Do NOT use water jet.
In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen and ammonia may be produced.
Cool closed containers exposed to fire with water spray.
Firefighter Protection
Appropriate self-contained breathing apparatus may be required.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Exclude non-essential personnel. Keep up-wind of spill to avoid breathing vapours. Do not get on skin or in eyes.
Prevent spills from entering drains or sewers.
Scrape the majority of the product into a suitable labelled container. Clean surfaces down with a water and detergent mixture.
Materials: water and detergent mixture
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Keep the container tightly closed when not in use. Vapours may collect in the container headspace during transit or prolonged storage. Avoid the inhalation of vapour when opening the container. Where possible open containers and mix components in a well ventilated place away from the application area. Exclude non-essential personnel. Minimise the number of employees exposed and the duration of their exposure. Do not get on skin or in eyes. Always keep in containers made of the same material as the supply container. Ensure emergency equipment (for fires, spills, leaks, etc.) is readily available.
Store between 5 °C and 30 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where necessary, contaminated work clothing and shoes should be removed to prevent cross contamination of surfaces and the risk of inadvertent skin contact and ingestion. Smoking, eating and drinking should be prohibited in areas of storage and use.
This product is combustible. Exclude sources of heat, sparks and open flame.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see 'Respiratory protection' below).
Hand protection should be selected in accordance with EN 374 Protective gloves against chemicals. The breakthrough time of the gloves selected should exceed the expected use period. Where this is not possible gloves should be changed in good time, and in any case before the breakthrough time is exceeded. If any doubt exists, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. SPECIFIC RECOMMENDATIONS Wear protective gloves made of the following material: Neoprene. Nitrile rubber. STANDARD APPLICATIONS Medium-heavy weight gauntlet type gloves that provide wrist protection are suitable. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS Light weight disposable gloves are normally suitable.
It is recommended that eye protection, for example safety spectacles or goggles are worn at all times during the handling and use of this material. Eye protection should be selected in accordance with EN 166 Personal eye protection. During subsequent machining, grinding, abrasion or removal of this product appropriate eye protection should be selected according to the type of tools or equipment used.
Respiratory protection is not normally required but it may be required when this product is used in confined spaces or where adequate ventilation cannot be achieved. It is essential that the concentration of the contaminant(s) in the application environment does not exceed the applicable Occupational Exposure Limit(s) (OELs) multiplied by the Assigned Protection Factor (APF) quoted for the respiratory protective equipment selected. Where necessary, it is recommended that respiratory protective equipment that complies with EN 136 (full face mask) or EN 140 (half face mask) should be worn in combination with an organic/inorganic vapours, acid gases and ammonia cartridge (ABEK1). Where the application environment is likely to be contaminated by significant concentrations of dust then the appropriate particulate prefilter (N-, R- or, P-series) should be worn in combination with the above. It is essential that the facepiece is correctly fitted and the filter is changed in accordance with the manufacturer's instructions.
STANDARD APPLICATIONS Synthetic polyethylene coveralls such as the Tyvek PROTECH® or equivalent coveralls manufactured to EN 13034 Type 6, Protective clothing against liquid chemicals. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS Cotton overalls are normally suitable.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
Stable under recommended storage and handling conditions (see Section 7).
There are no known reactivity hazards associated with this product.
No hazardous reactions expected when stored and handled as recommended.
There are no known conditions that are likely to result in a hazardous situation.
oxidising agents and strongly acidic materials
Does not decompose when used and stored as recommended.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
12.1. Toxicity
The product is expected to have experimental LC50/EC50/IC50 values between 1 and 10 mg/l in most sensitive species.
12.2. Persistence and degradability
The product is not expected to be rapidly biodegradable according to OECD/EC guidelines.
12.3. Bioaccumulative potential
The product is expected to bioaccumulate.
12.4. Mobility in soil
There is no data available on the product itself.
12.5. Results of PBT and vPvB assessment
Based on information received from our suppliers no PBT or vPvB substances are intentionally added to this product.
12.6. Other adverse effects
None known.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Controlled wastes include non-hazardous industrial and hazardous chemical wastes. All controlled wastes should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. In addition, hazardous chemical wastes should be disposed of in accordance with the Hazardous Waste Regulations.
UNREACTED PRODUCT and empty uncleaned containers should be disposed of as hazardous chemical waste. REACTED PRODUCT, contaminated mixing boards, spatulas, applicators, brushes, nominally empty containers and mixing bowls- once fully cured- should be disposed of as non-hazardous waste.
Waste Codes
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- 3259
- Shipping Name
- Amines, solid, corrosive, n.o.s. (containing Diethylenetriamine and Formaldehyde oligomeric copolymer mixture)
- Transport Class
- 8
- Packing Group
- III
Regulatory Information
Chemical regulations, safety assessments, and compliance status
The provisions of the Health and Safety at Work Act and the Control of Substances Hazardous to Health Regulations with amendments apply to the use of this product at work. This product may add to the calculation for determining whether a site is within scope of the Control of Major Accident Hazards Regulations.
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for BELZONA® 1111 (SUPER METAL) SOLIDIFIER?
The signal word is danger.
What is the physical form of BELZONA® 1111 (SUPER METAL) SOLIDIFIER?
BELZONA® 1111 (SUPER METAL) SOLIDIFIER is a paste appearing as paste. with light grey. color. It has amine. odor.
What is BELZONA® 1111 (SUPER METAL) SOLIDIFIER used for?
Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.
What are the hazard statements for BELZONA® 1111 (SUPER METAL) SOLIDIFIER?
This substance has 3 hazard statements:
- H314: Causes severe skin burns and eye damage.
- H317: May cause an allergic skin reaction.
- H411: Toxic to aquatic life with long lasting effects.
What is the melting point of BELZONA® 1111 (SUPER METAL) SOLIDIFIER?
The melting point is Not available. and the boiling point is >100°C/>212°F @ 760 mm Hg.