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Safety Data Sheet EN

BELZONA® 1212 SOLIDIFIER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
BELZONA® 1212 SOLIDIFIER
Product Code
SN2844

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.

Uses advised against

The product should not be used for purposes other than those recommended in the appropriate Instructions For Use (IFU) leaflet.

Manufacturers & Suppliers

B

Belzona Polymerics Limited

national supplier

Claro Road, Harrogate, HG1 4DS, United Kingdom

+44 1423 567641

B

Belzona Polymerics Limited

manufacturer

Claro Road, Harrogate, HG1 4DS, United Kingdom

+44 1423 567641

Emergency Contacts

VelocityEHS

+1 813-248-0585

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Not Classified
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Repr. Cat. 2 H361
STOT RE Cat. 2 H373
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs (Respiratory tract) through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe vapours.
P280 Wear protective gloves, protective clothing and eye protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE or doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
PHENOL, STYRENATED EC: 262-975-0 61788-44-1 5 - 10% Yes
2-PIPERAZIN-1-YLETHYLAMINE EC: 205-411-0 140-31-8 5 - 10% Yes
1,3-CYCLOHEXANEDIMETHANAMINE EC: 219-941-5 2579-20-6 1 - 5% Yes
TITANIUM OXIDE EC: 236-675-5 13463-67-7 1 - 5% Yes
PHENOL, METHYLSTYRENATED EC: 700-960-7 68512-30-1 1 - 5% Yes
SALICYLIC ACID EC: 200-712-3 69-72-7 3% Yes
DIISOPROPYLNAPHTHALENE ISOMERS EC: 254-052-6 38640-62-9 1% Yes

Notes

This mixture contains ≥ 1% Titanium Dioxide (CAS 13463-67-7). The Annex VI classification of Titanium Dioxide does not apply to this mixture according to its Note 10.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth.

Symptoms: Exposure to vapours may result in irritation of the mucous membrane and the respiratory system; in severe cases burns may occur.

Skin contact

Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. If irritation or inflammation persists, seek medical attention.

Symptoms: Skin contact causes chemical burns. Symptoms may include pain, severe local redness and tissue damage. May cause allergic skin reaction.

Eye contact

Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek medical advice.

Symptoms: Contact with eyes may cause severe irritation with corneal injury, which may result in permanent impairment of vision.

Ingestion

If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with plenty of water. Do NOT induce vomiting.

Symptoms: May cause chemical burns in mouth, oesophagus and stomach.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical attention. If accidentally swallowed obtain immediate medical attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger fires.

Unsuitable media

water jet.

Specific hazards

In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen and ammonia may be produced.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

Appropriate self-contained breathing apparatus may be required.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Exclude non-essential personnel. Keep up-wind of spill to avoid breathing vapours. Do not get on skin or in eyes.

Large spill

If the product enters drains or sewers in large quantities, the local Water Company should be contacted immediately.

Environmental

Prevent spills from entering drains or sewers.

Cleanup methods

Scrape the majority of the product into a suitable labelled container. Cover the spill area with sand or other suitable inert material and sweep up into the container. Clean surfaces down with a water and detergent mixture.

Materials: sand or other suitable inert material, water and detergent mixture

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep the container tightly closed when not in use. Vapours may collect in the container headspace during transit or prolonged storage. Do not breathe vapour when opening the container. Where possible open containers and mix components in a well ventilated place away from the application area. Exclude non-essential personnel. Minimise the number of employees exposed and the duration of their exposure. Do not get on skin or in eyes. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Always keep in containers made of the same material as the supply container. Ensure emergency equipment (for fires, spills, leaks, etc.) is readily available. Good housekeeping methods and regular safe removal of waste materials should be observed.

Storage

Store between 5 °C and 30 °C unless otherwise stated in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Store separately from oxidising agents and strongly acidic materials.

Hygiene

Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where necessary, contaminated work clothing and shoes should be removed to prevent cross contamination of surfaces and the risk of inadvertent skin contact and ingestion.

Fire prevention

This product is combustible. Exclude sources of heat, sparks and open flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use in well ventilated areas or provide adequate mechanical ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Where these controls are not sufficient to maintain concentrations of particulates and/or vapours to an acceptable level, suitable respiratory protective equipment should be worn (see 'Respiratory protection' below).

Hands

Hand protection should be selected in accordance with EN 374 Protective gloves against chemicals. The breakthrough time of the gloves selected should exceed the expected use period. Where this is not possible gloves should be changed in good time, and in any case before the breakthrough time is exceeded. If any doubt exists, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. SPECIFIC RECOMMENDATIONS Wear protective gloves made of the following material: Nitrile rubber. Medium-heavy weight gauntlet type gloves that provide wrist protection are suitable.

Eyes

It is recommended that eye protection, for example safety spectacles or goggles are worn at all times during the handling and use of this material. Eye protection should be selected in accordance with EN 166 Personal eye protection. During subsequent machining, grinding, abrasion or removal of this product appropriate eye protection should be selected according to the type of tools or equipment used.

Respiratory

Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Respirator selection must be based on exposure levels, the hazards of the product and the safe working limits of the selected respirator. It is essential that the concentration of the contaminant(s) in the application environment does not exceed the applicable Occupational Exposure Limit(s) (OELs) multiplied by the Assigned Protection Factor (APF) quoted for the respiratory protective equipment selected. Where necessary, it is recommended that respiratory protective equipment that complies with EN 136 (full face mask) or EN 140 (half face mask) should be worn in combination with an organic/inorganic vapours, acid gases and ammonia cartridge (ABEK1). Where the application environment is likely to be contaminated by significant concentrations of dust then the appropriate particulate prefilter (N-, R- or, P-series) should be worn in combination with the above. It is essential that the facepiece is correctly fitted and the filter is changed in accordance with the manufacturer's instructions. In confined or poorly-ventilated spaces, a supplied-air respirator must be worn.

Skin/Body

STANDARD APPLICATIONS Synthetic polyethylene coveralls such as the Tyvek PROTECH® or equivalent coveralls manufactured to EN 13034 Type 6, Protective clothing against liquid chemicals. EMERGENCY REPAIRS OR APPLICATION OF SINGLE UNITS Cotton overalls are normally suitable.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Metal Corrosion
---
Freezing Point
---
Softening Point
---
Melting Point
Not available.
State Under Standard Conditions
---
Solubility In Fat
---
Relative Evaporation Rate
---
Relative Density
2.27 - 2.37 @ 20°C/68°F
Decomposition Temperature
Not available.
Flash Point
>100°C/>212°F
Boiling Point
>200°C/>392°F
Cloud Point
---
Solubility
Immiscible with water.
Bulk Density
---
Solubility In Water
---
Density
---
Physical State Data
liquid
Physical State
Paste
Form
---
Evaporation Rate
Not available.
Crystallisation Point
---
Odor
Amine.
Partition Coefficient
Not available.
Kinematic Viscosity
---
Colour
Light grey.
Voc Content
---
Properties Status
---
Odor Threshold
Not applicable.
Colour Intensity
---
Flammability
Not applicable.
Explosive Limits
---
Solidification Point
---
Upper Explosive Limit
Not applicable.
Vapor Pressure
Low.
Dynamic Viscosity
---
Vapor Density
Not available.
Appearance
Paste.
Molecular Weight
---
Ph
Alkaline.
Auto Ignition Temperature
Not available.
Lower Explosive Limit
Not applicable.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see Section 7).

Reactivity

There are no known reactivity hazards associated with this product.

Hazardous reactions

No hazardous reactions expected when stored and handled as recommended.

Avoid

There are no known conditions that are likely to result in a hazardous situation.

Incompatible

Keep away from oxidising agents and strongly acidic materials to prevent the possibility of exothermic reaction.

Decomposition

Does not decompose when used and stored as recommended.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3259
Shipping Name
Amines, solid, corrosive, n.o.s. (containing 1,3-Cyclohexanedimethanamine and 2-Piperazin-1-ylethylamine mixture)
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for BELZONA® 1212 SOLIDIFIER?

The signal word is danger.

What is the physical form of BELZONA® 1212 SOLIDIFIER?

BELZONA® 1212 SOLIDIFIER is a paste appearing as paste. with light grey. color. It has amine. odor.

What is the solubility of BELZONA® 1212 SOLIDIFIER?

Immiscible with water.

What is BELZONA® 1212 SOLIDIFIER used for?

Engineering grade repair system for repairing and rebuilding machinery and equipment. For industrial use only.

What are the hazard statements for BELZONA® 1212 SOLIDIFIER?

This substance has 5 hazard statements:

  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H361: Suspected of damaging fertility or the unborn child.
  • H373: May cause damage to organs (Respiratory tract) through prolonged or repeated exposure.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of BELZONA® 1212 SOLIDIFIER?

The melting point is Not available. and the boiling point is >200°C/>392°F.