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Safety Data Sheet EN

ROBOND™ FD-07

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ROBOND™ FD-07

Regulatory Identifiers

CAS Number
N/A
UFI Code
96MU-R1JM-U00S-XDQU

Identified Uses

Adhesive and Coating

Manufacturers & Suppliers

D

DOW EUROPE GMBH

manufacturer

BACHTOBELSTRASSE 4, 8810 HORGEN, SWITZERLAND

31 115 67 2626

D

DOW BENELUX B.V.

national supplier

HERBERT H.DOWWEG 5, HOEK, 4542 NM TERNEUZEN, NETHERLANDS

(31) 115 67 2626

Emergency Contacts

Emergency Contact

00 41 447 28 2820

24-Hour

Emergency Contact

+39 333 210 7947

CAV "Osp. Pediatrico Bambino Gesù" Dip. Emergenza e Accettazione DEA, Piazza Sant'Onofrio 4, 165, Roma

06-68593726

Az. Osp. Univ. Foggia, V.le Luigi Pinto 1, 71122, Foggia

800183459

Az. Osp. "A. Cardarelli", Via A. Cardarelli 9, 80131, Napoli

081-5453333

CAV Policlinico "Umberto I", V.le del Policlinico 155, 161, Roma

06-49978000

CAV Policlinico "A. Gemelli", Largo Agostino Gemelli 8, 168, Roma

06-3054343

Az. Osp. "Careggi" U.O. Tossicologia Medica, Largo Brambilla 3, 50134, Firenze

055-7947819

CAV Centro Nazionale di Informazione Tossicologica, Via Salvatore Maugeri 10, 27100, Pavia

0382-24444

Osp. Niguarda Ca' Granda, Piazza Ospedale Maggiore 3, 20162, Milano

02-66101029

Azienda Ospedaliera Papa Giovanni XXII, Piazza OMS 1, 24127, Bergamo

800883300

Azienda Ospedaliera Integrata Verona, Piazzale Aristide Stefani 1, 37126, Verona

800011858

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H317 May cause an allergic skin reaction.

Precautionary Statements

P261 Avoid breathing mist or vapours.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
ammonia EC: 215-647-6 1336-21-6 0.1 - 0.25% Yes
2-methylisothiazol-3(2H)-one EC: 220-239-6 2682-20-4 0.0025 - 0.025% Yes
reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) EC: 611-341-5 55965-84-9 0.0002 - 0.0015% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation or rash occurs. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands.

Symptoms: May cause an allergic skin reaction.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion

If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

Immediate Medical Attention

Consult a physician if effects occur or if irritation/rash occurs.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing media appropriate for surrounding fire..

Unsuitable media

No data available

Specific hazards

Material can splatter above 100C/212F.. Dried product can burn..

Instructions

No data available

Firefighter Protection

Wear self-contained breathing apparatus and protective suit..

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Keep people away from and upwind of spill/leak. Material can create slippery conditions.

Environmental

CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.

Cleanup methods

Transfer liquids and solid diking material to separate suitable containers for recovery or disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Do not breathe vapors, mist or gas.

Storage

Keep container tightly closed.

Hygiene

Wash thoroughly after handling.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations.

Hands

Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Neoprene. When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN ISO 16321-1 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; however, if discomfort is experienced, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Particulate filter, type P2 (meeting standard EN 143).

Skin/Body

Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid milky
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
white
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
8,0 - 9,0
Melting Point
not determined
Boiling Point
100 °C Water
Flash Point
Noncombustible
Freezing Point
not determined
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
<1 Water
Vapor Pressure
22,66 hPa at 20 °C Water
Vapor Density
---
Relative Density
1,03 - 1,08
Bulk Density
---
Density
---
Flammability
not determined
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
not determined
Solubility In Water
partly miscible
Solubility In Fat
---
Molecular Weight
not determined
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
<300 mPa.s
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable

Reactivity

No data available

Hazardous reactions

None known. Product will not undergo polymerization.

Avoid

No data available

Incompatible

There are no known materials which are incompatible with this product.

Decomposition

Thermal decomposition may yield acrylic monomers..

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Information for the Product: Product test data not available.

Product test data not available.

12.2 Persistence and degradability

Information for components:

12.3 Bioaccumulative potential

Information for components:

12.4 Mobility in soil

Information for components:

12.5 Results of PBT and vPvB assessment

Information for components:

12.6 Endocrine disrupting properties

Information for components:

12.7 Other adverse effects

Information for components:

12.1 Toxicity

Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species). May increase pH of aquatic systems to > pH 10 which may be toxic to aquatic organisms. LC50, Lepomis macrochirus (Bluegill sunfish), 96 Hour, 0,87 mg/l LC50, Pimephales promelas (fathead minnow), 96 Hour, 1,2 mg/l EC50, Daphnia magna (Water flea), 48 Hour, 0,66 mg/l

12.1 Toxicity

2-methylisothiazol-3(2H)-one Acute toxicity to fish Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species). LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 4,77 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, 0,93 - 1,9 mg/l Acute toxicity to algae/aquatic plants ErC50, Skeletonema costatum (marine diatom), Static, 24 Hour, Growth rate, 0,0695 mg/l EC10, Skeletonema costatum (marine diatom), Static, 24 Hour, Growth rate, 0,024 mg/l Chronic toxicity to fish NOEC, Pimephales promelas (fathead minnow), 33 d, 2,1 mg/l Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna, 21 d, 0,04 mg/l

12.1 Toxicity

Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species). LC50, Oncorhynchus mykiss (rainbow trout), flow-through test, 96 Hour, 0,19 mg/l, OECD Test Guideline 203 or Equivalent LC50, Daphnia magna (Water flea), flow-through test, 48 Hour, 0,16 mg/l, OECD Test Guideline 202 or Equivalent NOEC, Skeletonema costatum (marine diatom), Static, 48 Hour, 0,00049 mg/l, OECD Test Guideline 201 ErC50, Skeletonema costatum (marine diatom), Static, 48 Hour, 0,0052 mg/l, OECD Test Guideline 201 Chronic toxicity to fish NOEC, Rainbow trout (Oncorhynchus mykiss), flow-through, 14 d, 0.05 mg/l Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna, flow-through test, 21 d, 0.1 mg/l

12.2 Persistence and degradability

Information for the Product: Product test data not available. Information for components:

Product test data not available.

12.2 Persistence and degradability

Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen). Biodegradation rate may increase in soil and/or water with acclimation.

12.2 Persistence and degradability

2-methylisothiazol-3(2H)-one Biodegradability: Material is expected to be readily biodegradable. Biodegradation: 98 % Exposure time: 48 d Method: Simulation study

12.2 Persistence and degradability

reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) Biodegradability: Considered to be rapidly degradable. Material is not readily biodegradable according to OECD/EEC guidelines. Biodegradation: < 50 % Exposure time: 10 d Photodegradation Atmospheric half-life: 0,38 - 1,3 d

12.3 Bioaccumulative potential

Information for the Product: Product test data not available. Information for components:

Product test data not available.

12.3 Bioaccumulative potential

ammonia Bioaccumulation: No bioconcentration is expected because of the relatively high water solubility.

No bioconcentration is expected because of the relatively high water solubility.

12.3 Bioaccumulative potential

2-methylisothiazol-3(2H)-one Bioaccumulation: Does not bioaccumulate. Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Page 18 of 25 Product name: ROBOND™ FD-07 Revision Date: 17.03.2026 Version: 6.0 Partition coefficient: n-octanol/water(log Pow): -0,75 Measured

12.3 Bioaccumulative potential

reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). 2-Methyl-4-isothiazolin-3-one(MIT): 5-Chloro-2-methyl-4-isothiazolin-3-one (CMIT): Partition coefficient: n-octanol/water(log Pow): -0,486 Measured Partition coefficient: n-octanol/water(log Pow): 0,401 Measured

Bioconcentration potential is low (BCF < 100 or Log Pow < 3).

12.4 Mobility in soil

Information for the Product: Product test data not available. Information for components: **ammonia** Potential for mobility in soil is very high (Koc between 0 and 50). **2-methylisothiazol-3(2H)-one** No relevant data found. **reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1)** Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Partition coefficient (Koc): 28 Estimated.

12.5 Results of PBT and vPvB assessment

Information for the Product: Product test data not available. Information for components: **ammonia** No data available **2-methylisothiazol-3(2H)-one** No data available **reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1)** No data available

Product test data not available. No data available for components.

12.6 Endocrine disrupting properties

Information for the Product: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100, Commission Regulation (EU) 2018/605 or Regulation (EC) 1272/2008 at levels of 0.1% or higher. ## Information for components: ### ammonia The substance is not considered to have endocrine disrupting properties according to REACH Article 57(f), Commission Regulation (EU) 2018/605, Commission Delegated Regulation (EU) 2017/2100 or Regulation (EC) 1272/2008. ### 2-methylisothiazol-3(2H)-one The substance is not considered to have endocrine disrupting properties according to REACH Article 57(f), Commission Regulation (EU) 2018/605, Commission Delegated Regulation (EU) 2017/2100 or Regulation (EC) 1272/2008. ### reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) The substance is not considered to have endocrine disrupting properties according to REACH Article 57(f), Commission Regulation (EU) 2018/605, Commission Delegated Regulation (EU) 2017/2100 or Regulation (EC) 1272/2008.

The product and its components (ammonia, 2-methylisothiazol-3(2H)-one, and the reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one) are not considered to have endocrine disrupting properties according to the specified EU regulations at levels of 0.1% or higher.

12.7 Other adverse effects

Information for the Product: Product test data not available. Information for components: ammonia This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. 2-methylisothiazol-3(2H)-one This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

No product test data available. Components listed are not on the Montreal Protocol list of substances that deplete the ozone layer.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Coagulate the emulsion by the stepwise addition of ferric chloride and lime. Remove the clear supernatant and flush to a chemical sewer.

Disposal

For disposal, incinerate or landfill at a permitted facility in accordance with local, state, and federal regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product contains only components that have been either registered, are exempt from registration, are regarded as registered or are not subject to registration according to Regulation (EC) No. 1907/2006 (REACH). Polymers are exempted from registration under REACH.

Chemical Safety Assessment Not performed

Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ROBOND™ FD-07?

The signal word is warning.

What is the physical form of ROBOND™ FD-07?

ROBOND™ FD-07 is a liquid milky with white color. It has no data available odor.

What is ROBOND™ FD-07 used for?

Adhesive and Coating

What are the hazard statements for ROBOND™ FD-07?

This substance has 1 hazard statement:

  • H317: May cause an allergic skin reaction.

What is the melting point of ROBOND™ FD-07?

The melting point is not determined and the boiling point is 100 °C Water.