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Safety Data Sheet EN

Formaldehyde, 37 wt% solution, stabilized with methanol

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formaldehyde, 37 wt% solution, stabilized with methanol
Product Code
AC119690000, AC119690010, AC119690025, AC119690050, AC119690250
Synonyms
Formalin; Formol; Methanal

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company: Acros Organics

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 4
Acute Tox. Cat. 3
Skin Corr. Cat. 1B
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Muta. Cat. 2
Carc. Cat. 1A
STOT SE Cat. 1

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 Combustible liquid
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H350i May cause cancer
H370 Causes damage to organs

Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P235 Keep cool
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor
P330 Rinse mouth
P331 Do NOT induce vomiting
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P362 + P364 Take off contaminated clothing and wash before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam to extinguish
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Water 7732-18-5 40 - 46% No
Formaldehyde 50-00-0 35 - 41% No
Methyl alcohol 67-56-1 5 - 14% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove to fresh air. Immediate medical attention is required.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Symptoms: May cause allergic skin reaction.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water mist may be used to cool closed containers. CO₂, dry chemical, dry sand, alcohol-resistant foam.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Combustible material. Containers may explode when heated.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Keep away from heat, sparks and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colorless
Colour Intensity
---
Form
---
Odor
Irritating pungent
Odor Threshold
0.8 - 1 ppm
Ph
3-4.2
Melting Point
-15 °C / 5 °F
Boiling Point
97 °C / 206.6 °F
Flash Point
63 - 75 °C / 145.4 - 167 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
2 mbar @ 20 °C
Vapor Density
>1.0
Relative Density
---
Bulk Density
Not applicable
Density
1.083
Flammability
Flammable Combustible liquid
Upper Explosive Limit
73 vol%
Lower Explosive Limit
7 vol%
Explosive Limits
---
Auto Ignition Temperature
424 °C / 795.2 °F
Decomposition Temperature
>150°C
Solubility
---
Partition Coefficient
---
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
30.02
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.0 mPas @ 20°C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions. Stabilized with Methanol.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization may occur upon depletion of inhibitor.

Avoid

Temperatures above 65°C. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Potassium permanganate, Peroxides, Perchloric acid + aniline, Strong bases, Sodium hydroxide, Ammonia, Hydroxides, Sodium bisulfite, Strong acids, Hydrogen chloride, Isocyanates, Acid anhydrides, Magnesium carbonates, Iodine

Decomposition

Formic acid, Oxygen from the air can oxidize formaldehyde to formic acid, especially when heated, Carbon monoxide (CO), Carbon dioxide (CO2)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Formaldehyde: Freshwater Algae EC50 (72h) = 4.89 mg/L (Desmodesmus subspicatus); Freshwater Fish Leuciscus idus: LC50 = 15 mg/L 96h; Water Flea EC50 = 20 mg/L 96h; Water Flea EC50 = 2 mg/L 48h

12.1 Toxicity

Pimephales promelas: LC50 > 10000 mg/L 96h; EC50 = 39000 mg/L 25 min, EC50 = 40000 mg/L 15 min, EC50 = 43000 mg/L 5 min; EC50 > 10000 mg/L 24h

Persistence and Degradability

Soluble in water Persistence is unlikely based on information available. Miscible with water

Bioaccumulation/ Accumulation

No information available.

Mobility

Will likely be mobile in the environment due to its water solubility.

12.3 Bioaccumulative potential

| Component | log Pow | | --- | --- | | Formaldehyde | -0.35 |

12.3 Bioaccumulative potential

Methyl alcohol: log Pow -0.74
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.

Disposal

Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Waste Codes

U122 Formaldehyde - 50-00-0 RCRA
U154 Methyl alcohol - 67-56-1 RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2209
Shipping Name
FORMALDEHYDE SOLUTION
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Formaldehyde, 37 wt% solution, stabilized with methanol known by?

Formaldehyde, 37 wt% solution, stabilized with methanol is also known as: Formalin; Formol; Methanal

What is the hazard signal word for Formaldehyde, 37 wt% solution, stabilized with methanol?

The signal word is danger.

What is the physical form of Formaldehyde, 37 wt% solution, stabilized with methanol?

Formaldehyde, 37 wt% solution, stabilized with methanol is a liquid with colorless color. It has irritating pungent odor.

What is Formaldehyde, 37 wt% solution, stabilized with methanol used for?

Laboratory chemicals.

What are the hazard statements for Formaldehyde, 37 wt% solution, stabilized with methanol?

This substance has 8 hazard statements:

  • H227: Combustible liquid
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H335: May cause respiratory irritation
  • H341: Suspected of causing genetic defects
  • H350i: May cause cancer
  • H370: Causes damage to organs

What is the melting point of Formaldehyde, 37 wt% solution, stabilized with methanol?

The melting point is -15 °C / 5 °F and the boiling point is 97 °C / 206.6 °F.