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Safety Data Sheet EN

Formaldehyde, 37% w/w in aqueous solution

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formaldehyde, 37% w/w in aqueous solution
Product Code
A16163
Chemical Name
Formaldehyde
Synonyms
Formalin; Formol; Methanal

Regulatory Identifiers

CAS Number
N/A
UFI Code
3YU0-N349-FX0C-MHMQ

Identified Uses

Laboratory chemicals

Uses advised against

No Information available

Manufacturers & Suppliers

A

Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific)

manufacturer

Shore Road, Heysham, Lancashire, LA3 2XY, United Kingdom

+44 (0) 1524 850506

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

National Poisons Information Centre (NPIC)

01 809 2166

8am-10pm, 7 days a week

Emergency Contact

+356 2395 2000

Emergency Contact

+357 2240 5611

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1B H350
STOT SE Cat. 1 H370

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 Combustible liquid
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H341 Suspected of causing genetic defects
H350 May cause cancer
H370 Causes damage to organs

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Water EC: 231-791-2 7732-18-5 40 - 46% No
Formaldehyde EC: 200-001-8 50-00-0 35 - 41% Yes
Methyl alcohol EC: 200-659-6 67-56-1 5 - 14% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove to fresh air. Immediate medical attention is required.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Severe swelling, severe damage to the delicate tissue and danger of perforation

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water mist may be used to cool closed containers. CO₂, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Combustible material. Containers may explode when heated.

Firefighter Protection

Wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Ensure adequate ventilation. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from open flames, hot surfaces and sources of ignition.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area. Keep away from heat, sparks and flame.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Use explosion-proof electrical/ventilating/lighting equipment. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Viton (R) (>480 minutes, 0.7 mm, EN 374), Nitrile rubber (>360 minutes, 15 - 22 mil), Butyl rubber (>240 minutes, 25 -35 mil), Neoprene gloves (>60 minutes, 18 - 24 mil). Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
---
Colour Intensity
---
Form
---
Odor
Irritating pungent
Odor Threshold
0.8 - 1 ppm
Ph
3-4.2
Melting Point
-15 °C / 5 °F
Boiling Point
97 °C / 206.6 °F @ 760 mmHg
Flash Point
63 - 75 °C / 145.4 - 167 °F Method - No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
2 mbar @ 20 °C
Vapor Density
>1.0 (Air = 1.0)
Relative Density
---
Bulk Density
Not applicable
Density
1.083
Flammability
Flammable Combustible liquid
Upper Explosive Limit
73 vol%
Lower Explosive Limit
7 vol%
Explosive Limits
---
Auto Ignition Temperature
424 °C / 795.2 °F
Decomposition Temperature
>150°C
Solubility
---
Partition Coefficient
Formaldehyde: -0.35, Methyl alcohol: -0.74
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
30.02
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.0 mPas @ 20°C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions. Stabilized with Methanol.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization may occur upon depletion of inhibitor.

Avoid

Temperatures above 65°C. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents. Potassium permanganate. Peroxides. Perchloric acid + aniline. Strong bases. Sodium hydroxide. Ammonia. Hydroxides. Sodium bisulfite. Strong acids. Hydrogen chloride. Isocyanates. Acid anhydrides. Magnesium carbonates. Iodine.

Decomposition

Formic acid. Oxygen from the air can oxidize formaldehyde to formic acid, especially when heated. Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2209
Shipping Name
FORMALDEHYDE SOLUTION
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Formaldehyde, 37% w/w in aqueous solution known by?

Formaldehyde, 37% w/w in aqueous solution is also known as: Formalin; Formol; Methanal

What is the hazard signal word for Formaldehyde, 37% w/w in aqueous solution?

The signal word is danger.

What is the physical form of Formaldehyde, 37% w/w in aqueous solution?

Formaldehyde, 37% w/w in aqueous solution is a liquid appearing as colorless . It has irritating pungent odor.

What is Formaldehyde, 37% w/w in aqueous solution used for?

Laboratory chemicals

What are the hazard statements for Formaldehyde, 37% w/w in aqueous solution?

This substance has 7 hazard statements:

  • H227: Combustible liquid
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H341: Suspected of causing genetic defects
  • H350: May cause cancer
  • H370: Causes damage to organs

What is the melting point of Formaldehyde, 37% w/w in aqueous solution?

The melting point is -15 °C / 5 °F and the boiling point is 97 °C / 206.6 °F @ 760 mmHg.