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Safety Data Sheet EN

Formaldehyde solution 37-41%

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formaldehyde solution 37-41%
Product Code
F/1501/PB08, F/1501/PB15, F/1501/PB17, F/1501/25, F/1501/99
Synonyms
Formalin; Formol; Methanal

Regulatory Identifiers

CAS Number
N/A
UFI Code
F5US-FQ5M-VS2M-YVU4

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

national supplier

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

T

Thermo Fisher Scientific

national supplier

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Emergency Contact

01509 231166

Chemtrec US

(800) 424-9300

Chemtrec EU

001-703-527-3887

National Poisons Information Centre (NPIC)

01 809 2166

8am-10pm, 7 days a week

Emergency Contact

+356 2395 2000

Emergency Contact

+357 2240 5611

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1B H350
STOT SE Cat. 1 H370
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapor
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H350 May cause cancer
H370 Causes damage to organs

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Formaldehyde EC: 200-001-8 50-00-0 35 - 41% Yes
Methyl alcohol EC: 200-659-6 67-56-1 5 - 15% Yes
Water EC: 231-791-2 7732-18-5 40 - 46% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Remove to fresh air. Immediate medical attention is required.

Symptoms: Difficulty in breathing.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Symptoms: May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, tingling of the hands and feet, flushing.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas.

Environmental

Should not be released into the environment. See Section 12 for additional Ecological Information.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only under a chemical fume hood. Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance. Do not breathe mist/vapors/spray.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting equipment. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Viton (R) > 480 minutes 0.7 mm EN 374. Nitrile rubber > 360 minutes 15 - 22 mil As tested under EN374-3 Determination of Resistance to Permeation by Chemicals. Butyl rubber > 240 minutes 25 -35 mil. Neoprene gloves > 60 minutes 18 - 24 mil.

Eyes

Goggles (European standard - EN 166)

Respiratory

Large scale/emergency use: When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
---
Colour Intensity
---
Form
---
Odor
Irritating pungent
Odor Threshold
0.8 - 1 ppm
Ph
3-4.2
Melting Point
-15 °C / 5 °F
Boiling Point
97 °C / 206.6 °F @ 760 mmHg
Flash Point
50 °C / 122 °F
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
2 mbar @ 20 °C
Vapor Density
> 1.0 (Air = 1.0)
Relative Density
1.083
Bulk Density
---
Density
---
Flammability
Flammable On basis of test data
Upper Explosive Limit
73 vol%
Lower Explosive Limit
7 vol%
Explosive Limits
---
Auto Ignition Temperature
424 °C / 795.2 °F
Decomposition Temperature
> 150°C
Solubility
---
Partition Coefficient
Formaldehyde -0.35, Methyl alcohol -0.74
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
30.02
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.0 mPas @ 20°C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions. Stabilized with Methanol. Hazardous polymerization may occur upon depletion of inhibitor.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization may occur upon depletion of inhibitor. Reaction of formaldehyde with nitrogen dioxide, nitromethane, perchloric acid and aniline, or peroxyformic acid yields explosive compounds. Formaldehyde reacts with hydrochloric acid to form the potent carcinogen bis-chloromethyl ether. The substance can react dangerously with:, strong oxidizing agents, potassium permanganate, magnesium carbonate, sodium hydroxide, perchloric acid + aniline, hydrochloric acid. The substance polymerize in contact with: alkali, nitrides, polymerization initiators. Risk of explosion in contact with: nitric acid, hydrogen peroxide, nitromethane, performic acid, peracetic acid, phenol, nitrogen dioxide (180 °C). Exothermic reaction with: bases, nitrides, polymerisation initiators, Sodium hydroxide, potassium permanganate, furfuryl alcohol, strong oxidizing agent.

Avoid

Temperatures above 65°C. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents. Potassium permanganate. Peroxides. Perchloric acid + aniline. Strong bases. Sodium hydroxide. Ammonia. Hydroxides. Sodium bisulfite. Strong acids. Hydrogen chloride. Isocyanates. Acid anhydrides. Magnesium carbonates. Iodine.

Decomposition

Formic acid. Oxygen from the air can oxidize formaldehyde to formic acid, especially when heated. Carbon monoxide (CO). Carbon dioxide (CO2).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1198
Shipping Name
FORMALDEHYDE SOLUTION, FLAMMABLE
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Formaldehyde solution 37-41% known by?

Formaldehyde solution 37-41% is also known as: Formalin; Formol; Methanal

What is the hazard signal word for Formaldehyde solution 37-41%?

The signal word is danger.

What is the physical form of Formaldehyde solution 37-41%?

Formaldehyde solution 37-41% is a liquid appearing as colorless . It has irritating pungent odor.

What is Formaldehyde solution 37-41% used for?

Laboratory chemicals.

What are the hazard statements for Formaldehyde solution 37-41%?

This substance has 8 hazard statements:

  • H226: Flammable liquid and vapor
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H335: May cause respiratory irritation
  • H341: Suspected of causing genetic defects
  • H350: May cause cancer
  • H370: Causes damage to organs

What is the melting point of Formaldehyde solution 37-41%?

The melting point is -15 °C / 5 °F and the boiling point is 97 °C / 206.6 °F @ 760 mmHg.