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Safety Data Sheet EN

CITRIC ACID

CAS 77-92-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CITRIC ACID
Chemical Name
citric acid
Synonyms
1,2,3-tricarboxy-2-hydroxypropane; 2-hydroxy-1,2,3-propanetricarboxylic acid, 2-hydroxypropanetricarboxylic acid, APS AR00000161 USP00005262 AR00000160 UL00000162 BP00005263, Acide citrique Roche Ro-017548001, Acidecitrique, Aciletten Food additive, C6-H8-O7, Citraclean, Citretten, Citro ROA 10, Dettrex, Food Acid 330, HOC(CH2COOH)2COOH, HOC-(CH2-CO2-H)2-CO2-H, beta-hydroxycarboxylic acid, beta-hydroxytricarballylic acid

Regulatory Identifiers

CAS Number
77-92-9 Check regulations →

Identified Uses

Component acidulant in beverages, confectionery, effervescent salts, in pharmaceutical syrups, medicines, in effervescent powders and tablets. Used to adjust the pH of foods and as synergistic antioxidant. Used in beverages, jellies, jams, preserves and candy to provide tartness. Manufacture of citrate salts.

Manufacturers & Suppliers

VWR International, Pty Ltd logo

VWR International, Pty Ltd

distributor

Level 1, Unit 1a/60 Enterprise PI QLD 4173 Australia

61 7 3009 4100 - 1300 727 696

https://au.vwr.com

Emergency Contacts

Emergency Contact

61 7 3009 4100 - 1300 727 696

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
STOT SE Cat. 3

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

Precautionary Statements

P261 Avoid breathing dust/fumes.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
citric acid 77-92-9 98% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Skin contact

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Symptoms: irritation

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Symptoms: sleepy or with reduced awareness; i.e. becoming unconscious

Immediate Medical Attention

Transport to hospital or doctor without delay.

Medical Treatment

Treat symptomatically. Simple antacid powders should be useful in the case of ingestion.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit).

Specific hazards

Combustible solid which burns but propagates flame with difficulty. Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion. Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture with air. Combustion products include; carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes.

Instructions

Alert Fire Brigade and tell them location and nature of hazard. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area.

Firefighter Protection

Wear breathing apparatus plus protective gloves.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Small spill

Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

Large spill

Moderate hazard. CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing.

Environmental

See section 12

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions). Minimise airborne dust and eliminate all ignition sources. Keep away from heat, hot surfaces, sparks, and flame. Establish good housekeeping practices. Remove dust accumulations on a regular basis by vacuuming or gentle sweeping to avoid creating dust clouds.

Storage

Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers.

Hygiene

Establish good housekeeping practices.

Fire prevention

Keep away from heat, hot surfaces, sparks, and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Divided Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
White odourless crystals, granules or powder; mixes with water, alcohol and methanol; practically insoluble in chloroform.
Colour
---
Colour Intensity
---
Form
---
Odor
---
Odor Threshold
---
Ph
Not Applicable
Melting Point
153 °C
Boiling Point
Decomposes
Flash Point
1000-1020 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Applicable
Vapor Pressure
Not Applicable
Vapor Density
---
Relative Density
1.67 @ 20 deg.C
Bulk Density
---
Density
---
Flammability
Not Applicable
Upper Explosive Limit
2.29 kg/m3
Lower Explosive Limit
0.28 kg/m3
Explosive Limits
---
Auto Ignition Temperature
1000-1020 °C
Decomposition Temperature
>153
Solubility
---
Partition Coefficient
---
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
192.13
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not Applicable
Kinematic Viscosity
Not Applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

• Unstable in the presence of incompatible materials. • Product is considered stable. • Hazardous polymerisation will not occur.

Reactivity

See section 7

Hazardous reactions

See section 7

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Toxicity | Ingredient | Endpoint | Test Duration (hr) | Species | Value | Source | | citric acid | LC50 | 96 | Fish | 9.23896mg/L | 3 | | citric acid | EC50 | 48 | Crustacea | >50mg/L | 2 | | citric acid | EC50 | 96 | Algae or other aquatic plants | 23.29809mg/L | 3 | | citric acid | EC0 | 72 | Crustacea | <80mg/L | 1 | | citric acid | NOEC | 16 | Crustacea | 153mg/L | 4 |

12.1 Toxicity

Fish LC50: >100mg/L

Persistence and degradability

Biodegradable in a waste treatment facility. BOD 5: 0.42. ThOD: 0.686.

12.3 Bioaccumulative potential

log Kow : -1.72

12.4 Mobility in soil

Environmental fate: Citric acid may be released into the environment as a result of its production and use as an additive in many processed food and beverages, pharmaceuticals, household cleaners, as well as in special technical applications. According to Level III generic fugacity model, citric acid will partition mainly to water (55.76%) and soil (44.20%) and with minimal distribution to air (0.02%) and sediment (0.02%). Terrestrial fate: If released to soil, citric acid is expected to be very highly mobile and is expected to exist primarily in the anion form in the environment, where anions generally do not adsorb strongly to soil containing organic carbon and clay compared to their neutral counterpart. Volatilization from moist and dry soil surfaces is not an important removal process for citric acid based upon its physico-chemical properties.

Persistence and degradability

Persistence and degradability | Ingredient | Persistence: Water/Soil | Persistence: Air | | citric acid | LOW | LOW |

Bioaccumulative potential

Bioaccumulative potential | Ingredient | Bioaccumulation | | citric acid | LOW (LogKOW = -1.64) |

Mobility in soil

Mobility in soil | Ingredient | Mobility | | --- | --- | | citric acid | LOW (KOC = 10) |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Legislation addressing waste disposal requirements may differ by country, state and/or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate: ► Reduction ► Reuse ► Recycling ► Disposal (if all else fails) This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

CITRIC ACID(77-92-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS: Australia Hazardous Substances Information System - Consolidated Lists, Australia Inventory of Chemical Substances (AICS)

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is CITRIC ACID known by?

CITRIC ACID is also known as: 1,2,3-tricarboxy-2-hydroxypropane; 2-hydroxy-1,2,3-propanetricarboxylic acid, 2-hydroxypropanetricarboxylic acid, APS AR00000161 USP00005262 AR00000160 UL00000162 BP00005263, Acide citrique Roche Ro-017548001, Acidecitrique, Aciletten Food additive, C6-H8-O7, Citraclean, Citretten, Citro ROA 10, Dettrex, Food Acid 330, HOC(CH2COOH)2COOH, HOC-(CH2-CO2-H)2-CO2-H, beta-hydroxycarboxylic acid, beta-hydroxytricarballylic acid

What is the hazard signal word for CITRIC ACID?

The signal word is warning.

What is the physical form of CITRIC ACID?

CITRIC ACID is a divided solid appearing as white odourless crystals, granules or powder; mixes with water, alcohol and methanol; practically insoluble in chloroform. .

What is CITRIC ACID used for?

Component acidulant in beverages, confectionery, effervescent salts, in pharmaceutical syrups, medicines, in effervescent powders and tablets. Used to adjust the pH of foods and as synergistic antioxidant. Used in beverages, jellies, jams, preserves and candy to provide tartness. Manufacture of citrate salts.

What are the hazard statements for CITRIC ACID?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.

What is the melting point of CITRIC ACID?

The melting point is 153 °C and the boiling point is Decomposes.