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Safety Data Sheet EN

Citric acid

CAS 77-92-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Citric acid
Product Code
251275
Chemical Name
Citric acid

Regulatory Identifiers

CAS Number
77-92-9 Check regulations →
REACH No.
01-2119457026-42-XXXX

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

Precautionary Statements

P261 Avoid breathing dust.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
citric acid EC: 201-069-1 77-92-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Risk of dust explosion. Development of hazardous combustion gases or vapours possible in the event of fire.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed. Dry.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Required when dusts are generated. Recommended Filter type: Filter type P2. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Fat
---
Appearance
colourless, or, white
Auto Ignition Temperature
No data available
Relative Evaporation Rate
---
Partition Coefficient
log Pow: -1,72 at 20 °C
Voc Content
---
Molecular Weight
---
Form
---
Physical State
crystalline
Colour Intensity
---
Density
1,67 g/cm3 at 20 °C
Colour
colourless, or, white
Solubility In Water
1.330 g/l at 20 °C
Properties Status
---
Odor Threshold
---
Boiling Point
200 °C
Solidification Point
---
Cloud Point
---
Vapor Density
---
Decomposition Temperature
No data available
Odor
odourless
Lower Explosive Limit
No data available
Solubility
---
Melting Point
200 °C
Freezing Point
200 °C
State Under Standard Conditions
---
Upper Explosive Limit
No data available
Ph
ca.1,7 at 100 g/l at 20 °C
Bulk Density
---
Evaporation Rate
---
Metal Corrosion
---
Flash Point
Not applicable
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Crystallisation Point
---
Flammability
No data available
Softening Point
---
Physical State Data
solid
Relative Density
1,67 at 20 °C
Vapor Pressure
< 0,1 hPa at 25 °C
Explosive Limits
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Metals, Oxidizing agents, Bases, Reducing agents

Avoid

no information available

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

No data available

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

Shipping Name
Not dangerous goods
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Citric acid?

The signal word is warning.

What is the physical form of Citric acid?

Citric acid is a crystalline appearing as colourless, or, white with colourless, or, white color. It has odourless odor.

What is Citric acid used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Citric acid?

This substance has 2 hazard statements:

  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.

What is the melting point of Citric acid?

The melting point is 200 °C and the boiling point is 200 °C.