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Safety Data Sheet EN

FRAGOL HYDRAULIC P 46 FG

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
FRAGOL HYDRAULIC P 46 FG

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Hydraulic fluid Industrial use Professional use

Uses advised against

Do not use for private purposes (household)

Manufacturers & Suppliers

FRAGOL AG logo

FRAGOL AG

manufacturer

Solinger Straße 16, D-45481 Mülheim, Germany

+49 (0)208-300 02-40

http://www.fragol.de

Emergency Contacts

Emergency Contact

+49 (0) 208-300 02-40

Mon-Fri 09:00 - 17:00

Giftnotruf der Charité - Universitätsmedizin Berlin

+49 30 30 686 700

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS09 - Environmental hazard

GHS09

Hazard Statements

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

The product does not contain (other) ingredients which are classified according to present knowledge of the supplier and contribute to the classification of the product and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene EC: 270-128-1 68411-46-1 1% Yes
O,O,O-triphenyl phosphorothioate EC: 209-909-9 597-82-0 1% Yes

Notes

All the percentages given are percentages by weight unless stated otherwise.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract irritation, consult a physician.

Skin contact

Take off contaminated clothing. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.

Eye contact

Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion

Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. Call a POISON CENTER or doctor if you feel unwell.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical advice. If breathing is irregular or stopped, immediately seek medical assistance. In case of respiratory tract irritation, consult a physician. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor if you feel unwell.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray; Dry extinguishing powder; Carbon dioxide (CO2); Co-ordinate firefighting measures to the fire surroundings.

Unsuitable media

Water jet.

Specific hazards

During fire hazardous fumes/smoke could be produced.

Instructions

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

Self-contained breathing apparatus (EN 133). Standard protective clothing for firefighters.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Remove persons to safety. Ventilate affected area.

Environmental

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

Cleanup methods

Absorb with liquid-binding material (sand, diatomite, diatomaceous earth, acid binder, universal binder, sawdust).

Materials: sand, diatomite, diatomaceous earth, acid binder, universal binder, sawdust

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use local and general ventilation. Use only in well-ventilated areas. Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

Storage

Store in a well-ventilated place. Keep container tightly closed. Protect against external exposure, such as Heat. High temperatures. UV-radiation/sunlight.

Hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

Fire prevention

measures to prevent fire

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

General ventilation. Provide eyewash stations and safety showers at the workplace.

Hands

Wear suitable gloves. Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Chemical protection gloves are suitable, which are tested according to EN 374. ATTENTION: Wearing moisture-proof gloves (occlusion) for longer than 4 hours is defined as a risk in Germany. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. - type of material: Nitrile rubber - material thickness: Use gloves with a minimum material thickness: ≥ 0,38 mm. - breakthrough time of the glove material: Use gloves with a minimum breakthrough time of the glove material: >480 minutes (permeation: level 6).

Eyes

Use safety goggle with side protection (EN 166).

Respiratory

In case of inadequate ventilation wear respiratory protection. Full face mask/half mask/quarter mask (EN 136/140). Breathing apparatus only in case of aerosol or mist formation.

Skin/Body

Protective clothing (EN 340 & EN ISO 13688).

Environmental

Take appropriate precautions to avoid uncontrolled release into the environment. Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless to yellow
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
---
Ph
not determined
Melting Point
not determined
Boiling Point
not determined
Flash Point
258 °C (ASTM D92)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
not determined
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,839 g/cm³ (ASTM D 1298)
Flammability
this material is combustible, but will not ignite readily
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
no data available
Solubility
---
Partition Coefficient
this information is not available
Solubility In Water
insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
44,6 mm²/g at 40 °C (ASTM D 445)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Reactivity

This material is not reactive under normal ambient conditions.

Hazardous reactions

No known hazardous reactions.

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible

Oxidisers.

Decomposition

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Acc. to 1272/2008/EC: Toxic to aquatic life with long lasting effects. Aquatic toxicity (acute) of components of the mixture | Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- |

12.1 Toxicity

| Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | O,O,O-triphenyl phosphorothioate | 597-82-0 | LL50 | >100 mg/l | fish | 96 h | | O,O,O-triphenyl phosphorothioate | 597-82-0 | EC50 | >100 mg/l | aquatic invertebrates | 48 h | | O,O,O-triphenyl phosphorothioate | 597-82-0 | EL50 | >100 mg/l | algae | 72 h |

12.1 Toxicity

| Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethyl-pentene | 68411-46-1 | LC50 | >100 mg/l | fish | 96 h | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethyl-pentene | 68411-46-1 | EC50 | 51 mg/l | aquatic invertebrates | 48 h | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethyl-pentene | 68411-46-1 | ErC50 | >100 mg/l | algae | 72 h | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethyl-pentene | 68411-46-1 | NOEC | 10 mg/l | aquatic invertebrates | 48 h |

12.1 Toxicity

| Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | O,O,O-triphenyl phosphorothioate | 597-82-0 | NOEC | ≥7,24 μg/l | aquatic invertebrates | 21 d | | O,O,O-triphenyl phosphorothioate | 597-82-0 | LOEC | >7,24 μg/l | aquatic invertebrates | 21 d |

12.1 Toxicity

| Name of substance | CAS No | Endpoint | Value | Species | Exposure time | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethyl-pentene | 68411-46-1 | EC50 | >100 mg/l | aquatic invertebrates | 24 h |

12.2 Persistence and degradability

Degradability of components | Name of substance | CAS No | Process | Degradation rate | Time | Method | | --- | --- | --- | --- | --- | --- |

12.2 Persistence and degradability

| Name of substance | CAS No | Process | Degradation rate | Time | Method | | O,O,O-triphenyl phosphorothioate | 597-82-0 | carbon dioxide generation | 17,8 - 19,3 % | 29 d | |

12.2 Persistence and degradability

| Name of substance | CAS No | Process | Degradation rate | Time | Method | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene | 68411-46-1 | carbon dioxide generation | 0 % | 28 d | |

12.3 Bioaccumulative potential

| Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | O,O,O-triphenyl phosphorothioate | 597-82-0 | | 5 (pH value: 6,4) | |

12.3 Bioaccumulative potential

| Name of substance | CAS No | BCF | Log KOW | BOD5/COD | | Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene | 68411-46-1 | 411 | 6,66 (pH value: 6,67, 23 °C) | |

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Does not contain a PBT-/vPvB-substance at a concentration of ≥ 0,1%.

The substance does not contain PBT or vPvB substances at concentrations of 0.1% or higher.

12.6 Endocrine disrupting properties

Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.

12.7 Other adverse effects

Data are not available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not empty into drains. Avoid release to the environment.

Waste Codes

13 01 11* synthetic hydraulic oils EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport Class
9
Packing Group
III
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for FRAGOL HYDRAULIC P 46 FG?

The signal word is no signal word.

What is the physical form of FRAGOL HYDRAULIC P 46 FG?

FRAGOL HYDRAULIC P 46 FG is a liquid with colourless to yellow color. It has characteristic odor.

What is FRAGOL HYDRAULIC P 46 FG used for?

Hydraulic fluid Industrial use Professional use

What are the hazard statements for FRAGOL HYDRAULIC P 46 FG?

This substance has 1 hazard statement:

  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of FRAGOL HYDRAULIC P 46 FG?

The melting point is not determined and the boiling point is not determined.