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Safety Data Sheet EN

Ethanol, absolute

CAS 64-17-5
EC 200-578-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethanol, absolute
Product Code
444220000, 444220050
Synonyms
Ethyl alcohol; Absolute ethanol

Regulatory Identifiers

CAS Number
64-17-5 Check regulations →
EC Number
200-578-6 Check regulations →
REACH No.
01-2119457610-43

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

national supplier

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

A

Acros Organics BVBA

national supplier

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Emergency Contact

001-800-ACROS-01

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor
H319 Causes serious eye irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P264 Wash face, hands and any exposed skin thoroughly after handling
P280 Wear eye protection/ face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P337 + P313 If eye irritation persists: Get medical advice/attention

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ethyl alcohol EC: 200-578-6 64-17-5 99 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: Difficulty in breathing.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Vapors may form explosive mixtures with air.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required.

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Ensure adequate ventilation. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Butyl rubber (> 480 minutes, 0.38 mm - 0.56 mm, Level 6, EN374-3), Neoprene (> 480 minutes, 0.45 mm, EN 374), PVC (< 60 minutes, 0.18 mm), Viton (R) (> 480 minutes, 0.7 mm).

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Maintain adequate ventilation

Skin/Body

Long sleeved clothing

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear, Colorless
Colour
---
Colour Intensity
---
Form
---
Odor
Alcohol
Odor Threshold
No data available
Ph
7 @ 20°C
Melting Point
-114 °C / -173.2 °F
Boiling Point
78 °C / 172.4 °F
Flash Point
13 °C / 55.4 °F Method - No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
No data available
Vapor Density
No data available
Relative Density
---
Bulk Density
Not applicable
Density
0.785 g/cm3 @20°C
Flammability
Highly flammable
Upper Explosive Limit
Upper 19 vol %
Lower Explosive Limit
Lower 3.3 vol %
Explosive Limits
---
Auto Ignition Temperature
363 °C / 685.4 °F
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
log Pow -0.32 (Ethyl alcohol)
Solubility In Water
Miscible
Solubility In Fat
---
Molecular Weight
46.07
Voc Content
100% (Organic Carbon (by mass) = 52.1 %) (EC/1999/13)
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Incompatible products. Heat, flames and sparks. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents. Strong acids. Acid anhydrides. Acid chlorides.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Component | Freshwater Fish | Water Flea | Freshwater Algae | | --- | --- | --- | --- | | Ethyl alcohol | Fathead minnow (Pimephales promelas) LC50 = 14200 mg/l/96h | EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h | EC50 (72h) = 275 mg/l (Chlorella vulgaris) |

12.1. Toxicity

Photobacterium phosphoreum:EC50 = 34634 mg/L/30 min Photobacterium phosphoreum:EC50 = 35470 mg/L/5 min

12.2. Persistence and degradability

Residly biodegradable Persistence Persistence is unlikely, based on information available. | Component | Degradability | | --- | --- |

The substance is readily biodegradable and persistence is unlikely based on available information.

12.2. Persistence and degradability

| Component | Degradability | | --- | --- | | Ethyl alcohol 64-17-5 (99-100) | OECD 301E = 94% |

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- |

Bioaccumulation is unlikely

12.3. Bioaccumulative potential

| Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- | | Ethyl alcohol | -0.32 | No data available |

12.4. Mobility in soil

The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. Will likely be mobile in the environment due to its volatility. Disperses rapidly in air

12.5. Results of PBT and vPvB assessment

Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB).

The substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB).

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

Persistent Organic Pollutant Ozone Depletion Potential This product does not contain any known or suspected substance This product does not contain any known or suspected substance
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Can be landfilled or incinerated, when in compliance with local regulations.

Disposal

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Waste Codes

Not specified Waste Codes are not product specific, but application specific. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1170
Shipping Name
ETHANOL
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ethanol, absolute known by?

Ethanol, absolute is also known as: Ethyl alcohol; Absolute ethanol

What is the hazard signal word for Ethanol, absolute?

The signal word is danger.

What is the physical form of Ethanol, absolute?

Ethanol, absolute is a liquid appearing as clear, colorless . It has alcohol odor.

What is Ethanol, absolute used for?

Laboratory chemicals.

What are the hazard statements for Ethanol, absolute?

This substance has 2 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H319: Causes serious eye irritation

What is the melting point of Ethanol, absolute?

The melting point is -114 °C / -173.2 °F and the boiling point is 78 °C / 172.4 °F.