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Safety Data Sheet EN

LOCTITE SF 7240

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE SF 7240
Product Code
34882
Synonyms
7240 90 ML E/G/A

Regulatory Identifiers

CAS Number
N/A
UFI Code
ET2A-UWVP-W206-RH3V

Identified Uses

activator

Manufacturers & Suppliers

Henkel Ltd logo

Henkel Ltd

manufacturer

Adhesives Wood Lane End HP2 4RQ Hemel Hempstead Great Britain

+44 (1442) 278000

http://www.mysds.henkel.com

Emergency Contacts

Emergency Contact

+44 (0)1442 278497

24 Hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H317 May cause an allergic skin reaction.

Precautionary Statements

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
2,2'-Ethylenedioxydiethyl dimethacrylate EC: 203-652-6 109-16-0 50 - 100% Yes
Hydroxypropyl methacrylate EC: 248-666-3 27813-02-1 1 - 5% Yes
methyl methacrylate EC: 201-297-1 80-62-6 0.1 - 1% Yes
Copper naphthenate EC: 215-657-0 1338-02-9 0.1 - 0.25% Yes
Limonene, D- EC: 227-813-5 5989-27-5 0.1 - 1% Yes

Notes

If no ATE values are displayed, please refer to LD/LC50 values in Section 11.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If symptoms persist, seek medical advice.

Skin contact

Rinse with running water and soap. Obtain medical attention if irritation persists.

Symptoms: SKIN: Rash, Urticaria. Prolonged or repeated contact may cause eye irritation.

Eye contact

Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist.

Symptoms: Prolonged or repeated contact may cause eye irritation.

Ingestion

Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

water, carbon dioxide, foam, powder

Unsuitable media

High pressure waterjet

Specific hazards

In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released.

Instructions

In case of fire, keep containers cool with water spray.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid contact with skin and eyes. Wear protective equipment.

Small spill

For small spills wipe up with paper towel and place in container for disposal.

Large spill

For large spills absorb onto inert absorbent material and place in sealed container for disposal.

Environmental

Do not empty into drains / surface water / ground water.

—

Related Products

Similar products with comparable safety profiles

L

LOCTITE SF 7200

---

L

LOCTITE SF 7649

---

L

LOCTITE SF 7840

UFI: Y5G7-SXF9-J20R-N0DE

L

LOCTITE SF 7471

---

L

LOCTITE SF 7070

---

L

LOCTITE SF 7803

---

L

LOCTITE SF 7063

---

L

LOCTITE SF 7039

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid skin and eye contact. See advice in section 8.

Storage

Refer to Technical Data Sheet.

Hygiene

Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure good ventilation/extraction.

Hands

Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eyes

Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Protective eye equipment should conform to EN166.

Respiratory

Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387)

Skin/Body

Wear suitable protective clothing. Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Green
Colour Intensity
---
Form
---
Odor
Acrylic
Odor Threshold
---
Ph
Not applicable, Product is non-soluble (in water).
Melting Point
Not applicable, Product is a liquid
Boiling Point
162 °C (323.6 °F)
Flash Point
> 150 °C (> 302 °F) The product does not support combustion in any way.
Freezing Point
---
Softening Point
---
Solidification Point
< 0 °C (< 32 °F)
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0,08 Pa (20 °C (68 °F))
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,05 - 1,09 g/cm3 None
Flammability
The product is not flammable.
Upper Explosive Limit
Not applicable, The product is not flammable.
Lower Explosive Limit
Not applicable, The product is not flammable.
Explosive Limits
---
Auto Ignition Temperature
225 °C (437 °F)
Decomposition Temperature
Not applicable, Substance/mixture is not self-reactive, no organic peroxide and does not decompose under foreseen conditions of use
Solubility
---
Partition Coefficient
Not applicable, Mixture
Solubility In Water
Not miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
9,15 mm2/s (20 °C (68 °F); )
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

Reacts with strong oxidants. Acids. Reducing agents. Strong bases.

Hazardous reactions

See section reactivity

Avoid

Stable under normal conditions of storage and use.

Incompatible

See section reactivity.

Decomposition

carbon oxides. Hydrocarbons nitrogen oxides Rapid polymerisation may generate excessive heat and pressure.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. The table below presents the data of the classified substances present in the mixture.

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | LC50 | 16,4 mg/l | 96 h | Danio rerio | OECD Guideline 203 (Fish, Acute Toxicity Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | LC50 | 493 mg/l | 48 h | Leuciscus idus melanotus | DIN 38412-15 |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | LC50 | 350 mg/l | 96 h | Leuciscus idus | OECD Guideline 203 (Fish, Acute Toxicity Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Copper naphthenate 1338-02-9 | LC50 | 0,161 mg/l | 96 h | Oncorhynchus mykiss | OECD Guideline 203 (Fish, Acute Toxicity Test) |

12.1. Toxicity

## 12.1. Toxicity | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Limonene, D-5989-27-5 | LC50 | 0,702 mg/l | 96 h | Pimephales promelas | OECD Guideline 203 (Fish, Acute Toxicity Test) | | Limonene, D-5989-27-5 | LC10 | 0,32 mg/l | 8 d | Pimephales promelas | OECD Guideline 212 (Fish, Short-term Toxicity Test on Embryo and Sac-Fry Stages) | ### Toxicity (aquatic invertebrates): The mixture is classified based on calculation method referring to the classified substances present in the mixture. The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | EC50 | >143 mg/l | 48 h | Daphnia magna | OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | EC50 | 69 mg/l | 48 h | Daphnia magna | EPA OTS 797.1300 (Aquatic Invertebrate Acute Toxicity Test, Freshwater Daphnids) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Limonene, D-5989-27-5 | EC50 | 0,577 mg/l | 48 h | Daphnia magna | OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) | ### Chronic toxicity (aquatic invertebrates): The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- |

12.1. Toxicity

12.1. Toxicity | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | NOEC | 32 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | NOEC | 45,2 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | NOEC | 37 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) |

12.1. Toxicity

12.1. Toxicity | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Limonene, D-5989-27-5 | EC10 | 0,153 mg/l | 21 d | Daphnia magna | OECD 211 (Daphnia magna, Reproduction Test) | ## Toxicity (Algae): The mixture is classified based on calculation method referring to the classified substances present in the mixture. The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | EC50 | > 100 mg/l | 72 h | Pseudokirchneriella subcapitata | OECD Guideline 201 (Alga, Growth Inhibition Test) | | 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | NOEC | 18,6 mg/l | 72 h | Pseudokirchneriella subcapitata | OECD Guideline 201 (Alga, Growth Inhibition Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | EC50 | > 97,2 mg/l | 72 h | Pseudokirchneriella subcapitata | OECD Guideline 201 (Alga, Growth Inhibition Test) | | Hydroxypropyl methacrylate 27813-02-1 | NOEC | > 97,2 mg/l | 72 h | Pseudokirchneriella subcapitata | OECD Guideline 201 (Alga, Growth Inhibition Test) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | EC50 | 170 mg/l | 96 h | Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) | OECD Guideline 201 (Alga, Growth Inhibition Test) | | methyl methacrylate 80-62-6 | NOEC | 100 mg/l | 96 h | Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) | OECD Guideline 201 (Alga, Growth Inhibition Test) |

12.1. Toxicity

## 12.1. Toxicity | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Limonene, D-5989-27-5 | EC50 | 0,32 mg/l | 72 h | Pseudokirchneriella subcapitata | OECD Guideline 201 (Alga, Growth Inhibition Test) | | Limonene, D-5989-27-5 | EC10 | 0,174 mg/l | 72 h | Pseudokirchneriella subcapitata | OECD Guideline 201 (Alga, Growth Inhibition Test) | ## Toxicity (microorganisms): The mixture is classified based on calculation method referring to the classified substances present in the mixture. The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | EC10 | 1.140 mg/l | 16 h | | not specified |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | EC20 | > 150 - 200 mg/l | 30 min | activated sludge, domestic | ISO 8192 (Test for Inhibition of Oxygen Consumption by Activated Sludge) |

12.1. Toxicity

| Hazardous substances CAS-No. | Value type | Value | Exposure time | Species | Method | | --- | --- | --- | --- | --- | --- | | Limonene, D-5989-27-5 | EC10 | 18 mg/l | 3 h | activated sludge of a predominantly domestic sewage | OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test) |

12.2. Persistence and degradability

12.2. Persistence and degradability

The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | readily biodegradable | aerobic | 85 % | 28 d | OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) |

12.2. Persistence and degradability

| Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | readily biodegradable | aerobic | 94,2 % | 28 d | OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test) |

12.2. Persistence and degradability

Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | readily biodegradable | aerobic | 94 % | 14 d | OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) |

12.2. Persistence and degradability

Hazardous substances CAS-No. | Result | Test type | Degradability | Exposure time | Method Limonene, D-5989-27-5 | readily biodegradable | aerobic | 71,4 % | 28 d | OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test)

12.3. Bioaccumulative potential

No substance data available. No data available.

No substance data available.

12.4. Mobility in soil

The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | LogPow | Temperature | Method | | --- | --- | --- | --- |

The table below presents the data of the classified substances present in the mixture.

12.4. Mobility in soil

| 2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | 2,3 | | OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC Method) |

12.4. Mobility in soil

| Hazardous substances CAS-No. | LogPow | Temperature | Method | | --- | --- | --- | --- | | Hydroxypropyl methacrylate 27813-02-1 | 0,97 | 20 °C | not specified |

12.4. Mobility in soil

| Hazardous substances CAS-No. | LogPow | Temperature | Method | | --- | --- | --- | --- | | methyl methacrylate 80-62-6 | 1,38 | 20 °C | other guideline: |

12.4. Mobility in soil

| Hazardous substances CAS-No. | LogPow | Temperature | Method | | --- | --- | --- | --- | | Limonene, D-5989-27-5 | 4,57 | | not specified |

12.5. Results of PBT and vPvB assessment

The table below presents the data of the classified substances present in the mixture. | Hazardous substances CAS-No. | PBT / vPvB | | --- | --- |

12.5. Results of PBT and vPvB assessment

2,2'-Ethylenedioxydiethyl dimethacrylate 109-16-0 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

The substance does not fulfill PBT or vPvB criteria.

12.5. Results of PBT and vPvB assessment

Hazardous substances CAS-No. | PBT / vPvB --- Hydroxypropyl methacrylate 27813-02-1 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

The substance does not fulfill the PBT or vPvB criteria.

12.5. Results of PBT and vPvB assessment

Hazardous substances CAS-No. | PBT / vPvB --- --- methyl methacrylate 80-62-6 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

The substance does not fulfill the criteria for Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB).

12.5. Results of PBT and vPvB assessment

| Hazardous substances CAS-No. | PBT / vPvB | | --- | --- | | Limonene, D-5989-27-5 | Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. |

Limonene, D (CAS 5989-27-5) does not fulfill the PBT or vPvB criteria.

12.6. Endocrine disrupting properties

not applicable

not applicable

12.7. Other adverse effects

No data available.

No data available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations.

Waste Codes

08 04 09* waste adhesives and sealants containing organic solvents and other dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is LOCTITE SF 7240 known by?

LOCTITE SF 7240 is also known as: 7240 90 ML E/G/A

What is the hazard signal word for LOCTITE SF 7240?

The signal word is warning.

What is the physical form of LOCTITE SF 7240?

LOCTITE SF 7240 is a liquid with green color. It has acrylic odor.

What is LOCTITE SF 7240 used for?

activator

What are the hazard statements for LOCTITE SF 7240?

This substance has 1 hazard statement:

  • H317: May cause an allergic skin reaction.

What is the melting point of LOCTITE SF 7240?

The melting point is Not applicable, Product is a liquid and the boiling point is 162 °C (323.6 °F).