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Safety Data Sheet EN

Automat XR Developer concentrate

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Automat XR Developer concentrate

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Special X-ray set for Dürr developers.

Uses advised against

None, if handled according to order.

Manufacturers & Suppliers

o

orochemie GmbH + Co. KG

manufacturer

Max-Planck-Straße 27, 70806 Kornwestheim

+49 7154 1308-0

D

DÜRR DENTAL AG

distributor

Höpfigheimer Straße 17, 74321 Bietigheim-Bissingen, Germany

+49 7142 705-0

D

DÜRR DENTAL [Products] UK Ltd.

distributor

14 Linnell Way - Telford Way Industrial Estate, Kettering Northants NN16 8PS, United Kingdom

+44 1536 526740

Emergency Contacts

Emergency Contact

+49 6132 84463

24 h/7 d

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aquatic Acute Cat. 1 H400
Carcinogenicity Cat. 2 H351
Eye Dam. Cat. 1 H318
Skin Irrit. Cat. 2 H315
Muta. Cat. 2 H341
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.

Precautionary Statements

P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves and eye/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Dür Automat XR Developer concentrate contains hydroquinone, potassium carbonate, potassium sulphite, potassium hydroxide, complexing agents, stabilizers and auxiliary agents in aqueous solution.

Chemical Name CAS Number Concentration Hazardous
1,4-DIHYDROXYBENZENE EC: 204-617-8 123-31-9 5 - 10% Yes
POTASSIUM CARBONATE EC: 209-529-3 584-08-7 5 - 10% Yes
2,2'-OXYBISETHANOL EC: 203-872-2 111-46-6 1 - 5% Yes
POTASSIUM HYDROXIDE EC: 215-181-3 1310-58-3 0.5 - 1% Yes
4-(HYDROXYMETHYL)-4-METHYL-1-PHENYL-PYRAZOLIDIN-3-ON EC: 235-920-3 13047-13-7 0.5% Yes

Full text of R-, H- and EUH-phrases: see section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In case of respiratory tract irritation, consult a physician.

Skin contact

Wash with plenty of water. In case of skin irritation, consult a physician.

Eye contact

Remove contact lenses, keep eyelids open. In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.

Symptoms: Causes serious eye damage.

Ingestion

If swallowed, immediately drink: Water. Never give anything by mouth to an unconscious person or a person with cramps. Do not induce vomiting. Call a physician immediately.

Immediate Medical Attention

In case of respiratory tract irritation, skin irritation, or ingestion, consult a physician or ophthalmologist immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguishing powder. Water spray Water mist The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.

Unsuitable media

High power water jet.

Specific hazards

None known.

Instructions

Adapt protective equipment to surrounding fire.

Firefighter Protection

Adapt protective equipment to surrounding fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection equipment. See protective measures under point 7 and 8.

Environmental

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

Cleanup methods

Absorb with liquid-binding material. Collect in closed and suitable containers for disposal.

Materials: liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents)

—

Related Products

Similar products with comparable safety profiles

A

Automat XR Fixer concentrate

---

T

Trionic Concentrate

---

A

AT10-Concentrate

CAS: 1338-43-8

S

Stahl Integra® XR-9900

---

X

XTRASE®

CAS: 9001-73-4

E

EXOCOAT AG-2 Development product

---

A

AZ 300 MIF Developer

---

S

SynerXID

---

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep/Store only in original container. Please note safety instructions and directions for use on the drum. Open and handle container with care. Do not breathe vapour/aerosol.

Storage

Keep/Store only in original container.

Hygiene

When using do not smoke.

Fire prevention

Usual measures for fire prevention. When using do not smoke.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No particular measures required.

Hands

Short-term exposure (Level 2: < 30 min): disposable gloves to EN374 category III, e.g. nitrile rubber, material thickness 0.1 mm. Long-term exposure (Level 6: < 480 min): protective gloves to EN374 category III, e.g. nitrile rubber, material thickness 0.7 mm. When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits.

Eyes

Eye glasses with side protection DIN EN 166

Respiratory

Usually no personal respirative protection necessary.

Skin/Body

Body protection: not applicable.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
yellow-orange
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
No data available
Ph
10 - 11
Melting Point
No data available
Boiling Point
ca. 100 °C
Flash Point
not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
No data available
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,2 - 1,4 g/cm³
Flammability
---
Upper Explosive Limit
not applicable
Lower Explosive Limit
not applicable
Explosive Limits
---
Auto Ignition Temperature
not applicable
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
100 Wt %
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
Not corrosive to metals.
Dynamic Viscosity
---
Kinematic Viscosity
< 12 s DIN-cup 4 mm
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions (see section 7).

Reactivity

None, if handled according to order.

Hazardous reactions

No information available.

Avoid

No information available.

Incompatible

None known.

Decomposition

No information available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Aquatic toxicity Parameter : LC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 ) Species : Gambusia affinis (Mosquito fish) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 80 mg/l Exposure time : 96 h

12.1 Toxicity

Aquatic toxicity There are no data available on the preparation itself. Acute (short-term) fish toxicity

There are no data available on the preparation itself.

12.1 Toxicity

Aquatic toxicity Parameter : LC50 ( 1,4-DIHYDROXYBENZENE ; CAS No. : 123-31-9 ) Species : Oncorhynchus mykiss (Rainbow trout) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 0,638 mg/l Exposure time : 96 h

12.1 Toxicity

Aquatic toxicity Parameter : LC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Pimephales promelas (fathead minnow) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 75200 mg/l Exposure time : 96 h

12.1 Toxicity

Aquatic toxicity Parameter : LC50 ( POTASSIUM CARBONATE ; CAS No. : 584-08-7 ) Species : Oncorhynchus mykiss (Rainbow trout) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 68 mg/l Exposure time : 96 h

12.1 Toxicity

### Aquatic toxicity Parameter : LC50 ( 4-(HYDROXYMETHYL)-4-METHYL-1-PHENYL-PYRAZOLIDIN-3-ON ; CAS No. : 13047-13-7 ) Species : Pimephales promelas (fathead minnow) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 1 - 10 mg/l Parameter : LC50 ( 4-(HYDROXYMETHYL)-4-METHYL-1-PHENYL-PYRAZOLIDIN-3-ON ; CAS No. : 13047-13-7 ) Species : Leuciscus idus (golden orfe) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 35 mg/l Exposure time : 48 h

12.1 Toxicity

Aquatic toxicity Parameter : LC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 ) Species : Poecilia reticulata (Guppy) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 165 mg/l Exposure time : 24 h

12.1 Toxicity

### Aquatic toxicity Parameter : LC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Carassius auratus (goldfish) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : > 5000 Exposure time : 24 h Parameter : LC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Gambusia affinis (Mosquito fish) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : > 100 mg/l Exposure time : 96 h Parameter : LC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Leuciscus idus (golden orfe) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : > 10000 mg/l Exposure time : 96 h Parameter : LC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Oncorhynchus mykiss (Rainbow trout) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : > 1000 mg/l Exposure time : 96 h Parameter : LC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Pimephales promelas (fathead minnow) Evaluation parameter : Acute (short-term) fish toxicity Effective dose : 75200 mg/l Exposure time : 96 h

12.1 Toxicity

Parameter : NOEC ( POTASSIUM CARBONATE ; CAS No. : 584-08-7 ) Species : Oncorhynchus mykiss (Rainbow trout) Evaluation parameter : Chronic (long-term) fish toxicity Effective dose : 33 mg/l Exposure time : 96 h

12.1 Toxicity

# Acute (short-term) daphnia toxicity Parameter : EC50 ( 1,4-DIHYDROXYBENZENE ; CAS No. : 123-31-9 ) Species : Daphnia magna (Big water flea) Evaluation parameter : Acute (short-term) daphnia toxicity Effective dose : 0,134 mg/l

12.1 Toxicity

Acute (short-term) daphnia toxicity Parameter : EC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Daphnia magna (Big water flea) Evaluation parameter : Acute (short-term) daphnia toxicity Effective dose : > 10000 mg/l Exposure time : 24 h

12.1 Toxicity

Acute (short-term) daphnia toxicity Parameter : EC50 ( POTASSIUM CARBONATE ; CAS No. : 584-08-7 ) Species : Daphnia magna (Big water flea) Evaluation parameter : Acute (short-term) daphnia toxicity Effective dose : 200 mg/l Exposure time : 48 h

12.1 Toxicity

# Acute (short-term) daphnia toxicity Parameter : EC50 ( 4-(HYDROXYMETHYL)-4-METHYL-1-PHENYL-PYRAZOLIDIN-3-ON ; CAS No. : 13047-13-7 ) Species : Daphnia magna (Big water flea) Evaluation parameter : Acute (short-term) daphnia toxicity Effective dose : 7,1 mg/l Exposure time : 24 h

12.1 Toxicity

# Acute (short-term) daphnia toxicity Parameter : EC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Daphnia magna (Big water flea) Effective dose : 48900 mg/l Exposure time : 48 h

12.1 Toxicity

Chronic (long-term) daphnia toxicity Parameter : NOEC ( 1,4-DIHYDROXYBENZENE ; CAS No. : 123-31-9 ) Species : Daphnia magna (Big water flea) Evaluation parameter : Chronic (long-term) daphnia toxicity Effective dose : 0,0057 mg/l Exposure time : 504 h

12.1 Toxicity

Acute (short-term) algae toxicity Parameter : EC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Selenastrum capricornutum Evaluation parameter : Inhibition of growth rate Effective dose : > 100 mg/l

12.1 Toxicity

Acute (short-term) algae toxicity Parameter : ErC50 ( 1,4-DIHYDROXYBENZENE ; CAS No. : 123-31-9 ) Species : Pseudokirchneriella subcapitata Evaluation parameter : Acute (short-term) algae toxicity Effective dose : 0,33 mg/l Exposure time : 72 h

12.1 Toxicity

Chronic (long-term) algae toxicity Parameter : NOEC ( 1,4-DIHYDROXYBENZENE ; CAS No. : 123-31-9 ) Species : Pseudokirchneriella subcapitata Evaluation parameter : Chronic (long-term) algae toxicity Effective dose : 0,019 mg/l Exposure time : 72 h

12.1 Toxicity

Chronic (long-term) algae toxicity Parameter : NOEC ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Scenedesmus quadricauda Evaluation parameter : Chronic (long-term) algae toxicity Effective dose : 2700 mg/l Exposure time : 192 h

12.1 Toxicity

Bacteria toxicity Parameter : EC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 ) Species : Bacteria Evaluation parameter : Bacteria toxicity Effective dose : 22 mg/l Exposure time : 0,25 h

12.1 Toxicity

Bacteria toxicity Parameter : EC50 ( 2,2' -OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Bacteria Evaluation parameter : Bacteria toxicity Effective dose : > 1,995 mg/l Exposure time : 0,5 h

12.1 Toxicity

Bacteria toxicity Parameter : EC50 ( 4-(HYDROXYMETHYL)-4-METHYL-1-PHENYL-PYRAZOLIDIN-3-ON ; CAS No. : 13047-13-7 ) Species : Pseudomonas putida Evaluation parameter : Bacteria toxicity Effective dose : 480 mg/l Exposure time : 16 h

12.1 Toxicity

Bacteria toxicity Parameter : EC10 ( 2,2'-OXYBISETHANOL ; CAS No. : 111-46-6 ) Species : Pseudomonas putida Evaluation parameter : Bacteria toxicity Effective dose : 8000 mg/l Exposure time : 16 h

12.2 Persistence and degradability

Abiotic degradation No data available. Biodegradation No data available.

12.3 Bioaccumulative potential

No information available.

12.4 Mobility in soil

Known or predicted distribution to environmental compartments There are no data available on the preparation itself.

12.5 Results of PBT and vPvB assessment

No information available.

12.6 Other adverse effects

No information available.

12.7 Further ecological information

Do not allow to enter into surface water or drains.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose according to legislation. Consult the appropriate local waste disposal expert about waste disposal.

Disposal

Dispose according to legislation. Consult the appropriate local waste disposal expert about waste disposal.

Waste Codes

09 01 01* water based developer baths EWC
15 01 10* packaging containing residues of or contaminated by hazardous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1,4-DIHYDROXYBENZENE)
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Restrictions of occupation: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Automat XR Developer concentrate?

The signal word is danger.

What is the physical form of Automat XR Developer concentrate?

Automat XR Developer concentrate is a liquid appearing as liquid with yellow-orange color. It has characteristic odor.

What is Automat XR Developer concentrate used for?

Special X-ray set for Dürr developers.

What are the hazard statements for Automat XR Developer concentrate?

This substance has 6 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H341: Suspected of causing genetic defects.
  • H351: Suspected of causing cancer.
  • H400: Very toxic to aquatic life.

What is the melting point of Automat XR Developer concentrate?

The melting point is No data available and the boiling point is ca. 100 °C.