R12276A

Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice. If breathing has stopped, assist ventilation with a mechanical device. Do not use mouth-to-mouth resuscitation if exposure to hydrogen sulphide is suspected.

Symptoms: If breathing has stopped.

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. In case of burns apply cold water until pain subsides then seek medical advice.

Symptoms: symptoms persist, burns, Dermatitis.

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists: Get medical advice/ attention.

Symptoms: Small amounts splashed into eyes can cause irreversible tissue damage and blindness. eye irritation.

Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Take victim immediately to hospital.

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames

High volume water jet

Not classified as flammable or combustible, but will combust if ignited.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Fire-fighters should exercise extreme caution in enclosed spaces due to the possible presence of toxic decomposition and combustion products. Self-contained full-face overpressure breathing apparatus should be used in enclosed spaces. Use standard body protective equipment.

Ensure adequate ventilation. Use personal protective equipment. Material can create slippery conditions. Avoid contact with spilled material. Do not touch or walk through spilled material.

Dyke far ahead of liquid spill for later recovery and disposal.

Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Try to prevent the material from entering drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities.

Recover by pumping or with suitable absorbent. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Clean contaminated floors and objects thoroughly while observing environmental regulations.

Materials: inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust)

Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Handle and open container with care. This product contains Zinc Dialkyl DithioPhosphate (ZDDP), a thermally sensitive substance. Do not reheat above the maximum loading temperature. Higher temperatures can result in exothermic decomposition of the ZDDP leading to the release of highly toxic hydrogen sulphide and possibly extremely odorous alkyl mercaptans. Alkyl mercaptans can be smelled at extremely low concentrations, and vapours may travel for many miles at detectable concentrations. These decomposition vapours are also flammable and may suddenly ignite when mixed with air in the presence of ignition sources such as sparks or flames. Caution must be exercised when heating this product. Electrical or steam heating systems with a self limiting maximum temperature not exceeding 120 deg C (e.g. low pressure steam at 1 bar(g) (15 psig)) is recommended when product cannot be agitated to avoid localised high temperatures. When heated, product temperature should be constantly monitored. Product should be stored below the recommended maximum loading / unloading temperature to avoid degradation of product quality and eventually decomposition. Extreme caution must be used in tank gauging or similar operations as overheating could lead to accumulation of lethal concentrations of hydrogen sulphide in the head-space of containers. Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may be released; this can cause rapid respiratory collapse, coma and death without necessarily any warning odour being sensed. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. No decomposition if stored and applied as directed. Do not reheat above: 65 °C (149 ° F) Storage temperature : <= 60 °C (140 ° F)

Smoking, eating and drinking should be prohibited in the application area.

Normal measures for preventive fire protection. These decomposition vapours are also flammable and may suddenly ignite when mixed with air in the presence of ignition sources such as sparks or flames.

See attached ES No special requirements under ordinary conditions of use and with adequate ventilation. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. When handling hot material, use heat resistant gloves. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Ensure that eyewash stations and safety showers are close to the workstation location. The applicable European standard can be found in EN 166.

In the case of vapour formation use a respirator with an approved filter. The applicable European standard can be found in EN 140, EN 137, EN 143, EN 14387.

Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing The applicable European standard can be found in EN 14605.

See attached ES Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Try to prevent the material from entering drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities.

Stable under recommended storage conditions.

No dangerous reaction known under conditions of normal use.

No hazards to be specially mentioned.

Excessive heat.

Strong oxidizing agents, water

Hydrogen Sulfide