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Safety Data Sheet EN

R10417A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
R10417A

Regulatory Identifiers

CAS Number
N/A
UFI Code
V2S2-51P1-A00G-KY9H

Identified Uses

Passenger car motor oil additive.

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL DEUTSCHLAND GMBH NIEDERLASSUNG HAMBURG logo

LUBRIZOL DEUTSCHLAND GMBH NIEDERLASSUNG HAMBURG

manufacturer

BILLBROOKDEICH 157 HAMBURG, D-22113 DE

+49 (0) 4032 3282-0

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

Emergency Contact

0 800 181 7059

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Aquatic Chronic Cat. 3 H412

GHS Pictograms

Hazard Statements

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
Calcium branched alkyl phenate sulphide (overbased) --- 5 - 10% Yes
zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) EC: 218-679-9 --- 3 - 5% Yes
Distillates (petroleum), hydrotreated heavy paraffinic EC: 265-157-1 --- 1 - 10% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC: 283-392-8 --- 1 - 2.5% Yes
2,6-Di-tert-butylphenol EC: 204-884-0 --- 0.25 - 1% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.01 - 0.25% Yes
Maleic anhydride EC: 203-571-6 --- 0.001% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash with soap and water. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. If irritation occurs, get medical assistance. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Immediate Medical Attention

If irritation occurs, get medical assistance. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

No unusual fire or explosion hazards noted.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Ventilate area if spilled in confined space or other poorly ventilated areas.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid environmental contamination. Open container in a well ventilated area. Avoid breathing vapors. Keep container closed when not in use and use with adequate ventilation.

Storage

Store away from incompatible materials. See section 10 for incompatible materials. Odorous and toxic fumes may form from the decomposition of this product if stored at temperatures in excess of 113 deg F (45 deg C) for extended periods of time or if heat sources in excess of 250 deg F (121 deg C) are used.

Hygiene

Observe good industrial hygiene practices.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For short-term, transient exposures and splash protection, gloves with shorter breakthrough times may commonly be used. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential.

Eyes

If contact is likely, safety glasses with side shields are recommended. Eye protection should meet the standards set out in EN 166.

Respiratory

Under normal use conditions, respirator is not usually required. Use appropriate respiratory protection if exposure to dust particles, mist or vapors is likely. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill cleanup sites. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark brown
Colour
Dark brown
Colour Intensity
---
Form
liquid
Odor
Mild
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
165 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
0,00635 PSI (40 °C)
Vapor Density
---
Relative Density
0,953 - 0,993 (15,6 °C)
Bulk Density
8,1 lb/gal (25 °C)
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
4000 mm2/s (40 °C); 170 mm2/s (100 °C )
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources, or oxidizing materials.

Incompatible

Strong mineral acids and strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide , nitrogen oxides, and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish Mineral oil|LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Calcium branched alkyl phenate sulphide (overbased) LC 50 (Fathead Minnow, 4 d): > 1.000 mg/l

12.1 Ecotoxicity

Fish zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl)bis(phosphorodithioate) LC 50 (Rainbow Trout, 4 Days): 4,5 mg/l LC 50 (Sheepshead Minnow, 4 Days): 46 mg/l

12.1 Ecotoxicity

Fish Distillates (petroleum), hydrotreated heavy paraffinic | LC 50 (Fathead Minnow, 96 h): > 100 mg/l

12.1 Ecotoxicity

Fish Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts|LC 50 (Rainbow Trout, 4 d): 4,5 mg/l LC 50 (Sheepshead Minnow, 4 d): 46 mg/l

12.1 Ecotoxicity

Fish 2,6-Di-tert-butylphenol LC 50 (Fathead Minnow, 4 d): 1,4 mg/l LC 50 (Rainbow Trout, 4 d): 13 mg/l

12.1 Ecotoxicity

Fish |Phenol, dodecyl-, branched|LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Ecotoxicity

Fish Maleic anhydride|LC 50 (Rainbow Trout, 4 Days): 75 mg/l

12.1 Toxicity

Aquatic Invertebrates: Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10.000 mg/l; EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l; NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Toxicity

Aquatic Invertebrates: Calcium branched alkyl phenate sulphide (overbased) EC 50 (Water flea (Daphnia magna), 48 h): > 1.000 mg/l

12.1 Toxicity

Aquatic Invertebrates: zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl)bis(phosphorodithioate) EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l; NOEC (Water flea (Daphnia magna), 21 d): 0,4 mg/l

12.1 Toxicity

Aquatic Invertebrates: Distillates (petroleum), hydrotreated heavy paraffinic: EC 50 (Water flea (Daphnia magna), 48 h): > 10.000 mg/l; EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l; NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Toxicity

Aquatic Invertebrates: Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0,8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0,4 mg/l

12.1 Toxicity

Aquatic Invertebrates: 2,6-Di-tert-butylphenol EC 50 (Water flea (Daphnia magna), 2 d): 0,45 mg/l EC 50 (Water flea (Daphnia magna), 2 d): 0,8 mg/l

12.1 Toxicity

Aquatic Invertebrates Phenol, dodecyl-, branched EC 50 (Water flea (Daphnia magna), 2 d): 0,037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0,58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0,0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0,0037 mg/l

12.1 Toxicity

Aquatic Invertebrates: Maleic anhydride EC 50 (Water flea (Daphnia magna), 2 d): 42,81 mg/l

Toxicity

Toxicity to Aquatic Plants: EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

Toxicity

Toxicity to Aquatic Plants: Calcium branched alkyl phenate sulphide (overbased) EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1.000 mg/l

Persistence and degradability

Not stated.

Bioaccumulative potential

Not stated.

Mobility in soil

Not stated.

Results of PBT and vPvB assessment

Not stated.

Endocrine disrupting properties

Not stated.

Other adverse effects

Not stated.

Toxicity to Aquatic Plants

zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl)bis(phosphorodithioate) EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): 21 mg/l

Toxicity to Aquatic Plants

EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): > 100 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): >= 100 mg/l

Toxicity to Aquatic Plants

EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 21 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 10 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants: 2,6-Di-tert-butylphenol EC 50 (Green algae (Selenastrum capricornutum), 3 d): 3,6 mg/l

Toxicity

Toxicity to Aquatic Plants Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0,36 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants: Maleic anhydride EC 50 (Green algae (Selenastrum capricornutum), 3 Days): 74,35 mg/l

Toxicity

Toxicity to microorganisms: EC 50 (Sludge, 0,1 d): > 1.000 mg/l

Toxicity

Toxicity to microorganisms: Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts: EC 50 (Sludge, 0,1 d): > 10.000 mg/l

12.1 Toxicity

Toxicity to microorganisms: 2,6-Di-tert-butylphenol EC 50 (Sludge, 0,1 d): > 1.000 mg/l

12.1 Toxicity

Toxicity to microorganisms Phenol, dodecyl-, branched EC 50 (Sludge, 0,1 d): > 1.000 mg/l

12.2 Persistence and Degradability

Biodegradation

12.2 Persistence and Degradability

Biodegradation Mineral oil|OECD TG 301 B, 31 %, 28 d, Not readily degradable.|

12.2 Persistence and Degradability

Biodegradation Calcium branched alkyl phenate sulphide (overbased)|OECD TG 301 B, 4,7 - 10,8 %, 28 d, Not readily degradable. Inherent Sludge, 38,8 %, 28 d

12.2 Persistence and Degradability

Biodegradation zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl)bis(phosphorodithioate) OECD TG 301 B, 1,5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Distillates (petroleum), hydrotreated heavy paraffinic|OECD TG 301 F, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts|OECD TG 301 B, 1,5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation |2,6-Di-tert-butylphenol|OECD TG 302 B, 24 %, 28 d, Not readily degradable. OECD TG 301 B, 5 %, 28 d, Not readily degradable.|

12.2 Persistence and Degradability

Biodegradation |Phenol, dodecyl-, branched|Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Maleic anhydride OECD TG 301 E, > 90 %, 28 d, Readily biodegradable OECD TG 302 B, 61 %, 28 d, Readily biodegradable

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) Calcium branched alkyl phenate Bioconcentration Factor (BCF): 2,2 sulphide (overbased) Phenol, dodecyl-, branched Bioconcentration Factor (BCF): 794,33 (Measured) Partition Coefficient n-octanol / water (log Kow) Calcium branched alkyl phenate Log Kow: 11,08 (Measured) sulphide (overbased) zinc O,O,O',O'-tetrakis(1,3Log Kow: 2,21 20 °C (Measured) dimethylbutyl) bis(phosphorodithioate) Phosphorodithioic acid, mixed Log Kow: 0,56 (Measured) O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts 2,6-Di-tert-butylphenol Log Kow: 4,5 (Measured) Phenol, dodecyl-, branched Log Kow: 7,14 (Measured) Maleic anhydride Log Kow: -0,048 (Read across)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine Disruption:

Product: This substance/mixture contains components considered to have endocrine disrupting properties for environment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. Phenol, dodecyl-, branched The substance is considered to have endocrine disrupting properties according to REACH Article 57(f) for the environment.

The substance is considered to have endocrine disrupting properties for the environment according to REACH Article 57(f).

12.7 Other adverse effects

This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity. Harmful to aquatic life with long lasting effects. Calcium branched alkyl phenate This material contains one or more components that have an sulphide (overbased) impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity.

The product contains an alkylated phenol impurity, but testing of the calcium phenate component indicates Aquatic Chronic 4 classification, overriding the impurity's classification for the final product. The product is classified as harmful to aquatic life with long lasting effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for R10417A?

The signal word is no signal word.

What is the physical form of R10417A?

R10417A is a liquid appearing as dark brown with dark brown color. It has mild odor.

What is R10417A used for?

Passenger car motor oil additive.

What are the hazard statements for R10417A?

This substance has 1 hazard statement:

  • H412: Harmful to aquatic life with long lasting effects.