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Safety Data Sheet EN

tert-Butanol for analysis EMSURE® ACS

CAS 75-65-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
tert-Butanol for analysis EMSURE® ACS
Product Code
1.09629

Regulatory Identifiers

CAS Number
75-65-0 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Acute Tox. Cat. 4 H332
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H336
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
tert-Butanol EC: 200-889-7 75-65-0 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature see product label.

Hygiene

Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,4 mm, Break through time: 480 min, Material tested: Camatril® (KCL 730 / Aldrich Z677442, Size M). Splash contact: Material: Chloroprene, Minimum layer thickness: 0,65 mm, Break through time: 240 min, Material tested: KCL 720 Camapren®. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Fat
---
Cloud Point
---
Properties Status
---
Decomposition Temperature
---
Flammability
---
Physical State
solid, liquid
Metal Corrosion
---
Lower Explosive Limit
2,3 %(V)
Vapor Pressure
40,7 hPa at 20 °C
Evaporation Rate
---
Dynamic Viscosity
3,3 mPa.s at 30 °C
Melting Point
24 - 25 °C
Softening Point
---
Odor
camphor-like
Explosive Limits
---
Flash Point
15 °C - closed cup
Colour Intensity
---
Relative Evaporation Rate
---
Form
---
Solubility In Water
at 20 °C soluble
Vapor Density
---
Solubility
---
Voc Content
---
Crystallisation Point
---
Physical State Data
liquid
Molecular Weight
---
Upper Explosive Limit
8,0 %(V)
Kinematic Viscosity
5,72 mm2/s at 25 °C - OECD Test Guideline 1142,23 mm2/s at 45 °C - OECD Test Guideline 114
Colour
colorless
Odor Threshold
---
Appearance
---
Bulk Density
---
Relative Density
---
Boiling Point
81 - 83 °C at 1.013 hPa
Partition Coefficient
log Pow: 0,30 - Bioaccumulation is not expected.
Auto Ignition Temperature
470 °C at 1.013 hPa
Density
0,775 g/cm3 at 20 °C
Freezing Point
---
State Under Standard Conditions
---
Ph
at 20 °Cneutral
Solidification Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapors may form explosive mixture with air.

Hazardous reactions

Violent reactions possible with: Alkali metals, Alkaline earth metals, Strong acids, Aluminum, Strong oxidizing agents

Avoid

Warming.

Incompatible

Alkali metals, Alkaline earth metals, Strong acids, Aluminum, Strong oxidizing agents

Decomposition

Peroxides. In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1120
Shipping Name
BUTANOLS
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for tert-Butanol for analysis EMSURE® ACS?

The signal word is danger.

What is the physical form of tert-Butanol for analysis EMSURE® ACS?

tert-Butanol for analysis EMSURE® ACS is a solid, liquid with colorless color. It has camphor-like odor.

What is tert-Butanol for analysis EMSURE® ACS used for?

Reagent for analysis

What are the hazard statements for tert-Butanol for analysis EMSURE® ACS?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.

What is the melting point of tert-Butanol for analysis EMSURE® ACS?

The melting point is 24 - 25 °C and the boiling point is 81 - 83 °C at 1.013 hPa.