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Safety Data Sheet EN

1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur

CAS 71-36-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur
Product Code
101990
Chemical Name
1-Butanol

Regulatory Identifiers

CAS Number
71-36-3 Check regulations →
REACH No.
01-2119484630-38-XXXX

Identified Uses

Reagent for analysis

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
STOT SE Cat. 3 H336
STOT SE Cat. 3 H335
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat.
P280 Wear eye protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Formula CH(CH)OH CHO (Hill); Molar mass 74,12 g/mol

Chemical Name CAS Number Concentration Hazardous
n-butanol EC: 200-751-6 71-36-3 100% Yes

Notes

Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air. Consult doctor if feeling unwell.

Symptoms: Cough, depressed respiration, Shortness of breath.

Skin contact

wash off with plenty of water. Remove contaminated clothing.

Symptoms: irritant effects

Eye contact

rinse out with plenty of water. Immediately call in ophthalmologist.

Symptoms: irritant effects

Ingestion

caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Consult a physician.

Symptoms: Nausea, Vomiting

Immediate Medical Attention

Consult doctor if feeling unwell, Immediately call in ophthalmologist, Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains. Risk of explosion.

Cleanup methods

Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,40 mm, Break through time: > 480 min. splash contact: Glove material: polychloroprene, Glove thickness: 0,65 mm, Break through time: > 120 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 730 Camatril® -Velours (full contact), KCL 720 Camapren® (splash contact).

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not empty into drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Auto Ignition Temperature
340 °C
Decomposition Temperature
No information available.
Evaporation Rate
No information available.
Ph
7 at 70 g/l 20 °C
Crystallisation Point
---
Form
liquid
Vapor Density
---
Vapor Pressure
6,7 hPa at 20 °C
Explosive Limits
---
Softening Point
---
Metal Corrosion
---
Colour
colourless
Flash Point
34 °C
Solubility In Water
66 g/l at 20 °C
Cloud Point
---
Density
0,81 g/cm3 at 20 °C
Upper Explosive Limit
11,3 %(V)
Solubility In Fat
---
Molecular Weight
---
Properties Status
---
Solidification Point
---
Voc Content
---
Flammability
No information available.
Bulk Density
---
Boiling Point
116 - 118 °C at 1.013 hPa
Odor
ethanolic
Physical State
liquid
Relative Evaporation Rate
---
State Under Standard Conditions
---
Physical State Data
liquid
Appearance
---
Lower Explosive Limit
1,4 %(V)
Kinematic Viscosity
---
Dynamic Viscosity
2,95 mPa.s at 20 °C
Partition Coefficient
log Pow: 1 (25 °C)
Freezing Point
---
Odor Threshold
0,004 - 48,7 ppm
Solubility
---
Colour Intensity
---
Melting Point
-89 °C
Relative Density
No information available.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Vapour/air-mixtures are explosive at intense warming. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: strong oxidising agents, chromium(VI) oxide. Exothermic reaction with: Alkali metals, Alkaline earth metals, Aluminium, strong reducing agents, Acid chlorides

Avoid

Heating.

Incompatible

rubber, various plastics

Decomposition

no information available

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1120
Shipping Name
BUTANOLS
Transport Class
3
Packing Group
III
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Take note of Dir 94/33/EC on the protection of young people at work. Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

The signal word is danger.

What is the physical form of 1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur is a liquid with colourless color. It has ethanolic odor.

What is 1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur used for?

Reagent for analysis

What are the hazard statements for 1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapour.
  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.

What is the melting point of 1-Butanol for analysis EMSURE® ACS, ISO, Reag. Ph Eur?

The melting point is -89 °C and the boiling point is 116 - 118 °C at 1.013 hPa.