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Safety Data Sheet EN

Propane

CAS 74-98-6
EC 200-827-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Propane
Chemical Name
Propane
Synonyms
Propel 110

Regulatory Identifiers

CAS Number
74-98-6 Check regulations →
EC Number
200-827-9 Check regulations →
REACH No.
01-2119486944-21

Identified Uses

Industrial and professional use for chemical analysis, calibration, (routine) quality control, laboratory use. Under controlled conditions.

Uses advised against

Contact supplier for more information on uses. Uses other than those listed above are not supported.

Manufacturers & Suppliers

B

BOC

manufacturer

Priestley Road, Worsley, M28 2UT Manchester

0800 111 333

Emergency Contacts

Emergency Contact

0800 111 333

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Press. Gas (Liq.) H280
Flam. Gas Cat. 1A H220

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical name: Propane; Purity: 100%

Chemical Name CAS Number Concentration Hazardous
Propane EC: 200-827-9 74-98-6 100% No

The concentrations of the components in the SDS header, product name on page one and in section 3.2 are in mol due to regulatory requirements. All concentrations are nominal. This substance has workplace exposure limit(s). PBT: persistent, bioaccumulative and toxic substance. vPvB: very persistent and very bioaccumulative substance.

Notes

The purity of the substance in this section is used for classification only, and does not represent the actual purity of the substance as supplied, for which other documentation should be consulted.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.

Symptoms: In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation.

Skin contact

In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Get medical attention.

Symptoms: Contact with evaporating liquid may cause frostbite or freezing of skin.

Eye contact

Rinse the eye with water immediately. Remove contact lenses, if present and easy to do. Continue rinsing. Flush thoroughly with water for at least 15 minutes. Get immediate medical assistance. If medical assistance is not immediately available, flush an additional 15 minutes.

Ingestion

Ingestion is not considered a potential route of exposure.

Immediate Medical Attention

Call a doctor. Get immediate medical assistance. Get medical attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Spray or Fog. Dry powder. Foam.

Unsuitable media

Carbon Dioxide.

Specific hazards

Incomplete combustion may form carbon monoxide

Instructions

In case of fire: Stop leak if safe to do so. Do not extinguish flames at leak because possibility of uncontrolled explosive reignition exists. Continue water spray from protected position until container stays cool. Use extinguishants to contain the fire. Isolate the source of the fire or let it burn out.

Firefighter Protection

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Guideline: EN 469 Protective clothing for firefighters. Performance requirements for protective clothing for firefighting. EN 15090 Footwear for firefighters. EN 659 Protective gloves for firefighters. EN 443 Helmets for fire fighting in buildings and other structures. EN 137 Respiratory protective devices - Self-contained open-circuit compressed air breathing apparatus with full face mask - Requirements, testing, marking.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate area. Provide adequate ventilation. Consider the risk of potentially explosive atmospheres. In case of leakage, eliminate all ignition sources.

Environmental

Prevent further leakage or spillage if safe to do so.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Only experienced and properly instructed persons should handle gases under pressure. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Purge system with dry inert gas (e.g. helium or nitrogen) before gas is introduced and when system is placed out of service. Purge air from system before introducing gas. Assess the risk of a potentially explosive atmosphere and the need for suitable equipment i.e. explosion-proof. Take precautionary measures against static discharges. Keep away from ignition sources (including static discharges). Provide electrical earthing of equipment and electrical equipment usable in explosive atmospheres. Use non-sparking tools. Protect containers from physical damage; do not drag, roll, slide or drop. Secure cylinders in an upright position at all times, close all valves when not in use. Suck back of water into the container must be prevented. Do not allow backfeed into the container. Avoid suckback of water, acid and alkalis. When using do not eat, drink or smoke.

Storage

Keep container below 50°C in a well ventilated place. Secure cylinders in an upright position at all times, close all valves when not in use. Store in accordance with local/regional/national/international regulations.

Hygiene

The substance must be handled in accordance with good industrial hygiene and safety procedures. When using do not eat, drink or smoke.

Fire prevention

Keep away from ignition sources (including static discharges). Provide electrical earthing of equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Consider a work permit system e.g. for maintenance activities. Ensure adequate air ventilation. Provide adequate general and local exhaust ventilation. Keep concentrations well below lower explosion limits. Gas detectors should be used when quantities of flammable gases or vapours may be released. Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. Systems under pressure should be regularly checked for leakages. Product to be handled in a closed system. Only use permanent leak tight installations (e.g. welded pipes). Take precautionary measures against static discharges.

Hands

Guideline: EN 388 Protective gloves against mechanical risks. Additional Information: Wear working gloves while handling containers

Eyes

Safety eyewear, goggles or face-shield to EN166 should be used to avoid exposure to liquid splashes. Wear eye protection to EN 166 when using gases. Guideline: EN 166 Personal Eye Protection.

Respiratory

When allowed by a risk assessment Respiratory Protective Equipment (RPE) may be used The selection of the Respiratory Protective Device (RPD) must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected RPD. Self-contained breathing apparatus (SCBA) or positive pressure airline with mask are to be used in oxygen-deficient atmospheres Guideline: EN 137 Respiratory protective devices - Self-contained open-circuit compressed air breathing apparatus with full face mask - Requirements, testing, marking.

Skin/Body

Wear fire resistant or flame retardant clothing. Guideline: ISO/TR 2801:2007 Clothing for protection against heat and flame -- General recommendations for selection, care and use of protective clothing. Other: Wear safety shoes while handling containers. Guideline: ISO 20345 Personal protective equipment - Safety footwear.

Environmental

Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment. For waste disposal, see section 13 of the SDS.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Gas
Physical State Data
gas
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
Liquefied gas
Odor
Odorless
Odor Threshold
Odor threshold is subjective and is inadequate to warn of over exposure.
Ph
Not applicable.
Melting Point
-187.6 °C
Boiling Point
-42.1 °C (1,013 hPa)
Flash Point
-104 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable to gases and gas mixtures.
Vapor Pressure
953.25 kPa (25 °C)
Vapor Density
---
Relative Density
0.5853 (-45 °C)
Bulk Density
---
Density
---
Flammability
Flammable Gas
Upper Explosive Limit
10.9 %(V)
Lower Explosive Limit
1.7 %(V)
Explosive Limits
---
Auto Ignition Temperature
450 °C
Decomposition Temperature
650 °C
Solubility
---
Partition Coefficient
2.36
Solubility In Water
75 mg/l
Solubility In Fat
---
Molecular Weight
44.09 g/mol (C3H8)
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.08 mPa.s (17.9 °C)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

No reactivity hazard other than the effects described in sub-section below.

Hazardous reactions

Can form a potentially explosive atmosphere in air. May react violently with oxidants.

Avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible

oxidants

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1965
Shipping Name
HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S.(Propane)
Transport Class
2
IATA

Passenger and cargo aircraft: Forbidden. Cargo aircraft only: Allowed.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Propane known by?

Propane is also known as: Propel 110

What is the hazard signal word for Propane?

The signal word is danger.

What is the physical form of Propane?

Propane is a gas appearing as colorless with colorless color. It has odorless odor.

What is Propane used for?

Industrial and professional use for chemical analysis, calibration, (routine) quality control, laboratory use. Under controlled conditions.

What are the hazard statements for Propane?

This substance has 2 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.

What is the melting point of Propane?

The melting point is -187.6 °C and the boiling point is -42.1 °C (1,013 hPa).