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Safety Data Sheet EN

Propane

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Propane

Regulatory Identifiers

CAS Number
N/A
UFI Code
2X2A-36WW-H00Y-H6K0

Identified Uses

Industrial and professional use. Perform risk assessment prior to use.

Uses advised against

Not for consumer use.

Manufacturers & Suppliers

A

Air Products Plc

manufacturer

2 Millennium Gate, Westmere Drive, Crewe, Cheshire

+44(0)3457 020202

Emergency Contacts

Emergency Contact

+44(0)8085 020202

NHS Direct in England or Wales

0845 46 47

NHS 24 in Scotland

08454 24 24 24

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Press. Gas (Liq.) H280

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Concentration is nominal. For the exact product composition, please refer to technical specifications.

Chemical Name CAS Number Concentration Hazardous
Propene EC: 204-062-1 115-07-1 7% Yes
Propane EC: 200-827-9 74-98-6 87% Yes
But-1-ene EC: 203-449-2 106-98-9 1% Yes
Butane EC: 203-448-7 106-97-8 2% Yes
Isobutane EC: 200-857-2 75-28-5 2% Yes

Notes

Refer to section 16 for full text of each relevant hazard statement (H).

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. In case of shortness of breath, give oxygen.

Symptoms: Exposure to oxygen deficient atmospheres may cause the following symptoms: Dizziness. Salivation. Nausea. Vomiting. Loss of mobility/consciousness. Shortness of breath.

Skin contact

Wash frost-bitten areas with plenty of water. Do not remove clothing. Cover wound with sterile dressing.

Eye contact

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Keep eye wide open while rinsing. Seek medical advice.

Ingestion

Ingestion is not considered a potential route of exposure.

Symptoms: Ingestion is not considered a potential route of exposure.

Immediate Medical Attention

If exposed or concerned: Get medical attention/advice.

Medical Treatment

If exposed or concerned: Get medical attention/advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Shutting off the source of the gas is the preferred method of control. Be aware of the risk of formation of static electricity with the use of CO2 extinguishers and do not use them in places where a flammable atmosphere may be present.

Unsuitable media

Do not use water jet to extinguish.

Specific hazards

Gas is heavier than air and may collect in low areas or travel along the ground where there may be an ignition source present. If flames are accidentally extinguished, explosive re-ignition may occur. Upon exposure to intense heat or flame, cylinder will vent rapidly and or rupture violently. Spontaneous/explosive re-ignition may occur.

Instructions

If possible, shut off the source of gas and allow the fire to burn itself out. Extinguish fire only if gas flow can be stopped. Do not extinguish a leaking gas flame unless absolutely necessary. Extinguish any other fire.

Firefighter Protection

Keep containers and surroundings cool with water spray. Move away from container and cool with water from a protected position. Keep adjacent cylinders cool by spraying with large amounts of water until fire burns itself out.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Remove all sources of ignition. Never enter a confined space or other area where the flammable gas concentration is greater the 10% of its lower flammable limit. Ventilate the area.

Environmental

Should not be released into the environment. Do not discharge into any place where its accumulation could be dangerous. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Prevent further leakage or spillage if safe to do so.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Protect cylinders from physical damage; do not drag, roll, slide or drop. Only experienced and properly instructed persons should handle compressed gases/cryogenic liquids. Before using the product, determine its identity by reading the label. Know and understand the properties and hazards of the product before use. When doubt exists as to the correct handling procedure for a particular gas, contact the supplier. Do not remove or deface labels provided by the supplier for the identification of the cylinder contents. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is ready for use. Use an adjustable strap wrench to remove over-tight or rusted caps. Before connecting the container, check the complete gas system for suitability, particularly for pressure rating and materials. Before connecting the container for use, ensure that back feed from the system into the container is prevented. Ensure the complete gas system is compatible for pressure rating and materials of construction. Ensure the complete gas system has been checked for leaks before use. Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with lower pressure rating than that of the container. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may damage valve, causing a leak to occur. Open valve slowly. If user experiences any difficulty operating cylinder valve discontinue use and contact supplier. Close container valve after each use and when empty, even if still connected to equipment. Never attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported immediately to the supplier. Close valve after each use and when empty. Replace outlet caps or plugs and container caps as soon as container is disconnected from equipment. Do not subject containers to abnormal mechanical shock. Never attempt to lift a cylinder by its valve protection cap or guard. Do not use containers as rollers or supports or for any other purpose than to contain the gas as supplied. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit. Do not smoke while handling product or cylinders. Never re-compress a gas or a gas mixture without first consulting the supplier. Never attempt to transfer gases from one cylinder/container to another. Always use backflow protective device in piping. Purge air from system before introducing gas. When returning cylinder install valve outlet cap or plug leak tight. Never use direct flame or electrical heating devices to raise the pressure of a container. Containers should not be subjected to temperatures above 50°C (122°F). Never attempt to increase liquid withdrawal rate by pressurizing the container without first checking with the supplier. Never permit liquefied gas to become trapped in parts of the system as this may result in hydraulic rupture.

Storage

Do not allow storage area temperature to exceed 50°C (122°F).

Hygiene

Do not smoke while handling product or cylinders.

Fire prevention

Do not smoke while handling product or cylinders. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit. Never use direct flame or electrical heating devices to raise the pressure of a container.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide natural or explosion-proof ventilation that is adequate to ensure flammable gas does not reach its lower explosive limit.

Hands

Wear work gloves when handling gas containers. Standard EN 388 - Protective gloves against mechanical risk.

Eyes

Safety glasses recommended when handling cylinders. Standard EN 166 - Personal eye-protection.

Respiratory

High concentrations that can cause rapid suffocation are within the flammable range and should not be entered.

Skin/Body

Consider the use of flame resistant anti-static safety clothing. Standard EN ISO 14116 - Limited flame spread materials. Standard EN ISO 1149-5 - Protective clothing: Electrostatic properties. Safety shoes are recommended when handling cylinders. Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Environmental

If applicable, refer to the extended section of the SDS for further information on CSA.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquefied gas.
Physical State Data
gas
State Under Standard Conditions
---
Appearance
---
Colour
Colorless gas
Colour Intensity
---
Form
---
Odor
Sweet. Poor warning properties at low concentrations. Stenchant often added.
Odor Threshold
Odour threshold is subjective and inadequate to warn of overexposure.
Ph
Not applicable for gases and gas mixtures.
Melting Point
No data available.
Boiling Point
- 44 F (-42 )
Flash Point
Not applicable for gases and gas mixtures.
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable for gases and gas mixtures.
Vapor Pressure
141.69 psia (9.77 bara) at 70 F (21 )
Vapor Density
---
Relative Density
Not applicable.
Bulk Density
---
Density
0.51 g/cm3 (31.838 lb/ft3) at 15 ( 59 F)
Flammability
Refer to product classification in Section 2
Upper Explosive Limit
9.6 %(V)
Lower Explosive Limit
2.1 %(V)
Explosive Limits
---
Auto Ignition Temperature
> 450
Decomposition Temperature
Not applicable.
Solubility
---
Partition Coefficient
Not known.
Solubility In Water
No data available.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Aquatic toxicity : No data is available on the product itself. Toxicity to fish - Components Isobutane LC50 (96 h) : 28 mg/l Species : Fish. Toxicity to daphnia - Components Isobutane EC50 (48 h) : 16.3 mg/l Species : Daphnia magna. Toxicity to algae - Components Isobutane EC50 (72 h) : 8.6 mg/l Species : Algae. Toxicity to other organisms : No data is available on the product itself.

12.2. Persistence and degradability

No data available.

12.3. Bioaccumulative potential

Refer to Section 9 "Partition Coefficient (n-octanol/water)".

Refer to Section 9 for partition coefficient information.

12.4. Mobility in soil

Because of its high volatility, the product is unlikely to cause ground pollution.

The product is unlikely to cause ground pollution due to its high volatility.

12.5. Results of PBT and vPvB assessment

If applicable, refer to the extended section of the SDS for further information on CSA.

12.6. Other adverse effects

This product has no known eco-toxicological effects. Effect on the ozone layer : No known effects from this product. Ozone Depleting Potential : None Effect on global warming : When discharged in large quantities may contribute to the greenhouse effect. Global Warming Potential Components Butane : 4 Isobutane : 3 Propene : 2 Propane : 3

The product has no known eco-toxicological effects or ozone-depleting potential. It may contribute to the greenhouse effect when discharged in large quantities.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1978
Shipping Name
PROPANE
Transport Class
2.1
Packing Group
Not applicable.
ADR

Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency.

IATA

Passenger and Cargo Aircraft : Transport forbidden Cargo Aircraft only : Transport allowed

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Propane?

The signal word is danger.

What is the physical form of Propane?

Propane is a liquefied gas. with colorless gas color. It has sweet. poor warning properties at low concentrations. stenchant often added. odor.

What is Propane used for?

Industrial and professional use. Perform risk assessment prior to use.

What are the hazard statements for Propane?

This substance has 2 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.

What is the melting point of Propane?

The melting point is No data available. and the boiling point is - 44 F (-42 ).