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Safety Data Sheet EN

Propane

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Propane
Product Code
169570
Synonyms
Commercial Propane(All); EGP; Export Grade Propane; HD5 Propane; LP-Gas; Liquefied Petroleum Gas; Odorized Propane; Propane (Unstenched); Propane Commercial; Propane Motor Fuel; Propane for Process; Stenched Propane; Unodorized Propane

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Fuel Chemical Chemical feedstock

Uses advised against

All others

Manufacturers & Suppliers

Phillips 66 Company logo

Phillips 66 Company

manufacturer

P.O. Box 421959, Houston, Texas 77242-1959

800-762-0942

http://www.phillips66.com/SDS

Emergency Contacts

CHEMTREC Global

+1 703 527 3887

CHEMTREC United States

1-800-424-9300

CHEMTREC Mexico

01-800-681-9531

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Press. Gas (Liq.) H280
Simple asphyxiant

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

Hazard Statements

H220 Extremely flammable gas
H280 Contains gas under pressure; may explode if heated
H280 May displace oxygen and cause rapid suffocation

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P243 Take precautionary measures against static discharge
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
P410 + P403 Protect from sunlight. Store in a well-ventilated place

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

HD-5 COMPOSITION: Propane >90%, Propylene <5%. Odorized products contain small quantities (<0.1%) ethyl mercaptan as an olfactory indicator.

Chemical Name CAS Number Concentration Hazardous
Propane 74-98-6 80 - 100% No
Propene 115-07-1 20% No
Ethane 74-84-0 6% No
Butane 106-97-8 5% No
Isobutane 75-28-5 2.5% No
ethyl mercaptan --- 0.1% No

Notes

¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

move victim away from source of exposure and into fresh air in a position comfortable for breathing. If breathing is difficult, oxygen or artificial respiration should be administered by qualified personnel. If symptoms persist, seek medical attention.

Symptoms: shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting. Continued exposure can lead to hypoxia (inadequate oxygen), rapid breathing, cyanosis (bluish discoloration of the skin), numbness of the extremities, unconsciousness and death.

Skin contact

Treat burned or frostbitten skin by flushing or immersing the affected area(s) in lukewarm water. Do not rub affected area. Do not remove clothing that adheres due to freezing. After sensation has returned to the frostbitten skin, keep skin warm, dry, and clean. If blistering occurs, apply a sterile dressing. Seek immediate medical attention.

Symptoms: cryogenic burns or injury

Eye contact

remove contact lenses if present and easy to do, hold eyelids apart and gently flush the affected eye(s) with lukewarm water. Seek immediate medical attention.

Ingestion

This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Immediate Medical Attention

Seek immediate medical attention.

Medical Treatment

Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to high concentrations of hydrocarbon solvents. The use of other drugs with less arrhythmogenic potential should be considered.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry chemical or carbon dioxide is recommended.

Specific hazards

Extremely flammable. Contents under pressure. This material can be ignited by heat, sparks, flames, or other sources of ignition. Vapors may travel considerable distances to a source of ignition where they can ignite, flash back, or explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. If container is not properly cooled, it can rupture in the heat of a fire.

Instructions

Stop spill/release if it can be done safely. If this cannot be done, allow fire to burn. Move undamaged containers from immediate hazard area if it can be done safely. Stay away from ends of container. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely.

Firefighter Protection

For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop and contain spill/release if it can be done safely. Water spray may be useful in minimizing or dispersing vapors. Ventilate area and allow to evaporate. Stay upwind and away from spill/release. Avoid direct contact with material.

Large spill

notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out

Environmental

Stop and contain spill/release if it can be done safely. Water spray may be useful in minimizing or dispersing vapors.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Use good personal hygiene practices and wear appropriate personal protective equipment. Extremely Flammable. Contents under pressure. Gas can accumulate in confined spaces and limit oxygen available for breathing. Cold burns may occur during filling operations.

Storage

Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Store only in approved containers. Post area 'No Smoking or Open Flame.' Protect container(s) against physical damage. Outdoor or detached storage is preferred.

Hygiene

Use good personal hygiene practices.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Grounding and bonding containers and equipment.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required.

Hands

Wear thermal insulating gloves when working with materials that present thermal hazards (hot or cold).

Eyes

The use of eye protection (such as splash goggles) that meets or exceeds ANSI Z.87.1 is recommended when there is potential liquid contact to the eye. Depending on conditions of use, a face shield may be necessary.

Respiratory

A NIOSH approved, self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode should be used in situations of oxygen deficiency (oxygen content less than 19.5 percent), unknown exposure concentrations, or situations that are immediately dangerous to life or health (IDLH). A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State Data
gas
Freezing Point
-309 °F / -189 °C
Density
---
Physical State
Liquefied Gas
State Under Standard Conditions
---
Explosive Limits
---
Evaporation Rate
>1
Ph
Not applicable
Vapor Density
>1 (air = 1)
Colour Intensity
---
Softening Point
---
Auto Ignition Temperature
842 °F / 450 °C
Decomposition Temperature
No data
Crystallisation Point
---
Kinematic Viscosity
---
Properties Status
---
Lower Explosive Limit
2.1
Appearance
Colorless
Solidification Point
---
Melting Point
-309 °F / -189 °C
Voc Content
---
Colour
Colorless
Upper Explosive Limit
No data
Relative Density
0.50-0.51 @ 60°F (15.6°C) (water = 1)
Solubility In Fat
---
Metal Corrosion
---
Odor Threshold
No data
Relative Evaporation Rate
---
Flammability
Extremely Flammable
Boiling Point
-44 °F / -42 °C
Vapor Pressure
208 psia (Reid VP) @ 100°F / 37.8°C
Form
---
Solubility In Water
---
Partition Coefficient
No data
Odor
No distinct odor (or skunk, rotten egg or garlic if odorant added)
Molecular Weight
No data
Cloud Point
---
Dynamic Viscosity
---
Solubility
Negligible
Bulk Density
No data
Flash Point
-156 °F / -104 °C
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal ambient and anticipated conditions of use.

Reactivity

Not chemically reactive.

Hazardous reactions

Hazardous reactions not anticipated.

Avoid

Avoid all possible sources of ignition. Heat will increase pressure in the storage tank.

Incompatible

Avoid contact with acids, aluminum chloride, chlorine, chlorine dioxide, halogens and oxidizing agents.

Decomposition

Not anticipated under normal conditions of use.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

This material is a gas and would not typically be managed as a waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1978
Shipping Name
Propane
Transport Class
2.1
ADR

For domestic transportation only, UN1075 may be substituted for the UN number shown as long as the substitution is consistent on package markings, shipping papers, and emergency response information. See 49 CFR 172.102 Special Provision 19. Containers of NON-ODORIZED liquefied petroleum gas must be marked either NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f), 326(d), 330(c) and 338(e)]

IMDG

For domestic transportation only, UN1075 may be substituted for the UN number shown as long as the substitution is consistent on package markings, shipping papers, and emergency response information. See 49 CFR 172.102 Special Provision 19. Containers of NON-ODORIZED liquefied petroleum gas must be marked either NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f), 326(d), 330(c) and 338(e)]

IATA

For domestic transportation only, UN1075 may be substituted for the UN number shown as long as the substitution is consistent on package markings, shipping papers, and emergency response information. See 49 CFR 172.102 Special Provision 19. Containers of NON-ODORIZED liquefied petroleum gas must be marked either NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f), 326(d), 330(c) and 338(e)]

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Propane known by?

Propane is also known as: Commercial Propane(All); EGP; Export Grade Propane; HD5 Propane; LP-Gas; Liquefied Petroleum Gas; Odorized Propane; Propane (Unstenched); Propane Commercial; Propane Motor Fuel; Propane for Process; Stenched Propane; Unodorized Propane

What is the hazard signal word for Propane?

The signal word is danger.

What is the physical form of Propane?

Propane is a liquefied gas appearing as colorless with colorless color. It has no distinct odor (or skunk, rotten egg or garlic if odorant added) odor.

What is the solubility of Propane?

Negligible

What is Propane used for?

Fuel Chemical Chemical feedstock

What are the hazard statements for Propane?

This substance has 3 hazard statements:

  • H220: Extremely flammable gas
  • H280: Contains gas under pressure; may explode if heated
  • H280: May displace oxygen and cause rapid suffocation

What is the melting point of Propane?

The melting point is -309 °F / -189 °C and the boiling point is -44 °F / -42 °C.