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Safety Data Sheet EN

Propane

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Propane
Product Code
169570

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Fuel Chemical Chemical feedstock

Uses advised against

All others

Manufacturers & Suppliers

Phillips 66 Company logo

Phillips 66 Company

manufacturer

P.O. Box 421959 Houston, Texas 77242-1959

800-762-0942

www.phillips66.com/SDS

Emergency Contacts

CHEMTREC Global

+1 703 527 3887

CHEMTREC United States

1-800-424-9300

CHEMTREC Mexico

01-800-681-9531

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Press. Gas (Liq.) H280
Simple asphyxiant

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

Hazard Statements

H220 Extremely flammable gas
H280 Contains gas under pressure; may explode if heated
May displace oxygen and cause rapid suffocation

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P243 Take precautionary measures against static discharge
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P381 Eliminate all ignition sources if safe to do so
P410 + P403 Protect from sunlight. Store in a well-ventilated place

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

HD-5 COMPOSITION: Propane >90%, Propylene <5%

Chemical Name CAS Number Concentration Hazardous
opaan EC: 200-827-9 74-98-6 90 - 100% No
propylene EC: 204-062-1 115-07-1 5% No
Ethane EC: 200-814-8 74-84-0 6% No
butane substance with national workplace exposure limit(s) (AT, BE, BG, DE, DK, ET, FI, FR, GB, GR, HU, IE, IT, LV. PL, PT) EC: 203-448-7 106-97-8 5% No
Isobutne EC: 200-857-2 75-28-5 2.5% No
Ethyl mercaptan --- 0.1% No

Notes

All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Odorized products contain small quantities (<0.1%) ethyl mercaptan as an olfactory indicator.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If respiratory symptoms develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. If breathing is difficult, oxygen or artificial respiration should be administered by qualified personnel. If symptoms persist, seek medical attention.

Symptoms: respiratory symptoms, shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting. Continued exposure can lead to hypoxia (inadequate oxygen), rapid breathing, cyanosis (bluish discoloration of the skin), numbness of the extremities, unconsciousness and death.

Skin contact

Liquefied gases may cause cryogenic burns or injury. Treat burned or frostbitten skin by flushing or immersing the affected area(s) in lukewarm water. Do not rub affected area. Do not remove clothing that adheres due to freezing. After sensation has returned to the frostbitten skin, keep skin warm, dry, and clean. If blistering occurs, apply a sterile dressing.

Symptoms: cryogenic burns or injury.

Eye contact

For contact with the liquefied gas, remove contact lenses if present and easy to do, hold eyelids apart and gently flush the affected eye(s) with lukewarm water.

Ingestion

This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Symptoms: This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Immediate Medical Attention

Seek immediate medical attention.

Medical Treatment

The use of other drugs with less arrhythmogenic potential should be considered.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional engineering controls may be required.

Hands

Wear thermal insulating gloves when working with materials that present thermal hazards (hot or cold).

Eyes

The use of eye protection (such as splash goggles) that meets or exceeds ANSI Z.87.1 is recommended when there is potential liquid contact to the eye. Depending on conditions of use, a face shield may be necessary.

Respiratory

A NIOSH approved, self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode should be used in situations of oxygen deficiency (oxygen content less than 19.5 percent), unknown exposure concentrations, or situations that are immediately dangerous to life or health (IDLH). A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquefied Gas
Physical State Data
gas
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
---
Odor
No distinct odor (or skunk, rotten egg or garlic if odorant added)
Odor Threshold
No data
Ph
Not applicable
Melting Point
-309 ºF / -189 ℃
Boiling Point
-44 ºF / -42 ℃
Flash Point
-156 °F / -104 ℃
Freezing Point
-309 ºF / -189 ℃
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
>1
Vapor Pressure
208 psia (Reid VP) @ 100°F / 37.8℃
Vapor Density
>1 (air = 1)
Relative Density
0.50-0.51 @ 60ºF (15.6℃) (water = 1)
Bulk Density
No data
Density
---
Flammability
Extremely Flammable
Upper Explosive Limit
No data
Lower Explosive Limit
2.1
Explosive Limits
---
Auto Ignition Temperature
842 ºF / 450 ℃
Decomposition Temperature
No data
Solubility
Negligible
Partition Coefficient
No data
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
No data
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1978
Shipping Name
Propane,
Transport Class
2.1
IMDG

For domestic transportation only, UN1075 may be substituted for the UN number shown as long as the substitution is consistent on package markings, shipping papers, and emergency response information. See 49 CFR 172.102 Special Provision 19. Containers of NON-ODORIZED liquefied petroleum gas must be marked either NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f), 326(d), 330(c) and 338(e)]

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Propane?

The signal word is danger.

What is the physical form of Propane?

Propane is a liquefied gas appearing as colorless with colorless color. It has no distinct odor (or skunk, rotten egg or garlic if odorant added) odor.

What is the solubility of Propane?

Negligible

What is Propane used for?

Fuel Chemical Chemical feedstock

What are the hazard statements for Propane?

This substance has 3 hazard statements:

  • H220: Extremely flammable gas
  • H280: Contains gas under pressure; may explode if heated
  • May displace oxygen and cause rapid suffocation

What is the melting point of Propane?

The melting point is -309 ºF / -189 ℃ and the boiling point is -44 ºF / -42 ℃.

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