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Safety Data Sheet EN

TG1089

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
TG1089

Regulatory Identifiers

CAS Number
N/A
UFI Code
7A3W-30SE-C00G-H5FF

Identified Uses

Additive for Off-Highway.

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE, CS 61062, 76173 ROUEN CEDEX, 76173, FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
Benzenesulfonic acid, mono-C16-24-alkyl derivatives, calcium salts EC: 274-263-7 --- 5 - 10% Yes
Benzene, polypropene derivatives, sulfonated, calcium salts --- 5 - 10% Yes
2-Propenoic acid, 2-hydroxyethyl ester, reaction products with O,O-bis(1,3-dimethylbutyl) hydrogen phosphorodithioate and dimethyl phosphonate --- 5 - 10% Yes
Distillates (petroleum), solvent-dewaxed heavy paraffinic EC: 265-169-7 --- 1 - 10% Yes
1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC: 293-927-7 --- 1 - 5% Yes
1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. EC: 482-000-4 --- 1 - 5% Yes
Reaction products of boric acid with 2-propylheptan-1-ol (1:3) EC: 806-750-2 --- 1 - 5% Yes
Distillates (petroleum), hydrotreated heavy paraffinic EC: 265-157-1 --- 1 - 10% Yes
Dibutyl phosphonate EC: 217-316-1 --- 1 - 5% Yes
2-tetradecyloxirane, reaction products with boric acid EC: 701-392-2 --- 1 - 5% Yes
Dicoco alkylamine EC: 263-086-0 --- 0.1 - 0.25% Yes
Benzene, polypropene derivatives EC: 614-264-5 --- 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Launder contaminated clothing before reuse.

Eye contact

Rinse cautiously with water for several minutes. Flush thoroughly with water. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth.

Immediate Medical Attention

If irritation occurs, get medical assistance. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs: Get medical attention. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Material creates a special hazard because it floats on water. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. See Section 8 of the SDS for Personal Protective Equipment.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse. Avoid environmental contamination. Avoid inhalation of vapors upon opening container.

Storage

Store away from incompatible materials. See section 10 for incompatible materials.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Launder contaminated clothing before reuse.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special requirements under ordinary conditions of use and with adequate ventilation. Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Gloves are recommended when handling this material. Unless material is used in a process where the use of gloves would pose sufficient risk of injury to the user/operator. Consult with an industrial hygienist to determine the appropriate clothing protection for your specific use of this material. Chemical resistant gloves Gloves that are impervious to the new chemical substance are required. Because specific work environments and material handling practices vary, safety procedures should be specific for each intended application. The correct choice of protective gloves depends upon the chemicals being handled, and the conditions of work and use. Most gloves provide protection for only a limited time before they must be discarded and replaced (even the best chemically resistant gloves will break down after repeated chemical exposures). Gloves should be chosen in consultation with the supplier / manufacturer and taking account of a full assessment of the working conditions. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. Break-through time: Breakthrough time data are generated by glove manufacturers under laboratory test conditions and represent how long a glove can be expected to provide effective permeation resistance. It is important when following breakthrough time recommendations that actual workplace conditions are taken into account. Always consult with your glove supplier for up-to-date technical information on breakthrough times for the recommended glove type. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. If suitable gloves are not available to offer that level of protection, gloves with shorter breakthrough times may be acceptable as long as appropriate glove maintenance and replacement regimes are determined and adhered to. For short-term, transient exposures and splash protection, gloves with shorter breakthrough times may commonly be used. Therefore, appropriate maintenance and replacement regimes must be determined and rigorously followed. Glove thickness: For general applications, we recommend gloves with a thickness typically greater than 0.35 mm. It is important to note that glove thickness is not the only predictor of glove resistance to a specific chemical, as the permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times. Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers' technical data should always be taken into account to ensure selection of the most appropriate glove for the task. Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example: Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only likely to give short duration protection and would normally be just for single use applications, before being disposed of. Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential.

Eyes

Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. NIOSH approved respirator with an APF of 50 is required in accordance with 29 CFR 1910.134. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Please refer to the relevant EN standards for the RPE selected.

Skin/Body

Gloves, coveralls, apron, boots as necessary to minimize contact. Do not wear rings, watches or similar apparel that could entrap the material. Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Dark amber
Colour Intensity
---
Form
liquid
Odor
Characteristic
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
114 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
0.967 - 1.007 (15.6 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
250 mm2/s (40 °C); 26 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

None known.

Incompatible

Strong oxidizing agents. Oxidizing agents. Contact with acids.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion. Thermal decomposition may generate phosphorus oxides and other phosphorus containing compounds. Hydrogen sulfide may also be released.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to Aquatic Plants 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol NOEC (Green algae (Selenastrum capricornutum), 3 Days): 100 mg/l EC 50 (Green algae (Selenastrum capricornutum), 3 Days): > 100 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants 1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. EC 50 (Alga, 3 d): 16 mg/l NOEC (Alga, 3 d): 3.2 mg/l

12.1 Toxicity

Fish

12.1 Toxicity

### Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Toxicity

### Fish 2-Propenoic acid, 2-hydroxyethyl ester, reaction products with O,O-bis(1,3-dimethylbutyl) hydrogen phosphorodithioate and dimethyl phosphonate LC 50 (Gobiocypris rarus, 96 h): 62 mg/l LC 50 (Fathead Minnow, 96 h): 48 mg/l

12.1 Toxicity

Fish Distillates (petroleum), solvent-dewaxed heavy paraffinic LC 50 (Fathead Minnow, 96 h): > 100 mg/l

12.1 Toxicity

### Fish 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Toxicity

Fish 1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. LC 50 (Rainbow Trout, 4 d): > 100 mg/l

12.1 Toxicity

Fish Reaction products of boric acid with 2-propylheptan-1-ol (1:3) LC 50 (Rainbow Trout, 96 h): 6.4 mg/l

12.1 Toxicity

++ Benzene, polypropylene derivatives LC 50 (Not reported, 4 d): > 100.1 mg/l

12.1 Toxicity

### Fish Distillates (petroleum), hydrotreated heavy paraffinic LC 50 (Fathead Minnow, 96 h): > 100 mg/l

12.1 Toxicity

### Fish Dibutyl phosphonate LC 50 (Zebra Fish, 96 h): 63.4 mg/l

12.1 Toxicity

Fish 2-tetradecyloxirane, reaction products with boric acid LC 50 (Rainbow Trout, 4 d): > 100 mg/l

12.1 Toxicity

Aquatic Invertebrates Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Toxicity

## 12.1 Toxicity ### Aquatic Invertebrates 2-Propenoic acid, 2-hydroxyethyl ester, reaction products with O,O-bis(1,3-dimethylbutyl) hydrogen phosphorodithioate and dimethyl phosphonate EC 50 (Water flea (Daphnia magna), 48 h): 2.0 mg/l EC 10 (Water flea (Daphnia magna)): 1.01 mg/l

12.1 Toxicity

Aquatic Invertebrates Distillates (petroleum), solvent-dewaxed heavy paraffinic EC 50 (Water flea (Daphnia magna), 48 h): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Toxicity

### Aquatic Invertebrates 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC 50 (Water flea (Daphnia magna), 2 d): 41 mg/l

12.1 Toxicity

Aquatic Invertebrates 1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. EC 50 (Water flea (Daphnia magna), 2 d): 230 mg/l

12.1 Toxicity

### Aquatic Invertebrates Reaction products of boric acid with 2-propylheptan-1-ol (1:3) EC 50 (Water flea (Daphnia magna), 48 h): 5.7 mg/l NOEC (Water Flea (Daphnia Magna), 21 d): 1.9 mg/l

12.1 Toxicity

Aquatic Invertebrates Distillates (petroleum), hydrotreated heavy paraffinic EC 50 (Water flea (Daphnia magna), 48 h): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Toxicity

Aquatic Invertebrates Dibutyl phosphonate EC 50 (Water Flea (Daphnia Magna), 48 h): 20.8 mg/l

12.1 Toxicity

Aquatic Invertebrates 2-tetradecyloxirane, reaction products with boric acid EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 20 mg/l NOEC (Water flea (Daphnia magna), 21 d): 10 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants 2-Propenoic acid, 2-hydroxyethyl ester, reaction products with O,O-bis(1,3-dimethylbutyl) hydrogen phosphorodithioate and dimethyl phosphonate EC 50 (Algae (Pseudokirchneriella subcapitata), 96 h): > 100 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Distillates (petroleum), solvent-dewaxed heavy paraffinic EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): > 100 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): >= 100 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Reaction products of boric acid with 2-propylheptan-1-ol (1:3) EC 50 (Green algae (Selenastrum capricornutum), 72 h): 21 mg/l NOEC (Green algae (Selenastrum capricornutum), 72 h): 5.2 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Distillates (petroleum), hydrotreated heavy paraffinic EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): > 100 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): >= 100 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Dibutyl phosphonate EC 50 (Algae (Pseudokirchneriella subcapitata), 72 h): 14.4 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): 3 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants 2-tetradecyloxirane, reaction products with boric acid EC 50 (Green algae (selenastrum capricomutum), 3 d): > 100 mg/l

12.1 Toxicity

Toxicity to microorganisms Distillates (petroleum), solvent-dewaxed heavy paraffinic EC 50 (Sludge, 0.1 d): > 10,000 mg/l

12.1 Toxicity

Toxicity to microorganisms 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol EC 50 (Pseudomonas putida, 0.7 Days): > 8,000 mg/l

12.1 Toxicity

Toxicity to microorganisms 1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. EC 50 (Sludge, 0.1 d): > 1,000 mg/l NOEC (Sludge, 0.1 d): > 1,000 mg/l

12.1 Toxicity

Toxicity to microorganisms Reaction products of boric acid with 2-propylheptan-1-ol (1:3) EC 50 (Bacteria, 0.1 Days): 230 mg/l

12.1 Toxicity

Toxicity to microorganisms 2-tetradecyloxirane, reaction products with boric acid EC 50 (Sludge, 0.1 d): > 10,000 mg/l

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation 2-Propenoic acid, 2-hydroxyethyl ester, reaction products with O,O-bis(1,3-dimethylbutyl) hydrogen phosphorodithioate and dimethyl phosphonate OECD TG 301 B, 3.3 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation Distillates (petroleum), solvent-dewaxed heavy paraffinic OECD TG 301 F, 31 %, 28 d, Not readily degradable. Inherent Sludge, 30 %, 28 d, Not readily degradable. OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation 1,3,4-Thiadiazolidine-2,5-dithione, reaction products with hydrogen peroxide and tert-nonanethiol OECD TG 301 C, 2 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation 1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. OECD TG 301 B, 11 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation Reaction products of boric acid with 2-propylheptan-1-ol (1:3) OECD TG 301 B, 74 %, 28 d, Readily biodegradable

12.2 Persistence and Degradability

### Biodegradation ++ Benzene, polypropene derivatives OECD TG 301 F, 58.8 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Distillates (petroleum), hydrotreated heavy paraffinic OECD TG 301 F, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

### Biodegradation 2-tetradecyloxirane, reaction products with boric acid Miscellaneous, 17.3 %, 28 d, Not readily degradable. Miscellaneous, 26.7 %, 28 d, Not readily degradable.

12.3 Bioaccumulative potential

Log Kow: 10.88 (Read across)

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Log Kow: 9.4 (Measured)

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

1,2-Propanediol, 3-amino-, N,N-dicoco alkyl derivs. Log Kow: 3.86 (calculated)

12.1 Toxicity

12.2 Persistence and degradability

12.3 Bioaccumulative potential

Log Kow: estimated 1.81 25 °C

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

Log Kow: 9.4 (calculated)

12.4 Mobility in soil:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine disrupting properties:

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

Product: Harmful to aquatic life with long lasting effects.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of in accordance with applicable Federal, State/Provincial, and Local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for TG1089?

The signal word is warning.

What is the physical form of TG1089?

TG1089 is a liquid with dark amber color. It has characteristic odor.

What is TG1089 used for?

Additive for Off-Highway.

What are the hazard statements for TG1089?

This substance has 2 hazard statements:

  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.