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Safety Data Sheet EN

ACMO

CAS 5117-12-4
EC 418-140-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ACMO
Chemical Name
4-(1-Oxo-2-propenyl)-morpholine
Synonyms
4-(1-Oxo-2-propenyl)-morpholine

Regulatory Identifiers

CAS Number
5117-12-4 Check regulations →
EC Number
418-140-1 Check regulations →

Identified Uses

Diluent for radically curable inks, coatings, adhesives, fillers, etc.

Uses advised against

No further relevant information available.

Manufacturers & Suppliers

RAHN USA Corp. logo

RAHN USA Corp.

manufacturer

1005 North Commons Drive, Aurora, IL 60504, USA

+1 630 851 42 20

http://www.rahn-group.com

Emergency Contacts

Infotrak

++1 800 535 5053

24h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

STOT RE Cat. 2 H373
Eye Dam. Cat. 1 H318
Acute Tox. Cat. 4 H302
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure. Route of exposure: Oral.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a poison center/doctor.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

CAS No. Description

Chemical Name CAS Number Concentration Hazardous
4-(1-oxo-2-propenyl)-morpholine EC: 418-140-1 5117-12-4 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. In the case of accidental inhalation of monomers provide fresh air, rest and warmth.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Avoid contact with UV- and sunlight.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

A person vomiting while lying on their back should be turned onto their side. Call a doctor immediately. Rinse out mouth and then drink plenty of water.

Immediate Medical Attention

Involve doctor immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire fighting measures that suit the environment.

Unsuitable media

Water with full jet

Specific hazards

In case of fire, the following can be released: COx, Nitrogen oxides (NOx)

Instructions

Use fire fighting measures that suit the environment.

Firefighter Protection

Wear self-contained respiratory protective device. Wear fully protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep people at a distance and stay upwind.

Environmental

Inform respective authorities in case of seepage into water course or sewage system.

Cleanup methods

Absorb with liquid-binding material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. When using this substance use skin protection

Storage

Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Store receptacle in a well ventilated area. Store under lock and key or with access restricted to technical experts or their assistants only. Do not store at temperatures above 40 °C.

Fire prevention

Keep ignition sources away - Do not smoke. Protect from heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No further data; see item 7.

Hands

Protective gloves. Material of gloves: Synthetic gloves, Neoprene gloves. Products used with solvents: wear thick (>0.5mm) nitrile gloves. Replace gloves immediately when torn or any change in appearance (dimesion, colour, flexibility etc) is noticed. Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eyes

Face protection. Tightly sealed goggles. Goggles recommended during refilling.

Respiratory

Filter A/P2. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Use suitable respiratory protective device only when aerosol or mist is formed.

Skin/Body

Impervious protective clothing

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Yellowish
Colour Intensity
---
Form
Fluid
Odor
Characteristic
Odor Threshold
Not determined.
Ph
7 - 9
Melting Point
-8 °C (18 °F)
Boiling Point
Undetermined.
Flash Point
126 °C (259 °F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
0.0103 hPa
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
---
Density
1.119 g/cm³ (9.338 lbs/gal)
Flammability
Not applicable.
Upper Explosive Limit
Not determined.
Lower Explosive Limit
Not determined.
Explosive Limits
---
Auto Ignition Temperature
Product is not selfigniting.
Decomposition Temperature
Not determined.
Solubility
---
Partition Coefficient
Not determined.
Solubility In Water
Fully miscible.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
12 mPas
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if used and stored according to specifications.

Hazardous reactions

No dangerous reactions known.

Avoid

Polymerisation occurs when exposed to white light, ultraviolet light or heat.

Incompatible

Avoid contact with radical forming initiators, peroxides, strong alkalies or reactive metals to prevent exothermic polymerisation.

Decomposition

No dangerous decomposition products known.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

- Toxicity | · Aquatic toxicity: | | | --- | --- | | 5117-12-4 4-(1-oxo-2-propenyl)-morpholine | |

12.1 Toxicity

OECD 201 algae growth inhibition >120 mg/l (algae) (EC50; 72h) OECD 202 Daphnia acute immobilization >200 mg/l (EC50/48h) (daphnia) (EC50, 48h) OECD 203 fish acute toxicity >200 mg/l (fish) (LC100; 96h)

12.2 Persistence and degradability

OECD 209 activated sludge ready biodegradability >120mg/l (bacteria) (EC50; 3h) 35% (28d) (-) (OECD 301) according OECD criteria not readily biodegradable, however potentially biodegradable (inherent biodegradable)

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Mobility in soil

No further relevant information available.

Other adverse effects

No further relevant information available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Can be incinerated, when in compliance with local regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is ACMO known by?

ACMO is also known as: 4-(1-Oxo-2-propenyl)-morpholine

What is the hazard signal word for ACMO?

The signal word is danger.

What is the physical form of ACMO?

ACMO is a liquid with yellowish color. It has characteristic odor.

What is ACMO used for?

Diluent for radically curable inks, coatings, adhesives, fillers, etc.

What are the hazard statements for ACMO?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H373: May cause damage to organs through prolonged or repeated exposure. Route of exposure: Oral.

What is the melting point of ACMO?

The melting point is -8 °C (18 °F) and the boiling point is Undetermined..