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Safety Data Sheet EN

ADDITOL® LED 01

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ADDITOL® LED 01
Product Code
0047174

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Binder

Uses advised against

This product should not be used in consumer applications such as food packaging or cosmetic applications

Manufacturers & Suppliers

Allnex USA Inc. logo

Allnex USA Inc.

manufacturer

9005 Westside Parkway, Alpharetta, Georgia 30009, USA

http://www.allnex.com/contact

Emergency Contacts

Emergency Contact

+1-866-928-0789

Carechem 24 - Allnex29003-NCEC

+1-215-207-0061

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Skin Sens. Cat. 1A
Aquatic Acute Cat. 1
Aquatic Chronic Cat. 1

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS09 - Environmental hazard

GHS09

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash face, hands and any exposed skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P321 Specific treatment (see supplemental first aid instructions on this label).
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local and national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethoxylated trimethylolpropane triacrylate 28961-43-5 20 - 30% Yes
Polyol acrylate --- 20 - 30% Yes
Mercapto derivative --- 25% Yes
Ethoxylated acrylated ester --- 40 - 50% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms.

Skin contact

Flush with a continuous flow of lukewarm water for 20 minutes or until material is removed. Wash with plenty of water and soap. Remove contaminated clothing and shoes without delay. Obtain medical attention if symptoms persist. Do not reuse contaminated clothing without laundering. Destroy or thoroughly clean shoes before reuse.

Eye contact

Rinse immediately with plenty of water for at least 15 minutes. Obtain medical advice if there are persistent symptoms.

Ingestion

If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical attention.

Medical Treatment

No specific measures have been identified.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray or fog, carbon dioxide or dry chemical.

Unsuitable media

high pressure water jet.

Specific hazards

Keep containers cool by spraying with water if exposed to fire.

Firefighter Protection

Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See SDS Section 8 (Exposure Controls/Personal Protection).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Use appropriate containment to avoid environmental contamination. Avoid release to the environment.

Cleanup methods

Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water.

Materials: Inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid release to the environment. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves and eye/face protection.

Storage

Store in a cool, dry, well ventilated place and keep container tightly closed. Keep away from heat sources and direct sunlight.

Hygiene

Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Fire prevention

Keep away from heat sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure when spraying or curing at elevated temperatures.

Hands

Wear protective gloves. Recommendations are listed below. Other protective materials may be used based on user's own risk assessment. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension, color, flexibility etc.) is noticed. Gloves for repeated or prolonged exposure - non exhaustive list: Nitrile rubber (NBR), thickness: > 0.56 mm, break through time: up to 480 min. Gloves for short term exposure/splash protection - non exhaustive list: Nitrile rubber (NBR), thickness: 0.1 mm, break through time: up to 30 min. The chemical resistance depends on the type of product and amount of product on the glove. Therefore gloves need to be changed when in contact with chemicals. Not suitable gloves - non exhaustive list: Latex gloves. Due to many conditions (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing. Use PE gloves as under gloves for difficult situations like for instance: high exposure, unknown composition or unknown properties of the chemicals.

Eyes

Wear eye/face protection such as chemical splash proof goggles or face shield. Eyewash equipment and safety shower should be provided in areas of potential exposure.

Respiratory

For operations where inhalation exposure can occur use an approved respirator. Recommendations are listed below. Other protective respiratory equipment may be used based on user's own risk assessment. Recommended respirators include those certified by NIOSH. Recommended: Full Face Mask with organic vapor cartridge, Type A filter (BP >65°C)

Skin/Body

Avoid skin contact. Wear impermeable gloves and suitable protective clothing. Barrier creams may be used in conjunction with the gloves to provide additional skin protection.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
pink
Colour Intensity
---
Form
---
Odor
acrylate
Odor Threshold
---
Ph
---
Melting Point
Not available
Boiling Point
> 200 °C
Flash Point
(polymerized at 150 °C) Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 1.33 hPa @ 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1.1685 g/cm³
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Low viscous liquid
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable.

Reactivity

No information available

Hazardous reactions

May occur. Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers. Hazardous polymerization can occur when exposed to direct sunlight. Hazardous exothermic polymerization can occur when heated.

Avoid

Avoid contact with bases. Avoid direct exposure to sunlight. Avoid exposure to excessive heat, UV light. Avoid temperatures above 60°C (140°F). Protect from heat and direct sunlight. Avoid friction with temperature increase as result. Loss of dissolved air. Loss of polymerization inhibitor.

Incompatible

Strong oxidizing agents and strong bases. Peroxides. Free radical initiators. Avoid contact with reactive metals. They give an exothermic reaction with the product. Unintentional contact with them should be avoided. Peroxides, free radical initiators, strong alkalies. Avoid contact with bases or amines.

Decomposition

Carbon dioxide, Carbon monoxide (CO), oxides of sulfur (includes sulfur di and tri oxides)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

HAZARDOUS INGREDIENT TOXICITY DATA

Ethoxylated trimethylolpropane triacrylate (28961-43-5): LC50 = 1.95 mg/l - Zebra Fish (Brachydanio rerio) (96h); EC50 70.7 mg/L - Daphnia magna (48h); ErC50 = 2.2 mg/l - Green Algae (Desmodesmus subspicatus) (72h). Mercapto derivative (-): LC50 = 0.42 mg/l - Oncorhynchus mykiss (96h); EC50 = 0.71 mg/l - Daphnia Magna (48h).

12.1 Toxicity

Overall Environmental Toxicity: Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

12.5 Results of PBT and vPvB assessment

Not determined

OTHER ADVERSE EFFECTS

Overall Environmental Toxicity: Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

12.1 Toxicity

LC50 = 1.95 mg/l - Zebra Fish (Brachydanio rerio) (96h)

12.1 Toxicity

LC50 = 0.42 mg/l - Oncorhynchus mykiss (96h)

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

EC50 70.7 mg/L - Daphnia magna (48h)

12.1 Toxicity

EC50 = 0.71 mg/l - Daphnia Magna (48h)

12.1 Toxicity

ErC50 = 2.2 mg/l - Green Algae (Desmodesmus subspicatus) (72h)

12.1 Toxicity

Overall Environmental Toxicity: Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

The substance is classified as very toxic to aquatic life with long lasting effects.

OTHER ADVERSE EFFECTS

The ecological assessment for this material is based on an evaluation of its components.

The ecological assessment for this material is based on an evaluation of its components.

Partition coefficient

Ethoxylated trimethylolpropane triacrylate (28961-43-5): Not available; Polyol acrylate (-): Not available; Mercapto derivative (-): Not available; Ethoxylated acrylated ester (-): Not available

RESULTS OF PBT AND vPvB ASSESSMENT

Not determined
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

thermal treatment or incineration at EPA approved facilities

Disposal

The Company encourages the recycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport Class
9
Packing Group
III
IMDG

Protect against external heat sources above +40°C/104°F.

IATA

Protect against external heat sources above +40°C/104°F.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ADDITOL® LED 01?

The signal word is warning.

What is the physical form of ADDITOL® LED 01?

ADDITOL® LED 01 is a liquid appearing as liquid with pink color. It has acrylate odor.

What is ADDITOL® LED 01 used for?

Binder

What are the hazard statements for ADDITOL® LED 01?

This substance has 5 hazard statements:

  • H315: Causes skin irritation
  • H317: May cause an allergic skin reaction
  • H319: Causes serious eye irritation
  • H400: Very toxic to aquatic life
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of ADDITOL® LED 01?

The melting point is Not available and the boiling point is > 200 °C.